金属间化合物生长对低轮廓焊点电迁移失效机制的影响

H. Madanipour, Y. Kim, C. Kim, N. Shahane, D. Mishra, L. Nguyen
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引用次数: 2

摘要

本文描述了电迁移(EM)失效的动力学和微观结构机制,发现在低轮廓焊点中,EM和金属间相形成竞争相同体积的锡。在我们的研究中使用的低轮廓焊点是由20-25um厚的焊料制成的,位于铜柱和Ni涂层铜引线框架(LF)之间。样品在140-170℃的温度范围内,在油浴中进行电磁测试,电流密度在35-45 KA/cm2之间变化,以诱导失效,无焦耳热诱发伪影。我们对电磁破坏动力学和微观结构机制的研究产生了两个关键发现。第一个发现表明,钎料基体中扩散物质(Sn, Ni, Cu)的EM扩散率(Z*D)可以通过显微结构分析进行唯一排序,估计为(Z*D) Cu> (Z*D) Sn>(Z*D) Ni。EM扩散率的差异导致Cu-Sn和Ni-Sn金属间化合物(IMC)在EM下以不同的方式发展,从而导致不同的EM破坏机制。第二个发现是,低轮廓焊点中的电磁包括多个失效阶段:a)在较低温度下,Sn中的电磁相关空洞占主导地位;b)高温下热诱导的IMC生长和侵入与em诱导的Sn空洞竞争,导致每个节理完全失效。
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Effect of Intermetallic Compound Growth on Electromigration Failure Mechanism in Low-Profile Solder Joints
This paper describes the kinetic and microstructural mechanism of electromigration (EM) failure found in low-profile solder joints where EM and intermetallic phase formation compete for the same volume of Sn. The low-profile solder joint used in our study was made of 20-25um thick solder situated in between a Cu pillar and a Ni coated Cu lead frame (LF). The samples were EM tested in a temperature range of 140-170oC with the current densities varying between 35-45 KA/cm2 in an oil bath to induce failure without Joule Heat induced artifacts. Our studies on EM failure kinetics and microstructural mechanism have produced two key findings. The first finding suggests that the EM diffusivity (Z*D) of diffusing species (Sn, Ni, Cu) in the solder matrix can be uniquely ranked from microstructural analysis, and it is estimated to be (Z*D) Cu> (Z*D) Sn>(Z*D) Ni. This difference in EM diffusivity causes Cu-Sn and Ni-Sn intermetallic compounds (IMC) to develop in distinctively different manners under EM, leading to different EM failure mechanisms. The second finding is that EM in low-profile solder joints consists of multiple failure stages: a) with EM-related voiding in Sn dominating at lower temperatures; while b) thermally-induced IMC growth and invasion competes with EM-induced Sn voiding at high temperatures leading to the complete failure of each joint.
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