Lightweight Materials for High Energy Density Lithium–Sulfur Batteries

IF 26 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Advanced Energy Materials Pub Date : 2025-02-28 DOI:10.1002/aenm.202406069
Yifan Li, Zhengran Wang, Qi Zhang, Kangdong Tian, Junjie Liu, Zhiwei Ni, Fangbing Dong, Shenglin Xiong, Xiaohang Lin, Jinkui Feng
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Abstract

At present, electronic devices such as electric vehicles and mobile phones have increasing requirements for battery energy density. Lithium–sulfur batteries (LSBs) have a high theoretical energy density and are considered a potential choice for realizing the next generation of high energy density (2600 W h kg−1) batteries. However, the actual energy density of LSBs is much lower than the theoretical energy density due to the poor conductivity of sulfur, serious LiPSs shuttle, low sulfur utilization, and so on. Many lightweight materials are characterized by high surface area and designability. The reasonable design of lightweight materials to modify LSBs can reduce the proportion of inactive substances by optimizing electrochemical performance, which is crucial to improving the energy density of LSBs. However, few reviews discuss the effect of lightweight materials on the energy density of LSBs from the perspective of the whole battery system. Herein, the application of lightweight materials in LSBs from six aspects: liquid electrolyte, solid electrolyte, cathode, anode, separator, and current collector is discussed. The significance of reasonable design and use of lightweight materials for the further improvement of the energy density of LSBs is summarized and prospected.

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高能量密度锂硫电池的轻质材料
目前,电动汽车、手机等电子设备对电池能量密度的要求越来越高。锂硫电池(LSBs)具有较高的理论能量密度,被认为是实现下一代高能量密度(2600 W h kg−1)电池的潜在选择。但由于硫的电导率差、lips穿梭严重、硫的利用率低等原因,lsb的实际能量密度远低于理论能量密度。许多轻量化材料的特点是高表面积和可设计性。合理设计轻量化材料对lsdb进行改性,可以通过优化电化学性能来降低非活性物质的比例,这对提高lsdb的能量密度至关重要。然而,很少有文献从整个电池系统的角度讨论轻量化材料对lsdb能量密度的影响。本文从液体电解质、固体电解质、阴极、阳极、分离器和集流器六个方面讨论了轻质材料在lsdb中的应用。总结和展望了合理设计和使用轻量化材料对进一步提高lsdb能量密度的意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Advanced Energy Materials
Advanced Energy Materials CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
41.90
自引率
4.00%
发文量
889
审稿时长
1.4 months
期刊介绍: Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small. With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics. The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.
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