Preparation and Gas Separation of Amorphous Silicon Oxycarbide Membrane Supported on Silicon Nitride Membrane.

An amorphous silicon oxycarbide membrane supported on a silicon nitride membrane substrate was prepared. A starting suspension containing polyhydromethylsiloxane (PHMS), tetramethyltetravinyl-cyclotetrasiloxane (TMTVS) and a platinum catalyst was first prepared and spin-coated on a silicon nitride membrane, and then the suspension was cross-linked and cured, followed by pyrolyzing at 1000 °C under a flowing Ar atmosphere. A dense amorphous silicon oxycarbon ceramic membrane with a thickness of about 1.8 µm was strongly bonded to the Si₃N₄ membrane substrate. The single gas permeation of H₂ and CO₂ indicated that the ideal permeation selectivity of H₂/CO₂ was up to 20 at 25 °C and 0.5 MPa with good long-term stability, indicating the potential application of the obtained membrane for hydrogen purification.