Enhancing exergy efficiency and environmental sustainability in pressure swing azeotropic distillation

This study explores the economic, energetic, exergy efficiency, and environmental benefits of energy integration in pressure-swing distillation, focusing on the separation of tetrahydrofuran/water and acetone/chloroform azeotropes. Heat integration and heat pump techniques are applied to reduce energy consumption. Three energy-efficient configurations are examined, comparing total annual cost (TAC), total energy consumption (TEC), CO₂ emissions, and second-law efficiency. In the tetrahydrofuran/water system, heat integration and heat pump technologies outperform conventional processes, achieving up to 50.2% TAC reduction, 59.6% TEC reduction, 82.8% CO₂ emission reduction, and thermodynamic efficiencies up to 23.5%. In the acetone/chloroform system, similar improvements are observed, with up to 70.9% TAC reduction, 87.2% CO₂ emission reduction, and thermodynamic efficiencies up to 17.6%. These findings demonstrate the effectiveness of energy-saving strategies, endorsing process intensification for environmentally sustainable azeotropic mixture separations.