被动式微型直接甲醇燃料电池的研究

Cao Yi-jiang, Yufeng Zhang, Xu Biao, Y. Jinghua, Xiaowei Liu
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引用次数: 0

摘要

为了克服无源微型直接甲醇燃料电池(DMFC)阴极氧质量传递效率低和性能不佳的缺点,对无源微型直接甲醇燃料电池(DMFC)阴极集流器的结构进行了研究。制备了采用平面多孔板结构的阴极集流器的无源微型DMFC。研究了阳极甲醇浓度和阴极开口面积比对性能的影响。由于接触电阻和氧质量输运的影响,无源微型DMFC在开孔率为50%时表现出最佳性能。在此基础上,提出了新型阴极集流器并联通道结构,并利用微精密加工技术制备了相应的无源微型DMFC。实验结果表明,与传统的平面结构相比,采用平行通道结构的阴极集流器提高了氧的传质性和性能稳定性。此外,最大输出功率密度达到9.7 mW/cm2。上述研究对便携式微电源系统的开发和应用具有一定的指导意义。
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Study on passive micro direct methanol fuel cell
In order to overcome the disadvantages of low mass transport efficiency of oxygen to the cathode and poor performance of passive micro direct methanol fuel cells (DMFC), the structures of the cathode current collector for the passive micro DMFC have been studied. The passive micro DMFC employing the cathode current collector with the planar perforated-plate structure has been fabricated. The effect of the anode methanol concentration and the opening area ratio of the cathode on the performance has been investigated. Owing to the influence of contact resistance and oxygen mass transport, the passive micro DMFC exhibits the optimal performance when opening ratio is 50%. Furthermore, the new parallel channels structure of the cathode current collector has been proposed, and the corresponding passive micro DMFC has also been fabricated by utilizing micro precision processing technology. The test results indicate that the mass transfer of oxygen and performance stability have been improved based on the cathode current collector with the parallel channels structure compared to the conventional planar structure. Moreover, a maximum output power density of 9.7 mW/cm2 is achieved. The above studies might be helpful for the developing and application of portable micro power systems.
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