埃米尔-欧仁-伯克

Jaime Wisniak
{"title":"埃米尔-欧仁-伯克","authors":"Jaime Wisniak","doi":"10.22201/fq.18708404e.2023.4.80822","DOIUrl":null,"url":null,"abstract":"Emile-Eugène Burcker (1846-1908) was a French military pharmacist who carried out a successful research program on the application of the Friedel-Crafts method to the synthesis of acids, ketones, aldehydes, and glycols in the aromatic series, which finally culminated in his doctoral thesis. In particular, he was able to synthesize a significant number of new acetonic and ketonic acids characterized by the presence in their molecule of both the carbonyl group CO and the group COOH; thus, having the ability to react as ketones, forming salts, esters, and as ordinary acids, and everything also, under the influence of nascent hydrogen, of forming oxyacids or acid-alcohols. Some new compounds included benzoylpropionic acid, benzhydrylpropionic acid, phenyl propyl acetone, toluylpropionic acid, phenylcamphoric acid, etc. Burcker also established the best procedure for dosing KOH, as well as an improved version of the Kjeldahl method to determine the amount of nitrogen present in organic compounds. @font-face {font-family:\"Cambria Math\"; panose-1:2 4 5 3 5 4 6 3 2 4; mso-font-charset:0; mso-generic-font-family:roman; mso-font-pitch:variable; mso-font-signature:-536870145 1107305727 0 0 415 0;}@font-face {font-family:Calibri; panose-1:2 15 5 2 2 2 4 3 2 4; mso-font-charset:0; mso-generic-font-family:swiss; mso-font-pitch:variable; mso-font-signature:-536859905 -1073732485 9 0 511 0;}p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-unhide:no; mso-style-qformat:yes; mso-style-parent:\"\"; margin:0cm; mso-pagination:widow-orphan; font-size:12.0pt; font-family:\"Calibri\",sans-serif; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:Calibri; mso-fareast-theme-font:minor-latin; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:Arial; mso-bidi-theme-font:minor-bidi;}.MsoChpDefault {mso-style-type:export-only; mso-default-props:yes; font-family:\"Calibri\",sans-serif; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:Calibri; mso-fareast-theme-font:minor-latin; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:Arial; mso-bidi-theme-font:minor-bidi;}div.WordSection1 {page:WordSection1;}","PeriodicalId":273178,"journal":{"name":"Educación Química","volume":"34 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Emile Eugéne Burcker\",\"authors\":\"Jaime Wisniak\",\"doi\":\"10.22201/fq.18708404e.2023.4.80822\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Emile-Eugène Burcker (1846-1908) was a French military pharmacist who carried out a successful research program on the application of the Friedel-Crafts method to the synthesis of acids, ketones, aldehydes, and glycols in the aromatic series, which finally culminated in his doctoral thesis. In particular, he was able to synthesize a significant number of new acetonic and ketonic acids characterized by the presence in their molecule of both the carbonyl group CO and the group COOH; thus, having the ability to react as ketones, forming salts, esters, and as ordinary acids, and everything also, under the influence of nascent hydrogen, of forming oxyacids or acid-alcohols. Some new compounds included benzoylpropionic acid, benzhydrylpropionic acid, phenyl propyl acetone, toluylpropionic acid, phenylcamphoric acid, etc. Burcker also established the best procedure for dosing KOH, as well as an improved version of the Kjeldahl method to determine the amount of nitrogen present in organic compounds. @font-face {font-family:\\\"Cambria Math\\\"; panose-1:2 4 5 3 5 4 6 3 2 4; mso-font-charset:0; mso-generic-font-family:roman; mso-font-pitch:variable; mso-font-signature:-536870145 1107305727 0 0 415 0;}@font-face {font-family:Calibri; panose-1:2 15 5 2 2 2 4 3 2 4; mso-font-charset:0; mso-generic-font-family:swiss; mso-font-pitch:variable; mso-font-signature:-536859905 -1073732485 9 0 511 0;}p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-unhide:no; mso-style-qformat:yes; mso-style-parent:\\\"\\\"; margin:0cm; mso-pagination:widow-orphan; font-size:12.0pt; font-family:\\\"Calibri\\\",sans-serif; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:Calibri; mso-fareast-theme-font:minor-latin; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:Arial; mso-bidi-theme-font:minor-bidi;}.MsoChpDefault {mso-style-type:export-only; mso-default-props:yes; font-family:\\\"Calibri\\\",sans-serif; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:Calibri; mso-fareast-theme-font:minor-latin; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:Arial; mso-bidi-theme-font:minor-bidi;}div.WordSection1 {page:WordSection1;}\",\"PeriodicalId\":273178,\"journal\":{\"name\":\"Educación Química\",\"volume\":\"34 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-10-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Educación Química\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.22201/fq.18708404e.2023.4.80822\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Educación Química","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22201/fq.18708404e.2023.4.80822","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

emile - eug Burcker(1846-1908)是一名法国军事药剂师,他成功地将Friedel-Crafts方法应用于合成芳香系列中的酸、酮、醛和乙二醇,并最终完成了他的博士论文。特别是,他能够合成大量新的丙酮酸和酮酸,其特征是在它们的分子中同时存在羰基CO和COOH;因此,有能力反应成酮,形成盐,酯,和作为普通酸,以及一切,在新生氢的影响下,形成氧酸或酸醇。新发现的化合物有苯甲酰丙酸、苯羟丙酸、苯丙丙酮、甲苯丙酸、苯樟脑酸等。Burcker还建立了KOH加药的最佳程序,以及凯氏定氮法的改进版本,以确定有机化合物中存在的氮量。@font-face {font-family:"剑桥数学";Panose-1:2 4 5 3 5 4 6 3 2 4 4;mso-font-charset: 0;mso-generic-font-family:罗马;mso-font-pitch:变量;mso-font-signature:-536870145 1107305727 0 0 415 0;潘诺斯-1:2 15 5 2 2 2 2 4 3 2 4;mso-font-charset: 0;mso-generic-font-family:瑞士;mso-font-pitch:变量;Mso-font-signature:-536859905 -1073732485 90 511 0;MsoNormal,李。msonnormal, div. msonnormal {mso-style-unhide:no;mso-style-qformat:是的;mso-style-parent:“”;保证金:0厘米;mso-pagination: widow-orphan;字体大小:12.0分;无衬线字体类型:“Calibri”;mso-ascii-font-family: Calibri;mso-ascii-theme-font: minor-latin;mso-fareast-font-family: Calibri;mso-fareast-theme-font: minor-latin;mso-hansi-font-family: Calibri;mso-hansi-theme-font: minor-latin;mso-bidi-font-family: Arial;mso-bidi-theme-font: minor-bidi;}。MsoChpDefault {mso-style-type:仅供出口的;mso-default-props:是的;无衬线字体类型:“Calibri”;mso-ascii-font-family: Calibri;mso-ascii-theme-font: minor-latin;mso-fareast-font-family: Calibri;mso-fareast-theme-font: minor-latin;mso-hansi-font-family: Calibri;mso-hansi-theme-font: minor-latin;mso-bidi-font-family: Arial;mso-bidi-theme-font: minor-bidi;} div。WordSection1{页面:WordSection1;}
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Emile Eugéne Burcker
Emile-Eugène Burcker (1846-1908) was a French military pharmacist who carried out a successful research program on the application of the Friedel-Crafts method to the synthesis of acids, ketones, aldehydes, and glycols in the aromatic series, which finally culminated in his doctoral thesis. In particular, he was able to synthesize a significant number of new acetonic and ketonic acids characterized by the presence in their molecule of both the carbonyl group CO and the group COOH; thus, having the ability to react as ketones, forming salts, esters, and as ordinary acids, and everything also, under the influence of nascent hydrogen, of forming oxyacids or acid-alcohols. Some new compounds included benzoylpropionic acid, benzhydrylpropionic acid, phenyl propyl acetone, toluylpropionic acid, phenylcamphoric acid, etc. Burcker also established the best procedure for dosing KOH, as well as an improved version of the Kjeldahl method to determine the amount of nitrogen present in organic compounds. @font-face {font-family:"Cambria Math"; panose-1:2 4 5 3 5 4 6 3 2 4; mso-font-charset:0; mso-generic-font-family:roman; mso-font-pitch:variable; mso-font-signature:-536870145 1107305727 0 0 415 0;}@font-face {font-family:Calibri; panose-1:2 15 5 2 2 2 4 3 2 4; mso-font-charset:0; mso-generic-font-family:swiss; mso-font-pitch:variable; mso-font-signature:-536859905 -1073732485 9 0 511 0;}p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-unhide:no; mso-style-qformat:yes; mso-style-parent:""; margin:0cm; mso-pagination:widow-orphan; font-size:12.0pt; font-family:"Calibri",sans-serif; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:Calibri; mso-fareast-theme-font:minor-latin; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:Arial; mso-bidi-theme-font:minor-bidi;}.MsoChpDefault {mso-style-type:export-only; mso-default-props:yes; font-family:"Calibri",sans-serif; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:Calibri; mso-fareast-theme-font:minor-latin; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:Arial; mso-bidi-theme-font:minor-bidi;}div.WordSection1 {page:WordSection1;}
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Los niveles de representación como criterio de selección para textos escolares de química Análisis de la interrelación de los contenidos temáticos de las asignaturas Procesos de Alimentos y Laboratorio de Tecnología de Alimentos de la licenciatura en Química de Alimentos Impacto de una estrategia contextualizada en la enseñanza de unidades de masa y volumen Enseñanza-aprendizaje virtual del componente experimental de la Química: una estrategia didáctica Práctica de laboratorio virtual de Química General: ácido-base
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1