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Variation in under-5 mortality attributable to anomalous precipitation during El Niño–Southern Oscillation cycles: Assessment of the intertemporal inequality in child health 厄尔尼诺-南方涛动周期期间异常降水导致的 5 岁以下儿童死亡率变化:评估儿童健康的时际不平等
IF 8.9 1区 环境科学与生态学 Q1 Social Sciences Pub Date : 2024-06-17 DOI: 10.1016/j.gloenvcha.2024.102879
Tao Xue , Jingyi Wu , Fangzhou Li , Mingkun Tong , Hengyi Liu , Wulin Yang , Pengfei Li

Objective

To explore the health effect of anomalous precipitation on deaths among children younger than 5 years (under-5 deaths) in low- and middle-income countries (LMICs).

Methods

Based on a sample of 1.6 million children from 56 LMICs, we conducted a sibling-matched Cox regression model to examine the association between under-5 deaths and anomalous precipitation in annual average. We established a nonlinear exposure–response function to characterize heterogeneity in the association, and checked its robustness by conducting a few sensitivity analyses. To illustrate absolute risks embedded in the complex climate-health linkage, across 100 LMICs, we calculated burden of under-5 deaths attributable to anomalous precipitation, and showed how the burden varied with the El Niño–Southern Oscillation (ENSO), a well-known predictable climate pattern affecting the rainfall cycle. We focused on the intertemporal inequality in the attributable burden.

Results

The epidemiological analyses showed a robust negative association between anomalous precipitation and under-5 deaths for arid areas, and a potentially positive association for humid areas. The anomalous precipitation was significantly associated to an intertemporal inequality in under-5 mortality. Across the 100 LMICs, 26.7% or 134 million under-5 children lived in ENSO-sensitive areas. Among them, anomalous rainfall decreased under-5 deaths by 46,246 (CI: 24,599–68,703) during an El Niño year (October 2015 to September 2016), and increased under-5 deaths by 77,505 (CI: 55,890–99,815) during a La Niña year (March 2008 to February 2009) across the 100 LMICs.

Conclusion

Anomalous precipitation can lead to intertemporal inequality in child health. Healthcare resources should be allocated according to predicted variability in precipitation, such as ENSO-mediated extreme rainfall.

目的 探讨异常降水对中低收入国家 5 岁以下儿童死亡(5 岁以下儿童死亡)的健康影响。方法 我们以 56 个中低收入国家的 160 万儿童为样本,采用同胞匹配的 Cox 回归模型研究了 5 岁以下儿童死亡与年均异常降水之间的关联。我们建立了一个非线性暴露-反应函数来描述关联中的异质性,并通过进行一些敏感性分析来检验其稳健性。为了说明复杂的气候-健康联系中蕴含的绝对风险,我们在 100 个低收入和中等收入国家计算了异常降水造成的 5 岁以下儿童死亡负担,并展示了这一负担如何随厄尔尼诺-南方涛动(ENSO)的变化而变化,厄尔尼诺-南方涛动是影响降雨周期的众所周知的可预测气候模式。结果流行病学分析表明,在干旱地区,异常降水与 5 岁以下儿童死亡之间存在密切的负相关关系,而在潮湿地区则可能存在正相关关系。异常降水与 5 岁以下儿童死亡率的时际不平等有显著关联。在 100 个低收入和中等收入国家中,有 26.7% 或 1.34 亿 5 岁以下儿童生活在厄尔尼诺/南方涛动敏感地区。其中,在厄尔尼诺年(2015 年 10 月至 2016 年 9 月)期间,异常降雨使 100 个低收入和中等收入国家的 5 岁以下儿童死亡人数减少了 46,246 人(CI:24,599-68,703),而在拉尼娜年(2008 年 3 月至 2009 年 2 月)期间,5 岁以下儿童死亡人数增加了 77,505 人(CI:55,890-99,815)。应根据预测的降水量变化,如厄尔尼诺/南方涛动引起的极端降雨,分配医疗保健资源。
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引用次数: 0
Porous Carbon Adsorbents for Highly Efficient Adsorption of Malachite Green Dye From Aqueous Solutions: Kinetics, Isotherms, and Mechanism of Adsorption 用于高效吸附水溶液中孔雀石绿染料的多孔碳吸附剂:动力学、等温线和吸附机理
IF 2.52 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-06-17 DOI: 10.1007/s11270-024-07198-y
Anastasia Memetova, Inderjeet Tyagi, Nariman Memetov, Alena Gerasimova, Elina Mkrtchyan, Oksana Ananyeva, Alexander Babkin, Alexander Blokhin, Alexey Tkachev, Suhas, Monika Chaudhary, Vinod Kumar Vashistha

A number of new micro-mesoporous carbon materials (FHU100N, FHU100K, FHU70N30K, FHU50N50K and FHU20N80K) based on a mixture of furfural, hydroquinone, and urotropine have been synthesized by the alkaline activation method using a combination of activating agents (KOH and NaOH). The influence of the porous structure of the synthesized adsorbents has been studied with particular attention to the pore size distribution, in particular, to the pore volume in which MG can be adsorbed most efficiently from aqueous solutions. Subsequently, among the tested carbons, the FHU100N has excellent porosity (total pore volume, micropore volume and mesopore volume: 1.136, 0.632 and 0.504 cm3 /g, respectively) with the highest surface area (2575 m2 /g). The adsorption capacity of FHU100N (1300 mg/g) for malachite green (MG) was superior to other micro mesoporous carbons (500–918 mg/g). The results obtained showed that the key contribution to the adsorption of the MG dye is made by pores ranging in size from 2 to 3.5 nm. The FHU100N adsorbent, which showed the highest MG adsorption activity, was characterized by nitrogen adsorption, FTIR, Raman spectroscopy, and XRD techniques. To understand the adsorption mechanisms on the obtained material, detailed mathematical analysis of experimental sorption data was carried out using the existing kinetic (pseudo-first order and pseudo-second order) models and diffusion (Weber-Morris and Boyd) models, along with adsorption equilibrium isotherms (Langmuir, Freundlich, Temkin, Dubinin-Radushkevich).

Graphical Abstract

本研究以糠醛、对苯二酚和乌洛托品的混合物为基础,通过碱性活化法并结合使用活化剂(KOH 和 NaOH)合成了多种新型微多孔碳材料(FHU100N、FHU100K、FHU70N30K、FHU50N50K 和 FHU20N80K)。研究了合成吸附剂多孔结构的影响,特别关注了孔径分布,尤其是从水溶液中最有效吸附 MG 的孔体积。随后,在测试的碳中,FHU100N 的孔隙率(总孔体积、微孔体积和中孔体积分别为 1.136、0.632 和 0.504 cm3 /g)极佳,比表面积(2575 m2 /g)最大。FHU100N 对孔雀石绿(MG)的吸附容量(1300 mg/g)优于其他微介孔碳(500-918 mg/g)。结果表明,孔径在 2 至 3.5 纳米之间的微孔对孔雀石绿染料的吸附起了关键作用。通过氮吸附、傅立叶变换红外光谱、拉曼光谱和 XRD 技术对显示出最高 MG 吸附活性的 FHU100N 吸附剂进行了表征。为了了解所获材料的吸附机理,我们利用现有的动力学模型(伪一阶和伪二阶)、扩散模型(Weber-Morris 和 Boyd)以及吸附平衡等温线(Langmuir、Freundlich、Temkin、Dubinin-Radushkevich)对实验吸附数据进行了详细的数学分析。
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引用次数: 0
Discourses of climate inaction undermine public support for 1.5 °C lifestyles 关于气候不作为的论调削弱了公众对 1.5 °C 生活方式的支持
IF 8.9 1区 环境科学与生态学 Q1 Social Sciences Pub Date : 2024-06-17 DOI: 10.1016/j.gloenvcha.2024.102875
Catherine Cherry , Caroline Verfuerth , Christina Demski

Urgent action to tackle the climate crisis will only be possible with significant public support for radical lifestyle change. Arguments that seek to delay climate action and justify inadequate mitigation efforts, often termed ‘discourses of delay’, are widespread within political and media debate on climate change. Here we report the results of novel public deliberation and visioning workshops, conducted across the UK in 2020/2021 to explore visions of a 1.5 °C future. We found that despite very strong public support for many low-carbon lifestyle strategies in principle, entrenched discourses of delay are limiting beliefs that a fair, low-carbon future is possible. Consisting of four overarching narratives of climate inaction (Resisting personal responsibility; Rejecting the need for urgency; Believing change is impossible; and Defending the social contract), this public discourse of delay is characterised by three distinct repertoires (each with its own emotional resonance), that act to weaken support for climate action by producing defensive responses to discussions of low-carbon lifestyle change and undermining public sense of agency. We argue that countering these narratives, and the defensive responses they invoke, is essential for achieving meaningful public action on climate change.

只有在公众大力支持彻底改变生活方式的情况下,才有可能采取紧急行动应对气候危机。在有关气候变化的政治和媒体辩论中,试图推迟气候行动并为不充分的减缓努力辩护的论点(通常称为 "推迟论述")十分普遍。在此,我们报告了新颖的公众讨论和愿景研讨会的结果,该研讨会于 2020/2021 年在英国各地举行,旨在探讨 1.5 °C 未来的愿景。我们发现,尽管公众原则上非常支持许多低碳生活方式战略,但根深蒂固的延迟论述限制了人们对公平、低碳未来的信念。由四种关于气候不作为的总体叙事(抵制个人责任;拒绝紧迫性;认为改变是不可能的;以及捍卫社会契约)组成,这种关于延迟的公共话语具有三种不同的再现(每种都有自己的情感共鸣),它们通过对低碳生活方式改变的讨论做出防御性反应,削弱了对气候行动的支持,并削弱了公众的能动性。我们认为,反驳这些叙事及其引发的防御性反应对于实现有意义的气候变化公众行动至关重要。
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引用次数: 0
Nutrient Accumulation in Silver Birch (Betula pendula Roth) Biomass in a Lignite Mining Area 褐煤开采区银桦(Betula pendula Roth)生物质中的营养积累
IF 2.52 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-06-17 DOI: 10.1007/s11270-024-07254-7
Beata Rustowska, Jerzy Jonczak, Artur Pędziwiatr

The influence of lignite mining on vegetation constitutes a key issue due to the role of plants in restoring and maintaining the ecological balance of ecosystems. In this context, the identification of its impact on the functioning of silver birch (Betula pendula Roth) as a species often colonizing disturbed habitats takes on particular importance. Therefore, we aimed to determine the changes in nutrient content in silver birch overgrowing a spoil heap and in the vicinity of a fly ash settling pond and power plant. For this purpose, plant tissues (fine and coarse roots, stemwood, bark, coarse and fine branches, leaves) and soil samples (0–10, 10–20, 20–40, 20–40 cm deep) were examined. The basic soil characteristics were determined, along with the N, P, K, Ca, Mg, S, Fe, Mn, Cu, and Zn contents of the soil and plant samples. The soils varied in terms of soil pH and were poor in total organic carbon and other elements. The plant nutrient content varied strongly across the analyzed tissues, with the leaves usually containing the most and the stemwood the least nutrients. Statistical analysis indicated significant differences between the control vs spoil heap (particularly in Mn, S, and Mg) and the stand close to the settling pond (particularly in Ca, Mn, P, K, and S). We found that the chemical properties of the spoil heap and fly ash originating from the lignite mining operations are likely factors influencing nutrient accumulation in silver birch trees.

由于植物在恢复和维持生态系统生态平衡方面的作用,褐煤开采对植被的影响成为一个关键问题。在这种情况下,银桦(Betula pendula Roth)作为一种经常在受干扰栖息地定居的物种,确定其对银桦功能的影响就显得尤为重要。因此,我们的目标是确定生长在垃圾堆和粉煤灰沉淀池及发电厂附近的银桦营养成分的变化。为此,我们检测了植物组织(细根和粗根、茎木、树皮、粗枝和细枝、叶片)和土壤样本(0-10、10-20、20-40、20-40 厘米深)。测定了土壤的基本特征,以及土壤和植物样本中的氮、磷、钾、钙、镁、硫、铁、锰、铜和锌含量。这些土壤的 pH 值各不相同,总有机碳和其他元素含量较低。所分析的植物组织的养分含量差异很大,通常叶片的养分含量最高,而茎木的养分含量最低。统计分析显示,对照组与垃圾堆(尤其是锰、硒和镁)以及靠近沉淀池的地块(尤其是钙、锰、磷、钾和硒)之间存在明显差异。我们发现,来自褐煤开采作业的废渣堆和粉煤灰的化学特性很可能是影响银桦树养分积累的因素。
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引用次数: 0
Impact of lifestyle, human diet and nutrient use efficiency in food production on eutrophication of global aquifers and surface waters 生活方式、人类饮食和粮食生产中的养分利用效率对全球含水层和地表水富营养化的影响
IF 8.9 1区 环境科学与生态学 Q1 Social Sciences Pub Date : 2024-06-15 DOI: 10.1016/j.gloenvcha.2024.102874
A.F. Bouwman , A.H.W. Beusen , J.C. Doelman , E. Stehfest , H. Westhoek

A spatially explicit (0.5 degree resolution) analysis is presented of the impact of human lifestyle, diet and nutrient use efficiency in food production and wastewater treatment on exceedance of threshold concentrations for nitrate in groundwater, and total N and total P concentrations in surface water, as well as criteria for their ratio. This analysis starts from the middle-of-the-road (SSP2) and the sustainability (SSP1) Shared Socio-economic Pathways (SSP), focusing on the year 2050. The scenarios with changed lifestyle assume a reduction of food wastage and a low-meat diet for all world inhabitants, implying large reductions of meat and milk consumption and production in industrialized countries. Scenarios with improved nutrient use efficiencies assume maximum achievable efficiencies under practical conditions. The SSP2 scenario combined with assumptions on lifestyle and human diet leads to improvement in industrialized countries only, and increased levels in many other regions. A strong improvement is achieved in SSP1, but not in many developing countries, and SSP1 combined with changed lifestyle leads to improvement of groundwater and surface water quality in industrialized countries only. Therefore, changed lifestyle needs to be combined with efforts to improve the efficiency in food production systems and wastewater treatment to achieve reductions of the area affected by groundwater contamination and eutrophication of surface waters. Reduction strategies need to find a balance between N and P, since it is easier to reduce N in rivers to levels below the threshold than P.

对人类生活方式、饮食习惯、粮食生产和废水处理中的营养物质利用效率对地下水硝酸盐阈值浓度、地表水总氮和总磷浓度超标的影响及其比率标准进行了空间明确(0.5 度分辨率)分析。本分析从中庸(SSP2)和可持续性(SSP1)共同社会经济路径(SSP)出发,以 2050 年为重点。改变生活方式的方案假定世界所有居民都会减少食物浪费和低肉类饮食,这意味着工业化国家会大量减少肉类和牛奶的消费和生产。提高养分利用效率的情景假设在实际条件下可达到的最高效率。结合生活方式和人类膳食假设的 SSP2 情景仅导致工业化国家的营养利用效率提高,而其他许多地区的营养利用效率则有所提高。在 SSP1 中,地下水和地表水的水质得到了很大改善,但在许多发展中国家却没有得到改善;SSP1 与改变生活方式相结合,仅在工业化国家改善了地下水和地表水的水质。因此,改变生活方式需要与提高食品生产系统和废水处理效率相结合,以减少受地下水污染和地表水富营养化影响的地区。减少战略需要在氮和磷之间找到平衡,因为将河流中的氮减少到阈值以下比将磷减少到阈值以下更容易。
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引用次数: 0
Migrants as sustainability actors: Contrasting nation, city and migrant discourses and actions 作为可持续发展行动者的移民:国家、城市和移民言论与行动的对比
IF 8.9 1区 环境科学与生态学 Q1 Social Sciences Pub Date : 2024-06-14 DOI: 10.1016/j.gloenvcha.2024.102860
Claudia Fry , Emily Boyd , Mark Connaughton , W. Neil Adger , Maria Franco Gavonel , Caroline Zickgraf , Sonja Fransen , Dominique Jolivet , Anita H. Fábos , Ed Carr

Although it is widely recognized that migration is socially transformative, the potential contributions of migrants to transformations towards sustainability in their destination areas are often overlooked in mainstream discourse on environmentalism and sustainability. Here we seek to identify current narratives of migrants and sustainability across individual, urban, and national scales. Migrants are commonly framed in public policy as having no or even negative impacts on sustainability. The study hypotheses that the lived experience of sustainability by migrants within urban destinations differ from dominant discourses and perceptions of migrant populations within societies. We test and document such divergence using data from 21 interviews with key stakeholders from the city and Swedish national level, an attitudinal survey of 895 migrants and non-migrants in Malmö, Sweden; and a media analysis of local and national Swedish newspapers. Survey results show that migrants engage more extensively with a number of sustainability actions compared to non-migrants culminating in new insights on ‘migrants as sustainability actors’. By contrasting individual scale practices against urban to national sustainability narratives, the study illuminates current barriers to and the potential of migrants to play a transformative role in progress towards sustainability that is unrecognized in dominant policy discourses. To tap into this potential, the study emphasizes that sustainability policy across scales should embrace plurality and migration as fundamental parts of progress towards sustainability.

尽管人们普遍认为移民具有社会转型作用,但在有关环境和可持续性的主流讨论中,移民对其目的地地区可持续性转型的潜在贡献往往被忽视。在此,我们试图找出当前在个人、城市和国家范围内有关移民和可持续性的叙述。公共政策通常认为移民对可持续发展没有影响,甚至有负面影响。本研究的假设是,移民在城市目的地的可持续发展生活体验与社会中的主流论述和对移民人口的看法不同。我们利用对城市和瑞典国家层面的主要利益相关者进行的 21 次访谈数据、对瑞典马尔默市 895 名移民和非移民进行的态度调查,以及对瑞典当地和全国性报纸进行的媒体分析,检验并记录了这种差异。调查结果显示,与非移民相比,移民更广泛地参与了一系列可持续发展行动,从而为 "移民作为可持续发展行动者 "提供了新的见解。通过将个人规模的实践与城市和国家的可持续发展叙事进行对比,该研究揭示了移民在可持续发展进程中发挥变革作用的现有障碍和潜力,而这些障碍和潜力在主流政策论述中尚未得到认可。为了挖掘这一潜力,研究强调,不同规模的可持续发展政策应将多元化和移民作为实现可持续发展的基本组成部分。
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引用次数: 0
Bioaccumulation and human risk assessment of inorganic nanoparticles in aquaculture species 无机纳米粒子在水产养殖物种中的生物累积和人类风险评估
IF 8.131 2区 环境科学与生态学 Q1 Environmental Science Pub Date : 2024-06-14 DOI: 10.1039/d4en00167b
Cristian Suárez-Oubiña, Paloma Herbello-Hermelo, Natalia Mallo, María Vázquez, Santiago Cabaleiro, Raquel Domínguez-González, Antonio Moreda-Piñeiro, Pilar Bermejo-Barrera
The escalating use of inorganic nanoparticles (NPs) in various applications raises concerns regarding their potential environmental release and subsequent bioaccumulation in the food chain, posing a risk to human health. This study aimed to assess the bioaccumulation potential of titanium dioxide (TiO2) and silver (Ag) NPs in three commercially relevant aquatic species: sea bream, sea bass, and Japanese carpet shell, and evaluate the associated human health risks through dietary exposure. Bioaccumulation patterns were evaluated in target organs (liver, kidney, and muscle) of sea bream and sea bass following dietary exposure to varying concentrations of NPs (0.25-1.5 mg/kg) for extended durations (up to 90 days). While moderate bioaccumulation was observed in non-edible organs like kidneys and livers, no significant accumulation was detected in the muscle tissue, even at high exposure levels. Conversely, bioaccumulation of both TiO2 and Ag NPs was evident in the soft tissues of Japanese carpet shell (maximum concentrations: 2.5×1010 g-1 for Ag NPs and 8.0×106 g-1 for TiO2 NPs). In vitro studies utilizing the Caco-2 human intestinal model revealed limited transcellular transport of NPs from both fish and shellfish muscle tissue (less than 34% for TiO2 NPs in sea bream and less than 61% and 4% for TiO2 NPs and Ag NPs, respectively, in Japanese carpet shell). These findings suggest that, while bioaccumulation may occur in certain species and organs, the human health risk associated with dietary exposure to NPs from commonly consumed fish appears to be low due to limited intestinal uptake. However, further research is necessary to elucidate the long-term consequences of chronic exposure and potential health effects.
无机纳米粒子(NPs)在各种应用中的使用不断增加,引起了人们对其潜在的环境释放和随后在食物链中的生物累积性的担忧,从而对人类健康构成风险。本研究旨在评估二氧化钛(TiO2)和银(Ag)纳米粒子在三种商业相关水生物种(鲷鱼、鲈鱼和日本地毯贝)中的生物累积潜力,并评估通过饮食接触对人类健康造成的相关风险。在长期(长达 90 天)膳食暴露于不同浓度的氮氧化物(0.25-1.5 毫克/千克)后,对鲷鱼和鲈鱼的目标器官(肝脏、肾脏和肌肉)中的生物累积模式进行了评估。虽然在肾脏和肝脏等非食用器官中观察到了适度的生物累积,但在肌肉组织中未检测到明显的累积,即使在高暴露水平下也是如此。相反,TiO2 和 Ag NPs 在日本地毯贝壳的软组织中都有明显的生物蓄积(最大浓度为 2.5×1010 g-1 和 2.5×1010 g-1):Ag NPs 为 2.5×1010 g-1,TiO2 NPs 为 8.0×106 g-1)。利用 Caco-2 人体肠道模型进行的体外研究表明,鱼类和贝类肌肉组织中的 NPs 跨细胞迁移都很有限(鲷鱼中 TiO2 NPs 的迁移率低于 34%,日本地毯贝中 TiO2 NPs 和 Ag NPs 的迁移率分别低于 61% 和 4%)。这些研究结果表明,虽然某些物种和器官可能会发生生物蓄积,但由于肠道摄取量有限,从常吃的鱼类中摄取 NPs 对人类健康造成的风险似乎很低。不过,有必要开展进一步研究,以阐明长期接触的长期后果和对健康的潜在影响。
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引用次数: 0
Novel Superadsorbent from Pozzolan-Charcoal based Geopolymer Composite for the Efficient Removal of Aqueous Crystal Violet 新型超吸附剂--基于滑石粉和木炭的土工聚合物复合材料可高效去除水溶液中的结晶紫
IF 2.52 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-06-14 DOI: 10.1007/s11270-024-07257-4
Jacques Madiba Mboka, Hermann Dzoujo Tamaguelon, Victor Shikuku, Sylvain Tome, Valery Franck Deugueu, Hanibal Othman, Christoph Janiak, Marchand Manga Dika, Marie Annie Etoh, David Joh Daniel Dina

In this study, geopolymer composites, GP0, GPC2.5, GPC5, GPC7.5 and GPC10 were synthesized from pozzolan, a naturally occurring, abundant and inexpensive precursor, substituted with varying proportions of 0, 2.5, 5, 7.5, and 10% content by weight of charcoal powder (CP), an industrial waste product, respectively. The geocomposites were characterized by Fourier Transformed Infrared Spectroscopy (FTIR), BET (Bruamer Emmet Teller) method, scanning electron microscopy (SEM), thermogravimetric analysis (TGA), methylene blue and iodine indices. The adsorption performances for the removal of crystal violet, a toxic dye, from water in batch mode were evaluated. Incorporation of charcoal powder improved the functional group density, the microporous structure and the specific surface areas (SSA) of the pozzolan-based geopolymers resulting in increased adsorption efficacy. Langmuir, Freundlich, Temkin, Dubin-Radushkevich-Kaganer and Flory Huggins isotherms were applied to model the equilibrium data. The GPC7.5 composite (7.5% wt CP), with SSA 15.93 m2 g−1, exhibited an unprecedented ultrahigh maximum monolayer adsorption density of 2803 mg g−1, a new benchmark value for adsorption of crystal violet. The adsorption rate was best described by the pseudo-first order kinetic model with an invariable adsorption rate constant (k1). The Gibbs free energy (ΔG < 0) signify a spontaneous and feasible adsorption process while the magnitude of the adsorption energies corresponded to a physisorption mechanism. The GPC7.5 composite is a novel inexpensive superadsorbent for the abatement of crystal violet dye in aqueous media with about 1000 mg g−1 higher adsorption capacity than pristine pozzolan-based geopolymer (GP0). The synthesis adopted minimal and abundant precursors producing a material that is techno-economical and reproducible in many countries, especially emerging economies.

在这项研究中,利用天然存在、丰富且廉价的前体--水青石,以不同比例(按重量计)的木炭粉(CP)(0、2.5、5、7.5 和 10%)替代,合成了土工聚合物复合材料 GP0、GPC2.5、GPC5、GPC7.5 和 GPC10。傅立叶变换红外光谱法(FTIR)、BET(Bruamer Emmet Teller)法、扫描电子显微镜(SEM)、热重分析(TGA)、亚甲基蓝和碘指数对土工复合材料进行了表征。在批处理模式下,对去除水中有毒染料结晶紫的吸附性能进行了评估。木炭粉的加入改善了以坡莫兰为基础的土工聚合物的官能团密度、微孔结构和比表面积(SSA),从而提高了吸附效能。兰缪尔、弗里德里希、滕金、杜宾-拉杜什凯维奇-卡甘纳和弗洛里-休金斯等温线被用来模拟平衡数据。GPC7.5 复合材料(7.5% 重量 CP)的 SSA 为 15.93 m2 g-1,显示出前所未有的超高最大单层吸附密度(2803 mg g-1),这是水晶紫吸附的新基准值。假一阶动力学模型对吸附速率进行了最佳描述,吸附速率常数(k1)不变。吉布斯自由能(ΔG <0)表明吸附过程是自发可行的,而吸附能的大小则与物理吸附机制相对应。GPC7.5复合材料是一种新型廉价的超级吸附剂,其在水介质中对水晶紫染料的吸附能力比原始的灰岩基土工聚合物(GP0)高出约1000 mg g-1。该合成方法采用了极少量的丰富前体,生产出的材料在许多国家,尤其是新兴经济体,具有技术经济性和可重复性。
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引用次数: 0
Multiple insights into the two-sided effects of foliar application of cerium oxide nanoparticles on the growth of alfalfa (Medicago sativa L.) 叶面喷施纳米氧化铈颗粒对紫花苜蓿(Medicago sativa L.)生长双面效应的多重启示
IF 8.131 2区 环境科学与生态学 Q1 Environmental Science Pub Date : 2024-06-14 DOI: 10.1039/d4en00271g
Zhao Chen, Zhipeng Guo, Nan Xu, Md. Zulfikar Khan, Junpeng Niu
Nanotechnology has a wide range of applications, and the pollution and toxicity of their overuse must also be taken seriously. The dual effects of cerium oxide nanoparticles (CeO2 NPs) on alfalfa (Medicago sativa L.) through regulating programmed cell death (PCD) were investigated. Herein, foliar spray of CeO2 NPs on alfalfa revealed a dose-dependent effect of CeO2 NPs. CeO2 NPs at low concentrations had a positive effect but at high concentrations had a phytotoxicity. Specifically, 100 mg L-1 CeO2 NPs improved morphology, biomass, pigments, photosynthesis, stomatal opening, ultrastructure, osmotic and redox homeostasis, the antioxidant enzyme and the anti-PCD genes, and several hormones, accompanied by lower PCD-promoting gene expression and cellular features. Conversely, 1000 mg L-1 CeO2 NPs induced PCD by causing oxidative damage, along with negative morphology, reduced quality, high Ce accumulation, weak photosynthesis, stomatal closure, lipid peroxidation, apoptosis, impaired cellular ultrastructure, DNA fragmentation, osmotic and redox instability, gene alterations, and hormonal fluctuations. Overall, alfalfa responds to the duality of CeO2 NPs by controlling PCD, which is regulated by a complex network. It proposes a fresh outlook on the rational utilization of CeO2 NPs, the promotion of sustainable agriculture, and the prevention of environmental pollution caused by nanomaterials.
纳米技术应用广泛,但过度使用纳米技术带来的污染和毒性也必须引起重视。本文研究了氧化铈纳米粒子(CeO2 NPs)通过调节细胞程序性死亡(PCD)对紫花苜蓿(Medicago sativa L.)的双重影响。在这里,对紫花苜蓿叶面喷洒 CeO2 NPs 表明了 CeO2 NPs 的剂量依赖效应。低浓度的 CeO2 NPs 有积极作用,但高浓度的 CeO2 NPs 有植物毒性。具体而言,100 mg L-1 CeO2 NPs 可改善紫花苜蓿的形态、生物量、色素、光合作用、气孔开放、超微结构、渗透和氧化还原平衡、抗氧化酶和抗 PCD 基因以及多种激素,同时降低促进 PCD 的基因表达和细胞特征。相反,1000 mg L-1 CeO2 NPs 则会诱导 PCD,导致氧化损伤、负形态、质量下降、高 Ce 积累、光合作用减弱、气孔关闭、脂质过氧化、细胞凋亡、细胞超微结构受损、DNA 断裂、渗透和氧化还原不稳定、基因改变和激素波动。总之,紫花苜蓿通过控制 PCD 对 CeO2 NPs 的双重性做出了反应,而 PCD 是由一个复杂的网络调控的。该研究为合理利用 CeO2 NPs、促进可持续农业发展和防止纳米材料造成的环境污染提出了新的展望。
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引用次数: 0
Biological invasions as burdens to primary economic sectors 生物入侵是初级经济部门的负担
IF 8.9 1区 环境科学与生态学 Q1 Social Sciences Pub Date : 2024-06-13 DOI: 10.1016/j.gloenvcha.2024.102858
Anna J. Turbelin , Emma J. Hudgins , Jane A. Catford , Ross N. Cuthbert , Christophe Diagne , Melina Kourantidou , David Roiz , Franck Courchamp

Many human-introduced alien species economically impact industries worldwide. Management prioritisation and coordination efforts towards biological invasions are hampered by a lack of comprehensive quantification of costs to key economic sectors. Here, we quantify and estimate global invasion costs to seven major sectors and unravel the introduction pathways of species causing these costs — focusing mainly on primary economic sectors: agriculture, fisheries and forestry. From 1970 to 2020, costs reported in the InvaCost database as pertaining to Agriculture, Fisheries, and Forestry totaled $509 bn, $1.3 bn, and $134 bn, respectively (in 2017 United States dollars). Pathways of costly species were diverse, arising predominantly from cultural and agricultural activities, through unintentional contaminants with trade, and often impacted different sectors than those for which species were initially introduced. Costs to Agriculture were pervasive and greatest in at least 37 % (n = 46/123) of the countries assessed, with the United States accumulating the greatest costs for primary sectors ($365 bn), followed by China ($101 bn), and Australia ($36 bn). We further identified 19 countries highly economically reliant on Agriculture, Fisheries, and Forestry that are experiencing massive economic impacts from biological invasions, especially in the Global South. Based on an extrapolation to fill cost data gaps, we estimated total global costs ranging from at least $517–1,400 bn for Agriculture, $5.7–6.5 bn for Fisheries, and $142–768 bn for Forestry, evidencing substantial underreporting in the Forestry sector in particular. Burgeoning global invasion costs challenge sustainable development and highlight the need for improved management action to reduce future impacts on industry.

Significance

With rapidly rising biological invasion rates, efficient management is critical for economic and environmental impact mitigation. Specifically, improved quantification of the economic cost of biological invasions to the world’s primary economic sectors could provide crucial information for policymakers who must prioritise actions to limit ongoing and future impacts. We show that since 1970, over $600 bn in impacts has been incurred across Agriculture, Fisheries and Forestry, with the largest share reported in Agriculture. We further identify 19 countries, which rely heavily on primary sectors, facing comparatively high impacts from invasions, requiring urgent action. However, gaps in cost reporting across invasive taxa and countries suggest that these impacts are grossly underestimated. Proactive prioritisation by policymakers is needed to mitigate future impacts to primary sectors.

许多人类引入的外来物种对全球各行业造成了经济影响。由于缺乏对主要经济部门成本的全面量化,针对生物入侵的优先管理和协调工作受到了阻碍。在此,我们对全球七大行业的入侵成本进行了量化和估算,并揭示了造成这些成本的物种引入途径--主要集中在主要经济部门:农业、渔业和林业。从 1970 年到 2020 年,InvaCost 数据库中报告的农业、渔业和林业成本总额分别为 5,090 亿美元、13 亿美元和 1,340 亿美元(按 2017 年美元计算)。代价高昂的物种的传播途径多种多样,主要来自文化和农业活动,以及贸易中的无意污染,而且影响的部门往往与最初引入物种的部门不同。在接受评估的国家中,至少有 37% 的国家(n = 46/123)普遍存在农业成本问题,且农业成本最高,其中美国的初级部门成本最高(3,650 亿美元),其次是中国(1,010 亿美元)和澳大利亚(360 亿美元)。我们进一步确定了 19 个在经济上高度依赖农业、渔业和林业的国家,这些国家正在经受生物入侵带来的巨大经济影响,尤其是在全球南部。为了填补成本数据缺口,我们进行了推断,估计全球农业总成本至少为 5,170-1,400 亿美元,渔业总成本为 57-650 亿美元,林业总成本为 1,420-7,680 亿美元。全球入侵成本的激增对可持续发展提出了挑战,并凸显了改善管理行动以减少未来对产业影响的必要性。具体来说,对生物入侵给世界主要经济部门造成的经济损失进行更好的量化,可以为决策者提供至关重要的信息,他们必须优先采取行动来限制当前和未来的影响。我们的研究表明,自 1970 年以来,农业、渔业和林业部门受到的影响超过 6000 亿美元,其中农业部门受到的影响最大。我们进一步确定了 19 个国家,这些国家严重依赖第一产业,面临着入侵带来的相对较高的影响,需要采取紧急行动。然而,不同入侵类群和国家在成本报告方面的差距表明,这些影响被严重低估。决策者需要积极主动地确定优先事项,以减轻未来对初级产业的影响。
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引用次数: 0
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