{"title":"原位生长富含氧空位的氧化锌纳米棒,用于 N-甲基吡咯烷酮传感器","authors":"","doi":"10.1016/j.micrna.2024.207984","DOIUrl":null,"url":null,"abstract":"<div><p>N-methyl pyrrolidone (NMP) is an organic compound that is mainly used in chemical synthesis, the manufacture of anesthetics and pesticides, and the production of electronic materials, especially in the preparation of electrodes for lithium-ion batteries. However, their high volatility and toxicity pose potential risks to health and the environment. Therefore, the development of rapid, highly sensitive and low-cost NMP gas sensors is urgent. In this paper, ZnO nanorods were in situ grown on ceramic tubes via hydrothermal method and subsequently annealed at different temperatures. The gas sensing performance of ZnO nanorods after annealing at different temperatures was investigated. The results show that the ZnO nanorods annealed at 400 °C have more oxygen vacancies and excellent selectivity to NMP at 210 °C, with a response value of up to 67.33–100 ppm NMP, a response time of 25 s, and a low recovery time as low as 8 s. The sensors have potential applications for rapid monitoring of NMP and environmental health protection, providing a simple and feasible method for NMP detection.</p></div>","PeriodicalId":100923,"journal":{"name":"Micro and Nanostructures","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"In situ growth of oxygen vacancies-rich ZnO nanorods for N-methyl pyrrolidone sensors\",\"authors\":\"\",\"doi\":\"10.1016/j.micrna.2024.207984\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>N-methyl pyrrolidone (NMP) is an organic compound that is mainly used in chemical synthesis, the manufacture of anesthetics and pesticides, and the production of electronic materials, especially in the preparation of electrodes for lithium-ion batteries. However, their high volatility and toxicity pose potential risks to health and the environment. Therefore, the development of rapid, highly sensitive and low-cost NMP gas sensors is urgent. In this paper, ZnO nanorods were in situ grown on ceramic tubes via hydrothermal method and subsequently annealed at different temperatures. The gas sensing performance of ZnO nanorods after annealing at different temperatures was investigated. The results show that the ZnO nanorods annealed at 400 °C have more oxygen vacancies and excellent selectivity to NMP at 210 °C, with a response value of up to 67.33–100 ppm NMP, a response time of 25 s, and a low recovery time as low as 8 s. The sensors have potential applications for rapid monitoring of NMP and environmental health protection, providing a simple and feasible method for NMP detection.</p></div>\",\"PeriodicalId\":100923,\"journal\":{\"name\":\"Micro and Nanostructures\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-09-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Micro and Nanostructures\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2773012324002334\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Micro and Nanostructures","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2773012324002334","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
引用次数: 0
摘要
N 甲基吡咯烷酮(NMP)是一种有机化合物,主要用于化学合成、麻醉剂和杀虫剂的制造以及电子材料的生产,尤其是锂离子电池电极的制备。然而,它们的高挥发性和毒性对健康和环境构成了潜在风险。因此,开发快速、高灵敏度和低成本的 NMP 气体传感器迫在眉睫。本文通过水热法在陶瓷管上原位生长 ZnO 纳米棒,然后在不同温度下进行退火。研究了不同温度退火后 ZnO 纳米棒的气体传感性能。结果表明,在 400 °C 下退火的 ZnO 纳米棒具有更多的氧空位,对 210 °C 下的 NMP 具有极佳的选择性,响应值可达 67.33-100 ppm NMP,响应时间为 25 s,恢复时间低至 8 s。该传感器具有快速监测 NMP 和保护环境健康的潜在应用价值,为 NMP 检测提供了一种简单可行的方法。
In situ growth of oxygen vacancies-rich ZnO nanorods for N-methyl pyrrolidone sensors
N-methyl pyrrolidone (NMP) is an organic compound that is mainly used in chemical synthesis, the manufacture of anesthetics and pesticides, and the production of electronic materials, especially in the preparation of electrodes for lithium-ion batteries. However, their high volatility and toxicity pose potential risks to health and the environment. Therefore, the development of rapid, highly sensitive and low-cost NMP gas sensors is urgent. In this paper, ZnO nanorods were in situ grown on ceramic tubes via hydrothermal method and subsequently annealed at different temperatures. The gas sensing performance of ZnO nanorods after annealing at different temperatures was investigated. The results show that the ZnO nanorods annealed at 400 °C have more oxygen vacancies and excellent selectivity to NMP at 210 °C, with a response value of up to 67.33–100 ppm NMP, a response time of 25 s, and a low recovery time as low as 8 s. The sensors have potential applications for rapid monitoring of NMP and environmental health protection, providing a simple and feasible method for NMP detection.