Direct deposition of Cu/barrier stacks on dielectric/nonconductive layers using supercritical CO/sub 2/

E. Kondoh, M. Hishikawa, M. Yanagihara, K. Shigama
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引用次数: 1

Abstract

Metallization in supercritical CO/sub 2/ (scCO/sub 2/) is a method to form nano-interconnects for future generation LSIs. It has been recognized that metal layers, Cu for instance, grow only on conductive layers thus requires an underlayer or 'activation' treatment to promote nucleation. Such a layer is formed by a conventional way, which may limit the potential of scCO/sub 2/ deposition. The keys to solve this issues are: 1) to develop a way to deposit a conductive barrier layer, and 2) to develop a proper chemistry to deposit the barrier layer directly on dielectric/nonconductive layers from scCO/sub 2/. The focus of this work is to form Cu/barrier stacks on dielectric layers using only scCO/sub 2/.
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用超临界CO/sub / 2/直接沉积Cu/势垒堆在介电/非导电层上
超临界CO/sub - 2/ (scCO/sub - 2/)金属化是形成未来一代lsi纳米互连的一种方法。人们已经认识到,金属层,例如Cu,只生长在导电层上,因此需要底层或“活化”处理来促进成核。这种层是通过常规的方式形成的,这可能限制了scCO/sub - 2/沉积的潜力。解决这一问题的关键是:1)开发一种沉积导电阻挡层的方法;2)开发一种合适的化学物质,将阻挡层直接沉积在scCO/sub /的介电/非导电层上。本工作的重点是仅使用scCO/sub 2/在介电层上形成Cu/势垒堆栈。
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