纳米二氧化硅替代对混凝土抗压强度的影响

Dr. Anil Kumar Singh, Chaitanya Chauhan
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摘要

在本工作中,我们研究了二氧化硅纳米颗粒(SNPs)替代水泥对超声脉冲速度和混凝土试件抗压强度的影响。我们还得到了超声脉冲速度(UPV)与抗压强度的相关性。二氧化硅纳米颗粒的平均粒径为20nm。通过测量超声脉冲速度(UPV, m/s)和抗压强度(N/mm2)来评价混凝土试件的质量。当SNPs含量为0%、0.5%、1.0%、1.5%、2.0%和2.5%时,养护第7天的UPV平均值分别为3200±36、3215±42、3290±41、3349±24、3450±17和3456±12。相同SNPs替换量下,第28天的UPV平均值分别为3540±36、3580±38、3696±42、3820±39、4160±40、4163±41。可以观察到,用二氧化硅纳米颗粒代替的样品(按水泥重量计)的UPV更高,并且在接近2%(即在2.0-2.5%之间)时达到最大强度。第7天的平均抗压强度分别为25、25、27.6、30、32.4和32 N/mm2,而第28天,相同二氧化硅纳米颗粒含量(0%、0.5%、1.0%、1.5%、2.0%和2.5%)的平均抗压强度分别为38、38.5、40、42、48.5和48.8 N/mm2。随着UPV的增加,抗压强度也随之增加。我们观察到USV与抗压强度和方差之间有很强的相关性(相关系数为0.997)(R2 = 0.87),这意味着获得抗压强度的试件在第28天的USV变化可以解释87%的抗压强度变化。水化反应导致C-S-H(水合硅酸钙)凝胶形成,填满混凝土基体孔隙,增加了混凝土的抗压强度和USV。在选择的掺量范围内(1.5 ~ 2.5%),随着纳米二氧化硅掺量的增加,混凝土的抗压强度显著提高,但可能由于纳米二氧化硅的团聚破坏了纳米二氧化硅的显著特性而存在一定的局限性。
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Impact of Substitution of Silica Nanoparticles on Compressive Strength of Concrete
In present work, we studied the effect of substitution of silica nanoparticles (SNPs), by replacement of cement on ultrasound pulse velocity and compressive strength of concrete specimens. We also obtained correlation between ultrasound pulse velocity (UPV) and the compressive strength. The mean particle size of silica nano-particle was 20nm. The quality of concrete specimen was assessed by measuring ultrasound pulse velocity (UPV) in m/s and compressive strength (N/mm2). The average value of UPV on 7th day of curing turned out to become 3200 ± 36, 3215 ± 42, 3290 ± 41, 3349 ± 24, 3450±17 and 3456 ± 12 for 0%, 0.5%, 1.0%, 1.5%, 2.0% and 2.5% content of SNPs in the specimens respectively. Similarly, the average value of UPV on 28th day was 3540 ± 36, 3580 ± 38, 3696 ± 42, 3820 ± 39, 4160 ± 40, 4163 ± 41 for same amount of substitution of SNPs respectively. It had been observed that the UPV was higher in the specimens replaced by silica nano-particles (by weight of cement) and it achieved maximum strength at nearly 2% (that is in between 2.0-2.5%). The average compressive strength on 7th day was 25, 25, 27.6, 30, 32.4 and 32 N/mm2, but, on 28th day the it increased up to 38, 38.5, 40, 42, 48.5 and 48.8 N/mm2 for the same content of silica nanoparticles ( 0%, 0.5%, 1.0%, 1.5%, 2.0% and 2.5%) respectively. As UPV increased so did the compressive strength. We observed strong correlation (correlation coefficient 0.997) between USV and compressive strength and variance (R2 = 0.87), which meant 87% of variation of compressive strength could be explained by variation of USV for the specimens (which acquired its compressive strength) on 28th day. Compressive strength and USV increased due to hydration reaction leading to C-S-H (Calcium-Silicate-hydrate) gel formation which filled the pores in the concrete matrix. The compressive strength of concrete significantly increased with content of silica nano-particles within the selected range of content (1.5-2.5%), but there is limitation probably due to agglomeration of nanoparticles, which destroyed the salient features nano-particles.
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