线性寡(苯乙烯基)共价有机框架

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-09-03 DOI:10.1039/d4cc04045g
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引用次数: 0

摘要

含有低聚亚苯基乙烯单元的共价有机框架(COFs)在提高光催化氢气进化方面前景广阔。本研究提出了一系列线性低聚亚苯基乙烯基 COFs,其β-酮烯胺与亚胺的连接比例各不相同。由于引入了甲氧基侧基,COFs-950-OMe 呈结晶状,与无定形 COFs-950 相比具有更高的比表面积。
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Linear oligo(phenylenevinylene)-based covalent organic frameworks†
Covalent organic frameworks (COFs) incorporating oligo(phenylenevinylene) units have shown promise in enhancing photocatalytic hydrogen evolution. This study presents a series of linear oligo(phenylenevinylene)-based COFs with various ratios of β-ketoenamine to imine linkages. The COFs-950-OMe are crystalline, exhibiting higher surface area compared to amorphous COFs-950, due to the introduction of methoxy side groups.
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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