{"title":"用于 DSSC 的聚苯乙烯/聚丙烯腈/聚吲哚基准固体电解质:提高效率和稳定性","authors":"Soner Çakar , Cengiz Soykan , Mahmut Özacar","doi":"10.1016/j.materresbull.2024.113108","DOIUrl":null,"url":null,"abstract":"<div><div>Recently, the utilization of quasi solid electrolytes has increased to overcome the stability and leakage issues caused by using liquid electrolytes in dye-sensitized solar cells. For this purpose, the novel different amounts of polystyrene/polyacrylonitrile/polyindole based quasi solid electrolytes were prepared and characterized via FTIR, GPC, TGA, DSC and electrochemical procedures. We aimed to develop conductive polymer-based solid electrolytes to be used in DSSCs to improve both solar cell conversion efficiency and stability. The conversion efficiency value of the solar cell using semi-solid electrolyte (PC4) boosted (9.91%) compared to the one using liquid electrolyte (9.74%). Additionally, the solar cells’ stabilities prepared with quasi solid electrolytes are two times higher than solar cells including liquid electrolytes. Therefore, in this study, the potentials of using conductive polymer-based quasi solid electrolytes in DSSCs were investigated and promising results were acquired for future applications.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"181 ","pages":"Article 113108"},"PeriodicalIF":5.3000,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Polystyrene/Polyacrylonitrile/Polyindole based quasi solid electrolytes for DSSCs: Boosting both efficiency and stability\",\"authors\":\"Soner Çakar , Cengiz Soykan , Mahmut Özacar\",\"doi\":\"10.1016/j.materresbull.2024.113108\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Recently, the utilization of quasi solid electrolytes has increased to overcome the stability and leakage issues caused by using liquid electrolytes in dye-sensitized solar cells. For this purpose, the novel different amounts of polystyrene/polyacrylonitrile/polyindole based quasi solid electrolytes were prepared and characterized via FTIR, GPC, TGA, DSC and electrochemical procedures. We aimed to develop conductive polymer-based solid electrolytes to be used in DSSCs to improve both solar cell conversion efficiency and stability. The conversion efficiency value of the solar cell using semi-solid electrolyte (PC4) boosted (9.91%) compared to the one using liquid electrolyte (9.74%). Additionally, the solar cells’ stabilities prepared with quasi solid electrolytes are two times higher than solar cells including liquid electrolytes. Therefore, in this study, the potentials of using conductive polymer-based quasi solid electrolytes in DSSCs were investigated and promising results were acquired for future applications.</div></div>\",\"PeriodicalId\":18265,\"journal\":{\"name\":\"Materials Research Bulletin\",\"volume\":\"181 \",\"pages\":\"Article 113108\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2024-09-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Research Bulletin\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0025540824004392\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Research Bulletin","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0025540824004392","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Polystyrene/Polyacrylonitrile/Polyindole based quasi solid electrolytes for DSSCs: Boosting both efficiency and stability
Recently, the utilization of quasi solid electrolytes has increased to overcome the stability and leakage issues caused by using liquid electrolytes in dye-sensitized solar cells. For this purpose, the novel different amounts of polystyrene/polyacrylonitrile/polyindole based quasi solid electrolytes were prepared and characterized via FTIR, GPC, TGA, DSC and electrochemical procedures. We aimed to develop conductive polymer-based solid electrolytes to be used in DSSCs to improve both solar cell conversion efficiency and stability. The conversion efficiency value of the solar cell using semi-solid electrolyte (PC4) boosted (9.91%) compared to the one using liquid electrolyte (9.74%). Additionally, the solar cells’ stabilities prepared with quasi solid electrolytes are two times higher than solar cells including liquid electrolytes. Therefore, in this study, the potentials of using conductive polymer-based quasi solid electrolytes in DSSCs were investigated and promising results were acquired for future applications.
期刊介绍:
Materials Research Bulletin is an international journal reporting high-impact research on processing-structure-property relationships in functional materials and nanomaterials with interesting electronic, magnetic, optical, thermal, mechanical or catalytic properties. Papers purely on thermodynamics or theoretical calculations (e.g., density functional theory) do not fall within the scope of the journal unless they also demonstrate a clear link to physical properties. Topics covered include functional materials (e.g., dielectrics, pyroelectrics, piezoelectrics, ferroelectrics, relaxors, thermoelectrics, etc.); electrochemistry and solid-state ionics (e.g., photovoltaics, batteries, sensors, and fuel cells); nanomaterials, graphene, and nanocomposites; luminescence and photocatalysis; crystal-structure and defect-structure analysis; novel electronics; non-crystalline solids; flexible electronics; protein-material interactions; and polymeric ion-exchange membranes.