水性阻燃交联聚乙烯绝缘材料的研究

T. Kawashima, T. Maki, T. Takahashi, K. Maeda
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引用次数: 7

摘要

采用两种类型的聚乙烯对水性阻燃XLPE进行了评估:一种是含有极性共聚物的聚合物共混XLPE,另一种是极低密度聚乙烯(VLDPE),这是一种新型聚乙烯。由于聚合物共混XLPE的基础材料是传统的XLPE,因此它可以在与传统XLPE相同的条件下挤出电缆,但VLDPE很难挤出,因此必须改变挤出条件。采用电缆样品(绝缘厚度为3mm)进行的水树加速试验(10 kV, 1 kHz,导体和护套内部浇水,90℃热循环)表明,聚合物共混XLPE的水树阻燃效果优于常规XLPE,即与常规XLPE相比,水树(结带树)生成约为1/30,水树最大长度约为1/2。此外,测试显示,VLDPE中没有产生领结树,证明了几乎完全的水树阻燃效果。
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Study on water treeing retardant XLPE insulations
Water-tree-retardant XLPE was evaluated using two types of polyethylene: a polymer-blend XLPE containing blends of ethylene copolymer having a polar group, and VLDPE (very low density polyethylene), which is a novel grade of polyethylene. While the polymer blend XLPE permitted cable extrusion under the same conditions as in the case of conventional XLPE because its base material is conventional XLPE, the VLDPE was so difficult to extrude that the extruding conditions had to be modified. The water-tree acceleration test (10 kV, 1 kHz, conductor and inside of jacket poured with water, 90 degrees C heat cycle) using the cable samples (insulation thickness of 3 mm) demonstrated a water-tree retardant effect in favor of the polymer blend XLPE, that is, about 1/30 of the water-tree (bow-tie tree) generation and 1/2 of the maximum length of the water tree as compared with conventional XLPE. Furthermore, the test revealed no generation of bow-tie trees in the VLDPE, demonstrating an almost complete water-tree retardant effect.<>
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