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Integrating Passive Biomonitoring and Active Monitoring: Spider Web Silk and Portable Instruments for Air Quality in Urban Areas 被动生物监测与主动监测相结合:用于城市地区空气质量的蜘蛛网丝和便携式仪器
IF 2.52 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-06-26 DOI: 10.1007/s11270-024-07264-5
Amina Muzamil, Khawar Sultan, Abeer Hashem, Graciela Dolores Avila-Quezada, Elsayed Fathi Abd-Allah, Qamar uz Zaman

Urban areas worldwide face significant challenges from increasing air pollution, posing health risks and environmental concerns. Lahore, a major city in Pakistan, is particularly affected by severe air pollution due to rapid industrial growth, high vehicle emissions, and various human activities. Traditional air quality monitoring methods, while effective, are often costly and complex, limiting their widespread use. This study investigates a dual monitoring system combining passive biomonitoring with spider web silk and active measurements using portable instruments to assess airborne pollutants in urban environments. Spider webs, collected from various sites in Lahore, were analyzed for heavy metals, while portable instruments simultaneously measured PM2.5, PM10, total volatile organic contents, formaldehyde, and carbon monoxide at the same locations. A spatial distribution analysis using GIS and statistical analysis revealed a pattern with significant changes as per land use in the urban environment related to anthropogenic activities. The Principal Component Analysis revealed three distinct clusters of pollutants origins consisting of: I) effluent drains and landfills, II) construction sites, and III) residential areas. The concentrations of Hg in spider silk (average ~ 2.66 mg/kg) were found to be significantly higher in the northeastern part of Lahore, with a similar trend observed in Cd, Cu, Ni, and As levels (average ~ 15.45, 102.87, 31.72, and 6.64, respectively). Several-fold changes in levels and spatial distribution of Pb (15.12 to 356.41 mg/kg) showed a higher concentration in the northern and northeastern parts of Lahore. The spatial variation pattern of Cr (average~ 57.04 mg/kg) registered a higher concentration in southwestern Lahore. Ambient air levels of measured pollutants followed almost similar patterns in spatial distribution. PM2.5 and PM10 measured higher levels (195 and 226 μg/m3, respectively) in the southwestern and northwestern areas, with a similar pattern of variation observed in TVOC (average ~ 0.14 μg/m3). The concentration of HCHO (average ~ 0.003 μg/m3) was higher in the southwest of Lahore. All measured pollutants registered higher values than air quality standards. Particulate matter is the most dominant pollutant contributing to air pollution (up to 20x higher than WHO guidelines). The findings support the use of a dual monitoring system, integrating passive spider web silk biomonitoring and active portable instruments, as a scalable and sustainable solution for air quality management. This approach holds potential for global application in diverse urban environments, with future research focusing on further validation and integration with advanced remote sensing technologies to enhance air quality monitoring and contribute to improved public health and environmental management worldwide. Hence, this research work points to the pote

全世界的城市地区都面临着空气污染日益严重的严峻挑战,给人们带来了健康风险和环境问题。拉合尔是巴基斯坦的一个主要城市,由于工业发展迅速、汽车尾气排放量大以及各种人类活动,该市尤其受到严重空气污染的影响。传统的空气质量监测方法虽然有效,但往往成本高昂且复杂,限制了其广泛应用。本研究调查了一种双重监测系统,该系统结合了利用蜘蛛网丝进行的被动生物监测和利用便携式仪器进行的主动测量,以评估城市环境中的空气传播污染物。对从拉合尔不同地点收集的蜘蛛网进行了重金属分析,便携式仪器同时测量了同一地点的 PM2.5、PM10、总挥发性有机物含量、甲醛和一氧化碳。利用地理信息系统和统计分析进行的空间分布分析表明,城市环境中与人为活动有关的土地利用模式发生了显著变化。主成分分析显示,污染物来源有三个不同的群组,包括I) 污水排水沟和垃圾填埋场;II) 建筑工地;III) 居民区。在拉合尔东北部,蛛丝中的汞浓度(平均约为 2.66 毫克/千克)明显较高,镉、铜、镍和砷的浓度(平均分别约为 15.45、102.87、31.72 和 6.64)也呈类似趋势。铅(15.12 至 356.41 毫克/千克)含量和空间分布的数倍变化表明,拉合尔北部和东北部地区的铅浓度较高。铬(平均~ 57.04 毫克/千克)在拉合尔西南部的浓度较高。环境空气中测量到的污染物水平在空间分布上几乎遵循相似的模式。西南部和西北部地区 PM2.5 和 PM10 含量较高(分别为 195 微克/立方米和 226 微克/立方米),TVOC(平均值~ 0.14 微克/立方米)的变化模式与此类似。拉合尔西南部的 HCHO 浓度较高(平均约为 0.003 微克/立方米)。所有测得的污染物值均高于空气质量标准。颗粒物是造成空气污染的最主要污染物(比世界卫生组织的标准高出 20 倍)。研究结果支持使用双重监测系统,将被动式蛛网丝生物监测和主动式便携仪器结合起来,作为空气质量管理的一种可扩展和可持续的解决方案。这种方法具有在全球各种城市环境中应用的潜力,未来的研究重点是进一步验证和整合先进的遥感技术,以加强空气质量监测,为改善全球公共卫生和环境管理做出贡献。因此,这项研究工作指出了蜘蛛丝作为生物监测工具与环境空气污染物仪器测量相结合的潜在用途。
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引用次数: 0
Impacts of Different Sizes and Concentrations of Polyethylene on Chemical, Physical, Mechanical, and Biological Properties in a Loess Soil 不同大小和浓度的聚乙烯对黄土中化学、物理、机械和生物特性的影响
IF 2.52 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-06-26 DOI: 10.1007/s11270-024-07297-w
Rozhin Sarlak, Soheila Ebrahimi, Elham Malekzadeh, Seyed Ali Reza Movahedi Naeini

Microplastics (MPs) are greatly released into soils in different ways, specifically through mulching practices in irrigated loess soils in northern Iran as the fertile and susceptible soils to water erosion. This study was conducted to examine the effects of Polyethylene (PE) (a common kind of MPs used in mulching farming in loess soils of north Iran), in a Loess soil under an experimental study. A loess soil was collected from 0- 30 cm surface and incubated at two levels of PE (2.5 and 5 % by weight) in two sizes (1-2 mm and >2mm) for 60 days, at 70% of field capacity moisture and temperature of 25-28 ° C. Soils samples were collected in 1, 15, 30, 45 and 60 days after incubation and different soil chemical, physical, mechanical and biological properties were measured. The results showed that soil pH was significantly (P<0.05) reduced by timing (time after incubation), and application rate of MPs. Inclusion of MPs led to increasing bulk density significantly (P<0.05) and also led to reducing aggregation and mean weight diameter (MWD) compared to control soil. The rate of MWD decreasing varied from 79 % to 87 % in different rates of MPs application. Among the mechanical attributes, liquid limit, plastic limit, and plastic index, all were reduced significantly (P<0.05) after mixing up and incubation with MPs. Reducing aggregation and aeration in treated soils compared to control soils, led to lowering soil microbial respiration, especially with timing. As our results about the effects of MPs in loess soils in a few cases were contrary to other soils studied worldwide, further studies are recommended to perform in loess soils in northern Iran, where receive considerable MPs by farming and open landfill practices in the studied region.

微塑料(MPs)以不同的方式大量释放到土壤中,特别是通过在伊朗北部肥沃且易受水流侵蚀的黄土灌溉土壤中进行地膜覆盖。本研究旨在通过实验研究聚乙烯(PE)(一种在伊朗北部黄土覆盖耕作中常用的 MPs)对黄土土壤的影响。从 0-30 厘米表层采集黄土,在两种规格(1-2 毫米和 2 毫米)的聚乙烯含量(2.5%和 5%(重量百分比))条件下培养 60 天,培养温度为 25-28 ° C,湿度为田间容重的 70%。培养后 1、15、30、45 和 60 天采集土壤样本,测量不同的土壤化学、物理、机械和生物特性。结果表明,土壤的 pH 值随着时间(培养后的时间)和 MPs 施用量的增加而显著降低(P<0.05)。与对照土壤相比,添加 MPs 能显著提高容重(P<0.05),还能减少团聚和平均重量直径(MWD)。在不同的 MPs 施用量下,平均重量直径的减小率从 79% 到 87% 不等。在机械属性方面,混合和培养 MPs 后,液限、塑限和塑性指数均显著降低(P<0.05)。与对照土壤相比,处理过的土壤的团聚性和通气性降低,导致土壤微生物呼吸作用降低,尤其是随着时间的推移。由于我们关于 MPs 在黄土中的影响的研究结果在少数情况下与世界范围内研究的其他土壤相反,因此建议对伊朗北部的黄土进行进一步的研究,因为在研究地区的耕作和露天垃圾填埋做法会使黄土受到大量 MPs 的影响。
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引用次数: 0
Emerging investigator series: quantitative insights into the relationship between the concentrations and SERS intensities of neonicotinoids in water 新晋研究人员系列:对水中新烟碱浓度与 SERS 强度之间关系的定量研究
IF 8.131 2区 环境科学与生态学 Q1 Environmental Science Pub Date : 2024-06-26 DOI: 10.1039/d4en00221k
Shengdong Liu, James Lazarcik, Haoran Wei
This study explores the theoretical foundation behind the application of surface-enhanced Raman spectroscopy (SERS) for neonicotinoid quantification. Our findings demonstrate that SERS intensities are determined by the thermodynamic adsorption behaviors of neonicotinoid molecules transitioning from aqueous phases to gold nanoparticle (AuNP) surfaces. The dynamic ranges and limits of detection can be accurately predicted by classic adsorption isotherms.
本研究探讨了应用表面增强拉曼光谱(SERS)进行新烟碱定量背后的理论基础。我们的研究结果表明,SERS 强度是由新烟碱分子从水相过渡到金纳米粒子(AuNP)表面的热力学吸附行为决定的。经典的吸附等温线可以准确预测动态范围和检测限。
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引用次数: 0
Nano-TiO2 immobilized Polyvinylidene fluoride based spongy-spheres: Ciprofloxacin photocatalytic degradation with antibacterial activity removal, mechanism, UVA LED irradiation and easy recovery 纳米二氧化钛固定聚偏氟乙烯海绵球:具有抗菌活性的环丙沙星光催化降解去除、机理、UVA LED 照射和易于回收
IF 8.131 2区 环境科学与生态学 Q1 Environmental Science Pub Date : 2024-06-25 DOI: 10.1039/d4en00302k
Laxman Raikar, Atul Patel, Jemi Gandhi, KVK Gupta, Halan Prakash
TiO2 is promising for photocatalytic treatment of water contaminated with organic micropollutants. However, it is hard to recover TiO2 slurry from water. Energy intensive separation methods are required to recover TiO2, which is a setback for effective usage of TiO2 for water treatment. Herein, we present nano-TiO2 immobilized with Polyvinylidene fluoride spongy beads (TP) by simple phase inversion of mixture of TiO2 (1 %), PVDF (13 %) and PVP (0.7 %), for degradation of Ciprofloxacin (CIP), a micropollutant in water under UVA LED irradiation with easy TP recovery. Stable immobilization of TiO2 with PVDF beads is attributed to interactions between Ti-F atoms. Pseudo first order rate constant value (kobs = 0.0761 min-1) was determined for degradation of CIP by TP. Radical scavenging, chronoamperometry and ESR analysis revealed the presence of O2-•, h+, HO and 1O2 reactive species. LC-HRMS analysis detected ten degradation byproducts with plausible degradation pathways. Importantly, antibacterial activity of CIP against Bacillus subtilis and Escherichia coli was totally removed after 60 min treatment. TP beads were easily recovered by using a simple strainer. TP was recovered and reused 30 times, and no significant TiO2 leaching into water demonstrated its stable immobilization. TP photocatalysis under UVA LED irradiation proves an energy efficient treatment method with electrical energy per order of 24.20 kWh/m3/order. Overall, the study highlights a concrete way to effectively use TiO2 photocatalyst for water treatment by immobilization via a simple phase inversion method.
二氧化钛有望用于光催化处理被有机微污染物污染的水。然而,很难从水中回收二氧化钛浆料。回收二氧化钛需要高能耗的分离方法,这阻碍了二氧化钛在水处理领域的有效应用。在此,我们通过将 TiO2(1%)、PVDF(13%)和 PVP(0.7%)的混合物进行简单的相反转,将纳米 TiO2 与聚偏氟乙烯海绵状微珠(TP)固定在一起,用于在 UVA LED 照射下降解水中的微污染物质环丙沙星(CIP),且 TP 易于回收。TiO2 与 PVDF 珠子的稳定固定是由于 Ti-F 原子间的相互作用。确定了 TP 降解 CIP 的伪一阶速率常数值(kobs = 0.0761 min-1)。自由基清除、计时器和 ESR 分析表明了 O2-、h+、HO- 和 1O2 活性物种的存在。LC-HRMS 分析检测到了十种降解副产物,其降解途径都是可信的。重要的是,经过 60 分钟处理后,CIP 对枯草杆菌和大肠杆菌的抗菌活性完全消失。使用简单的滤网就能轻松回收 TP 珠。TP 被回收并重复使用了 30 次,TiO2 没有明显浸出到水中,这表明其固定作用非常稳定。在 UVA LED 照射下进行 TP 光催化是一种高效节能的处理方法,每阶电能为 24.20 kWh/m3/阶。总之,该研究强调了一种通过简单的相反转方法固定二氧化钛光催化剂,从而有效利用其进行水处理的具体方法。
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引用次数: 0
Diatom-Derived Extracellular Polymeric Substances Form Eco-corona and Enhance Stability of Silver Nanoparticles 硅藻细胞外高分子物质形成生态电晕并增强银纳米粒子的稳定性
IF 8.131 2区 环境科学与生态学 Q1 Environmental Science Pub Date : 2024-06-25 DOI: 10.1039/d4en00232f
Rocco Gasco, Isabelle A. M. Worms, Arin Kantarciyan, Vera I Slaveykova
Silver nanoparticles (nAg) are extensively used across various fields and are frequently introduced into aquatic environments, where their behavior depends on environmental conditions. Extracellular polymeric substances (EPS) derived from aquatic organisms, such as diatoms, could play an important yet to be explored role in shaping the fate of nAg in aquatic environment. This study investigates the interactions between EPS, particularly those from the diatom Cyclotella meneghiniana, and citrate-coated nAg. The main objective is to understand how EPS influence the behaviours of nAg in freshwater settings, in terms of modulation of the nAg surface properties, colloidal stability and dissolution. To achieve these objectives a combination of the state-of-the-art spectroscopic and imaging techniques was employed. nAg was incubated with EPS isolated from an axenic C. meneghiniana culture, and their interactions were explored in a simulated freshwater environment over both short-term (0-2 hours) and long-term (0-72 hours) periods. The study focused on the changes in nAg, examining surface modulation, colloidal stability, dissolution, EPS adsorption on nAg, and the resulting ecocorona formation.The results indicate that EPS enhance the colloidal stability of nAg and decrease their dissolution in synthetic freshwater by adsorbing onto their surface and inducing steric repulsion between nAg particles. Visualization of the eco-corona formed by diatom EPS on nAg and its impact on aggregation processes is achieved through transmission electron microscopy. The formation of the EPS corona is attributed to the presence of diverse biopolymers within EPS, particularly proteins and polysaccharides. Fluorescence quenching studies on protein fluorophores demonstrate the formation, through hydrophobic interactions, of protein-nAg complex, further confirmed by AF4-DAD-FLD-ICP-MS. In a broader context, the results of this mechanistic study imply that diatoms, through the release of EPS, may significantly influence the destiny and possibly the bioavailability of nAg in EPS-abundant aquatic environments.
纳米银(nAg)被广泛应用于各个领域,并经常被引入水生环境,其行为取决于环境条件。来自硅藻等水生生物的胞外高分子物质(EPS)在影响 nAg 在水生环境中的归宿方面可能发挥着重要作用,但这一作用尚待探索。本研究调查了 EPS(尤其是硅藻 Cyclotella meneghiniana 中的 EPS)与柠檬酸盐涂层 nAg 之间的相互作用。主要目的是了解 EPS 如何在调节 nAg 表面特性、胶体稳定性和溶解性方面影响 nAg 在淡水环境中的行为。将 nAg 与从 C. meneghiniana 轴向培养物中分离出来的 EPS 一起培养,并在模拟淡水环境中探索它们在短期(0-2 小时)和长期(0-72 小时)内的相互作用。结果表明,EPS 通过吸附在 nAg 表面和诱导 nAg 颗粒之间的立体排斥,增强了 nAg 的胶体稳定性,并降低了它们在合成淡水中的溶解度。通过透射电子显微镜,可以观察到硅藻 EPS 在 nAg 上形成的生态电晕及其对聚集过程的影响。EPS 电晕的形成是由于 EPS 中存在多种生物聚合物,特别是蛋白质和多糖。对蛋白质荧光团的荧光淬灭研究表明,通过疏水相互作用,形成了蛋白质-银复合物,AF4-DAD-FLD-ICP-MS 进一步证实了这一点。从更广泛的角度来看,这项机理研究的结果表明,硅藻通过释放 EPS,可能会极大地影响 EPS 丰富的水生环境中 nAg 的去向,甚至可能影响其生物利用率。
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引用次数: 0
About the Sorption of P(v) on Fe(iii) Oxyhydroxides: Comments and Corrections to the Paper by Xu, Zhu and Xiong [Water, Air & Soil Pollution 233:454 (2022)] 关于 P(v) 在 Fe(iii) 氧氢氧化物上的吸附:对 Xu、Zhu 和 Xiong 论文的评论和更正 [水、空气和土壤污染 233:454 (2022)]
IF 2.52 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-06-25 DOI: 10.1007/s11270-024-07241-y
Véronique Deluchat, Jean-Claude Bollinger
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引用次数: 0
Optimizing benefit-risk trade-off in nano-agrochemicals through explainable machine learning: Beyond concentration 通过可解释的机器学习优化纳米农用化学品的效益与风险权衡:超越浓度
IF 8.131 2区 环境科学与生态学 Q1 Environmental Science Pub Date : 2024-06-25 DOI: 10.1039/d4en00213j
Hengjie Yu, Shiyu Tang, Eslam Hamed, Sam Fong Yau Li, Yaochu Jin, Fang Cheng
Balancing the benefits and undesirable environmental impacts is essential for ensuring successful applications of emerging nano-agrochemicals. However, there is a lack of transparent and explainable trade-off methodologies in this safety-sensitive field. Here, an explainable machine learning-driven multi-objective optimization approach is proposed to maximize the performance and minimize undesirable implications of seed nanopriming. The root dry weight under salinity stress and the relative concentration of the constituent elements of used nanoparticles in shoots are considered prospective indicators of the benefit and risk, respectively. An ensemble strategy of model explanation, based on self-explainable models, is employed to obtain more reliable, unbiased, and trustworthy results with small datasets. Multi-objective optimization is employed to select potential treatments among numerous generated candidates based on the predictions of explainable machine learning models. Furthermore, model explanations are combined with prior knowledge to explain this selection process and elucidate the factors’ effects on the benefit and risk. The explanation results highlight the importance of considering the well-known concentration-dependent effect of nanoparticles in conjunction with other factors such as Zeta potential and surface area, which is further verified by statistical analysis. Together, this study provides a promising approach to accelerating the discovery, assessment, and regulation of nanomaterials and may facilitate their sustainable applications in agriculture and the environment.
平衡效益与不良环境影响对于确保成功应用新兴纳米化学品至关重要。然而,在这一安全敏感领域,缺乏透明、可解释的权衡方法。本文提出了一种可解释的机器学习驱动的多目标优化方法,以最大限度地提高种子纳米处理的性能并减少其不良影响。盐度胁迫下的根系干重和芽中所用纳米粒子成分的相对浓度分别被视为效益和风险的前瞻性指标。在可自我解释模型的基础上,采用了模型解释的集合策略,以便在数据集较小的情况下获得更可靠、无偏见和可信的结果。根据可解释机器学习模型的预测结果,采用多目标优化方法从众多生成的候选模型中选择潜在的治疗方法。此外,模型解释与先验知识相结合,解释了这一选择过程,并阐明了各种因素对收益和风险的影响。解释结果强调了将众所周知的纳米粒子浓度依赖效应与 Zeta 电位和表面积等其他因素结合起来考虑的重要性,这一点通过统计分析得到了进一步验证。总之,这项研究为加快纳米材料的发现、评估和监管提供了一种很有前景的方法,可促进纳米材料在农业和环境中的可持续应用。
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引用次数: 0
Exploring the Role of Shrubs in Modulating Heavy Metal Accumulation in Forest Soils in Single-Species Pine Stands 探索灌木在调节单一树种松树林土壤重金属积累中的作用
IF 2.52 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-06-25 DOI: 10.1007/s11270-024-07268-1
Marzena Kaźmierczak, Ewa Błońska, Jarosław Lasota

Heavy metals accumulate and bind strongly in soil, making them difficult to eliminate. The objective of this study was to evaluate the effect of alder buckthorn (Frangula alnus) and European hazelnut (Coryllus avellana) admixtures in pine monocultures on the accumulation and vertical distribution of heavy metals in soil surface horizons. Ten sites each of pine stands admixed with alder buckthorn, pine stands admixed with European hazelnut, and pine monocultures in the Rybnik Forest District in southern Poland were selected for each variant. For the study, soil samples were taken from each site from the organic and mineral horizons and analysed for N and C contents, C/N ratio, pHH2O, base cation contents, and heavy metal contents. For all three stand compositions, the organic horizons showed a significant accumulation of heavy metals compared to the mineral horizons. Heavy metal content was correlated with pH, N and C contents, C/N ratio, and base cation contents. The admixture of shrubs, especially European hazelnut, positively affected soil organic matter quality and, consequently, the accumulation of heavy metals. European hazelnut had the most beneficial soil effects on the tested soil, which confirms that this species can be used in planning species composition, particularly in regions prone to heavy pollutant deposition.

重金属在土壤中积累和结合力很强,因此很难消除。本研究的目的是评估松树单一栽培中掺入赤杨(Frangula alnus)和欧洲榛子(Coryllus avellana)对土壤表层重金属的积累和垂直分布的影响。在波兰南部的 Rybnik 林区,每个变体各选择了十个地点,分别是掺杂赤松的松林、掺杂欧洲榛子的松林和松树单植林。在研究中,从每个地点的有机层和矿质层采集了土壤样本,并对氮和碳含量、碳/氮比、pHH2O、碱阳离子含量和重金属含量进行了分析。在所有三种土壤层组成中,有机层的重金属含量都比矿质层高。重金属含量与 pH 值、氮和碳含量、碳/氮比和碱式阳离子含量相关。灌木(尤其是欧洲榛子)的加入对土壤有机质质量产生了积极影响,进而影响了重金属的积累。欧洲榛对测试土壤的影响最为有利,这证明该物种可用于规划物种组成,尤其是在重污染物沉积地区。
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引用次数: 0
Carbon, Nitrogen, and Phosphorus Fluxes in Sixty Tropical Brazilian Rivers: Current Status, Stoichiometry and Trends 巴西 60 条热带河流的碳、氮和磷通量:现状、化学计量和趋势
IF 2.52 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-06-25 DOI: 10.1007/s11270-024-07271-6
Carlos Noriega, Humberto Varona, Carmen Medeiros, Aubains Hounsou-Gbo, Julia Araujo, Moacyr Araujo

Public data from sixty tropical rivers were used to explore variations in C, N, and P and the potential impact of anthropogenic activities over a decade on freshwater bodies. The results showed the Total Organic Carbon (TOC) varying between 2.7–73.0 mg C l−1; whereas Total Nitrogen observations showed concentrations between 0.9 and 32.0 mg N l−1 and Total Phosphorus showed a higher frequency of data in the range of 0.02–0.4 mg P l−1. The annual total C load (TC) was estimated at 32.7 Tg C yr−1, where dissolved inorganic carbon (DIC) accounted for 69% of TC and dissolved organic carbon (DOC) contributed 22%. The stoichiometry showed P depletion relative to C and/or N in 39 of the sixty rivers (65%). This was further supported by the fact that most catchments had TOC values > 50% (C/N/P = 100%). A significant trend was found for yearly fluxes of TOC for the period 2008–2018 (Mann–Kendall test; p = 0.0006; α = 0.05). Land-use and cover at period 2008–2018 indicated a trend of increasing anthropized area of 4%, whereas the natural area decreased by 3.1%. The organic load trend analysis showed 85% of municipalities with a positive trend, this high rate in the remaining organic load is indicative of urban and agricultural in the region.

利用来自六十条热带河流的公开数据,探讨了碳、氮、磷的变化以及十年来人类活动对淡水水体的潜在影响。结果显示,总有机碳(TOC)在 2.7-73.0 毫克 C l-1 之间变化;而总氮观测数据显示浓度在 0.9-32.0 毫克 N l-1 之间,总磷数据频率较高,在 0.02-0.4 毫克 P l-1 之间。年总碳负荷(TC)估计为 32.7 吨碳/年-1,其中溶解无机碳(DIC)占总碳负荷的 69%,溶解有机碳(DOC)占 22%。化学计量学显示,在 60 条河流中,有 39 条河流(65%)的碳和/或氮含量低于碳和/或氮含量。大多数集水区的总有机碳值为 50%(C/N/P=100%),进一步证实了这一点。在 2008-2018 年期间,TOC 的年通量呈明显趋势(Mann-Kendall 检验;p = 0.0006;α = 0.05)。2008-2018 年期间的土地利用和覆盖情况表明,人为化面积呈上升趋势,上升了 4%,而自然面积则下降了 3.1%。有机负荷趋势分析表明,85% 的城市呈正趋势,剩余有机负荷的这一高比率表明了该地区的城市和农业情况。
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引用次数: 0
The long proboscis of the aphid Stomaphis yanonis (Aphididae Lachninae) is advantageous for avoiding predation by tending ants. 蚜虫 Stomaphis yanonis(蚜科 Lachninae)的长触角有利于躲避蚂蚁的捕食。
IF 2.1 3区 生物学 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-06-25 DOI: 10.1007/s00114-024-01922-8
Takumi Matsuura, Shunsuke Nakamura, Tetsuya Yamamoto, Tsubasa Toji, Takao Itino

Whether in ant-aphid mutualism the ants exert evolutionary selection pressure on aphid morphology has not yet been fully tested. Here, we tested whether the long proboscises of Stomaphis yanonis (Aphididae Lachninae) aphids confer an advantage in preventing predation by the tending ants. Specifically, we tested the hypothesis that aphids with a shorter proboscis would excrete less honeydew, making them more likely to be preyed upon by ants. Our results showed that aphid individuals with a shorter proboscis took up less phloem sap and excreted less honeydew than individuals with a longer proboscis. In addition, among aphids with a similar body size, those with a shorter proboscis were more susceptible to predation by ants than those with a longer proboscis. These results suggest that predation by tending ants, by exerting selection pressure on aphid proboscis morphology, has caused the aphids to evolve longer proboscises.

在蚂蚁与蚜虫的互生关系中,蚂蚁是否对蚜虫的形态施加了进化选择压力,这一问题尚未得到充分检验。在这里,我们测试了蚜蝇科(Stomaphis yanonis)蚜虫的长触角是否在防止蚂蚁捕食方面具有优势。具体来说,我们测试了这样一个假设,即长鼻较短的蚜虫排出的蜜露较少,因此更容易被蚂蚁捕食。结果表明,与长探针的蚜虫个体相比,短探针的蚜虫个体吸收的韧皮部汁液更少,排出的蜜露也更少。此外,在体型相似的蚜虫中,探针较短的蚜虫比探针较长的蚜虫更容易被蚂蚁捕食。这些结果表明,蚂蚁的捕食对蚜虫的探针形态产生了选择压力,导致蚜虫进化出更长的探针。
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