Younsoo Kim, Kyung-Cheol Jeong, J. Joo, Jongee Park, Jun-Sik Lee, Jong-Woo Yoon, J. Roh
{"title":"Growth of RuO/sub x/ thin films by metalorganic chemical vapor deposition","authors":"Younsoo Kim, Kyung-Cheol Jeong, J. Joo, Jongee Park, Jun-Sik Lee, Jong-Woo Yoon, J. Roh","doi":"10.1109/ICVC.1999.820985","DOIUrl":null,"url":null,"abstract":"RuO/sub x/ thin films were deposited on TiN/SiO/sub 2//Si substrates by metal organic chemical vapor deposition (MOCVD) at deposition temperatures of 250/spl deg/C-400/spl deg/ C. We have used Ru(mhd), as a metal organic (MO) source. No films were deposited without the addition of O/sub 2/ gas. RuO/sub 2/ films were deposited at high O/sub 2/ addition. For the deposition of Ru films in the surface reaction controlled region, the activation energy was 0.58 eV. The smooth and well-adherent Ru films had very low resistivities. The microstructure of Ru films was greatly dependent on deposition conditions. Ru films deposited at 27/spl deg/C showed a good step coverage.","PeriodicalId":13415,"journal":{"name":"ICVC '99. 6th International Conference on VLSI and CAD (Cat. No.99EX361)","volume":"9 1","pages":"501-503"},"PeriodicalIF":0.0000,"publicationDate":"1999-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ICVC '99. 6th International Conference on VLSI and CAD (Cat. No.99EX361)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/ICVC.1999.820985","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
RuO/sub x/ thin films were deposited on TiN/SiO/sub 2//Si substrates by metal organic chemical vapor deposition (MOCVD) at deposition temperatures of 250/spl deg/C-400/spl deg/ C. We have used Ru(mhd), as a metal organic (MO) source. No films were deposited without the addition of O/sub 2/ gas. RuO/sub 2/ films were deposited at high O/sub 2/ addition. For the deposition of Ru films in the surface reaction controlled region, the activation energy was 0.58 eV. The smooth and well-adherent Ru films had very low resistivities. The microstructure of Ru films was greatly dependent on deposition conditions. Ru films deposited at 27/spl deg/C showed a good step coverage.