ZnSe中间层CuInSe/ sub2 /太阳能电池的制备及性能研究

Ji-Beom Yoo, A. Fahrenbruch, R. Bube
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引用次数: 2

摘要

以CdS和In/sub 2/O/sub 3/作为窗口层,采用热蒸发法制备了CuInSe/sub 2/基太阳能电池,窗口层与CuInSe/sub 2/之间有一层薄薄的ZnSe层。研究了ZnSe厚度在200aa ~ 2000aa之间,ZnSe沉积温度在100℃~ 200℃之间的影响。对于CdS:In/CdS/ZnSe/CuInSe/sub 2/电池,随着ZnSe厚度的增加,J/sub 0/减小和/或二极管因子A增加。对于In/sub 2/O/sub 3//ZnSe/CuInSe/sub 2/电池,J/sub 0/的变化要小得多,而随着ZnSe厚度的增加,二极管系数也有所增加。光照下,添加ZnSe和不添加ZnSe时,电池的V/sub / oc值相同,且ZnSe层厚度大于400 AA的电池表现出较强的光抑制作用。
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Preparation and properties of CuInSe/sub 2/ solar cells with a ZnSe intermediate layer
CuInSe/sub 2/-based solar cells were prepared by thermal evaporation using CdS and In/sub 2/O/sub 3/ as window layers, with a thin ZnSe layer between the window layer and the CuInSe/sub 2/. The effects of ZnSe with thicknesses between 200 AA and 2000 AA and ZnSe deposition temperatures between 100 degrees C and 200 degrees C were investigated. For the CdS:In/CdS/ZnSe/CuInSe/sub 2/ cells, as the ZnSe thickness increases, J/sub 0/ decreases and/or the diode factor A increases. For the In/sub 2/O/sub 3//ZnSe/CuInSe/sub 2/ cells the change of J/sub 0/ is much less and there is an increase in the diode factor for increasing ZnSe thickness. Under illumination, the V/sub oc/ of the cell is the same with and without ZnSe and the cells with ZnSe layers thicker than 400 AA show strong photosuppression.<>
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