用咀嚼法制备液体天然橡胶及其分子量控制

Saengchao Thongseenuch, Sopapan Jindapaisan, W. Taweepreda
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引用次数: 0

摘要

天然橡胶(NR)含有不饱和成分(双键),易解聚。在二辊轧机中,咀嚼是通过机械作用和热作用使橡胶分子链断裂的过程。本文主要研究了在温控双辊轧机上采用咀嚼法制备解聚天然橡胶。采用凝胶渗透色谱法(GPC)研究了咀嚼温度和时间对解聚度的影响。结果表明,随着咀嚼温度和咀嚼时间的增加,NR的平均分子量有所降低。
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Preparation and molecular weight controlled of liquid natural rubber using Mastication
Natural rubber (NR) can be easily depolymerized because that contain unsaturated component (double bond). Mastication is breaking the rubber molecular chains through mechanical action and thermal in two roll mill. This attention is preparation depolymerized natural rubber, using mastication method with temperature-controlled two roll mill. The effect of temperature and time of mastication on degree of depolymerization were studied and characterized by Gel Permeation Chromatography (GPC). It was found increasing temperature and time of mastication to the resulting decreased average molecular weight of NR.
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