通过引入丙酮作为共溶剂提高由 1-乙基-3-甲基咪唑鎓乙酸酯制成的纤维素膜的分离性能。

IF 3.3 4区 工程技术 Q2 CHEMISTRY, PHYSICAL Membranes Pub Date : 2024-09-23 DOI:10.3390/membranes14090202
Luying Chen, Dooli Kim, Wiebe M de Vos
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引用次数: 0

摘要

纤维素是一种可持续原材料,有望成为膜材料的理想候选材料。在这项工作中,我们采用了由离子液体 1-乙基-3-甲基咪唑醋酸盐([EMIM]OAc)和丙酮组成的共溶剂系统,重点研究了生产纤维素微滤膜的低成本路线。在浇铸溶液中引入丙酮作为助溶剂可以控制粘度,从而显著提高纤维素膜的形态和过滤性能。事实上,使用这种助溶剂可以显著提高透水性,同时保持较高的剔除率。此外,在具有挑战性的水包油乳液过滤过程中,制备的纤维素膜表现出优异的抗污垢性能和通量恢复性能。这些结果凸显了一种制造高性能纤维素膜的可行方法。
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Enhancing the Separation Performance of Cellulose Membranes Fabricated from 1-Ethyl-3-methylimidazolium Acetate by Introducing Acetone as a Co-Solvent.

Cellulose, a sustainable raw material, holds great promise as an ideal candidate for membrane materials. In this work, we focused on establishing a low-cost route for producing cellulose microfiltration membranes by adopting a co-solvent system comprising the ionic liquid 1-ethyl-3-methylimidazolium acetate ([EMIM]OAc) and acetone. The introduction of acetone as a co-solvent into the casting solution allowed control over the viscosity, thereby significantly enhancing the morphologies and filtration performances of the resulting cellulose membranes. Indeed, applying this co-solvent allowed the water permeability to be significantly increased, while maintaining high rejections. Furthermore, the prepared cellulose membrane demonstrated excellent fouling resistance behavior and flux recovery behavior during a challenging oil-in-water emulsion filtration. These results highlight a promising approach to fabricate high-performance cellulose membranes.

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来源期刊
Membranes
Membranes Chemical Engineering-Filtration and Separation
CiteScore
6.10
自引率
16.70%
发文量
1071
审稿时长
11 weeks
期刊介绍: Membranes (ISSN 2077-0375) is an international, peer-reviewed open access journal of separation science and technology. It publishes reviews, research articles, communications and technical notes. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. There is no restriction on the length of the papers. Full experimental and/or methodical details must be provided.
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