位错对低硫化氢酸性环境下碳钢酸蚀的影响

I. Samusawa, D. Izumi, J. Shimamura
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引用次数: 3

摘要

本文研究了位错对低硫化氢酸腐蚀环境下低合金钢腐蚀的影响,包括浸没腐蚀试验和极化测量,以及ESM - RISM模拟。结果表明,位错通过促进阳极溶解反应来增加腐蚀失重。对两种模拟有/无晶格缺陷条件的铁板模型的铁原子溶解度进行了评价,阐明了有晶格缺陷模型的高铁溶解度。基于这些实验和理论结果,讨论了位错影响阳极溶解的机理。
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Influence of dislocation on sour corrosion of carbon steel in a low H2S sour environment
The influence of dislocation on corrosion of low alloy steel in a low H2S sour corrosion environment was investigated experimentally (immersion corrosion test and polarization measurement) and theoretically (ESM‐RISM simulation). The results showed that dislocation increases corrosion weight loss by promoting the anodic dissolution reaction. The Fe atom solubilities of two kinds of Fe slab models simulating conditions with/without lattice defects were evaluated, and the high Fe solubility of the model with lattice defects was clarified. Based on these experimental and theoretical findings, the mechanism by which dislocation influences anodic dissolution was discussed.
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