改善低银SnAgCu钎焊的可焊性和电迁移行为

Sun Fenglian, Liu Yang, Wang Jiabing
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引用次数: 14

摘要

与广泛使用的SAC305 (Sn-3.0Ag-0.5Cu)焊料相比,低银(Ag≤1%)SAC焊料在成本和机械抗冲击性方面具有明显优势,但在润湿性差、熔点高、电迁移退化等方面存在缺点,制约了其应用。因此,在焊料中加入一些合适的元素,以提高可焊性和机械性能,对于应用是非常重要的。本文研究了低银SAC焊料的可焊性和电迁移行为。通过SEM和DSC分析了添加Bi和Ni元素对SAC0705 (Sn-0.7Ag-0.5Cu)钎料润湿性、熔化温度和电迁移性能的影响。结果表明,在SAC0705中加入一定的Bi和Ni元素,可以降低钎料的峰值熔点,明显提高钎料在Cu焊盘上的润湿性,减小界面IMC晶粒尺寸。此外,添加一定的Bi和Ni元素可以限制高温和高密度电流应力下的电迁移行为。发现热条件对电迁移行为的影响更大。在高温和高密度电流应力条件下,IMC极化分布和铜消耗急剧加剧。
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Improving the solderability and electromigration behavior of Low-Ag SnAgCu soldering
Compared with widely used SAC305 (Sn-3.0Ag-0.5Cu) solder, low-Ag (Ag≤1%) SAC solder obviously shows advantages in cost and mechanical impact resistance, and disadvantages in worse wettability, higher melting point and degeneration in electromigration, which restrict its application. Therefore, adding some suitable elements to the solder to improve the solderability and mechanical performance is very important for applications. In this paper, the solderability and electromigration behavior of Low-Ag SAC solder were studied. The effect of adding Bi and Ni elements on the wettability, melting temperature and electromigration properties of SAC0705 (Sn-0.7Ag-0.5Cu) soldering on Cu pad were analysed by SEM and DSC investigations. Results indicate that addition of some Bi and Ni elements into SAC0705 could decrease the peak melting point of the solder, improve the wettability of solder on Cu pad obviously, and decrease the IMC grain size in interface. In addition, adding some Bi and Ni elements could restrict the electromigration behavior under high temperature and high density current stressing. It is found that the thermal condition has much more influence on electromigartion behavior. The IMC polarized distribution and copper consumption aggravate sharply under higher temperature and high density current stressing condition.
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