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Absorption spectroscopy of 40Ca atomic beams produced via pulsed laser ablation: a quantitative comparison of Ca and CaTiO3 targets 通过脉冲激光烧蚀产生的 40Ca 原子束的吸收光谱学:Ca 和 CaTiO3 靶件的定量比较
IF 2 Q2 MATERIALS SCIENCE, BIOMATERIALS Pub Date : 2024-11-12 DOI: 10.1007/s00340-024-08332-8
Kevin D. Battles, Brian J. McMahon, Brian C. Sawyer

Pulsed laser ablation is an increasingly prevalent method for fast ion trap loading of various species, however characteristics of the ablation target source material can affect the ion-loading process. One factor which can reduce the atomic flux from a target is oxidation during atmospheric exposure when preparing or making changes to the ion trap vacuum system. Recent work has shown that perovskite ablation targets produce consistent atomic densities even after exposure to atmosphere when compared to elemental source targets. In this work, we directly compare calcium (Ca) and calcium-titanate (CaTiO(_3)) ablation targets, characterizing the neutral atomic beam flux using resonant, time-resolved absorption spectroscopy of the 423 nm 1S0 (rightarrow) 1P1 transition in neutral Ca. We measure the ablation plume longitudinal and transverse temperatures, number density, ion production, and spot lifetime for each target. In addition, we compare the probe laser beam absorption for both targets before and after 21-h of exposure to atmosphere, demonstrating the relative robustness of the CaTiO(_3) source.

脉冲激光烧蚀是一种越来越普遍的快速离子阱装载各种物质的方法,但烧蚀靶源材料的特性会影响离子装载过程。在准备或改变离子阱真空系统时,大气暴露过程中的氧化作用是降低靶材原子通量的一个因素。最近的研究表明,与元素源靶相比,即使暴露在大气中,包晶烧蚀靶也能产生一致的原子密度。在这项工作中,我们直接比较了钙(Ca)和钙钛矿(CaTiO(_3))烧蚀靶,利用共振、时间分辨吸收光谱对中性钙中的 423 nm 1S0 (rightarrow) 1P1 转变进行了描述。我们测量了每个目标的烧蚀羽流纵向和横向温度、数量密度、离子产量和光斑寿命。此外,我们还比较了两个目标在大气中暴露 21 小时之前和之后的探针激光束吸收情况,证明了 CaTiO(_3) 源的相对稳健性。
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引用次数: 0
Effect of rainbow function on radial oscillations and some other properties of Chaplygin dark star 彩虹函数对查普里金暗星径向振荡和其他一些特性的影响
IF 2.8 Q2 MATERIALS SCIENCE, BIOMATERIALS Pub Date : 2024-11-12 DOI: 10.1140/epjp/s13360-024-05785-w
Krishna Pada Das, Ujjal Debnath

In the present article, we have imagined a hypothetical spherically symmetric stellar structure, made by an isotropic fluid satisfying dark energy equation of sate (EOS), named as dark energy star (DES), in the context of gravity’s rainbow. We adopted modified Chaplygin gas EOS with an extra parameter (alpha ) satisfying (0le alpha le 1). In a recent literature Tudeshki et al. (Phys. Lett. B 848 (2024) 138333) investigated the same type stellar configuration, including the mass-radius relation for (alpha =1). However, we have investigated the effect of the rainbow function on such hypothetical DESs corresponding to (alpha =0.8~text {and}~0.9). Mainly, we have concentrated on two features like, mass-radius relation and radial oscillations in the effect of rainbow function. After computing the values of maximum mass and corresponding radius of the star, we compared our results with GR and some chosen observed relativistic stellar candidates. Moreover, we have computed the frequencies and shown the behavior of corresponding Eigenfunctions for the six lowest excited modes in the variation of the rainbow function. As a final result, we have our proposed stellar structure is physically reasonable and may be placed in the ‘mass-gap’ region corresponding to some fixed values of model parameters.

在本文中,我们在引力彩虹的背景下,想象了一个由满足暗能量状态方程(EOS)的各向同性流体构成的假想球对称恒星结构,命名为暗能量星(DES)。我们采用了修正的查普利金气体EOS,其额外参数(alpha )满足(0le alpha le 1)。在最近的一篇文献中,Tudeshki 等人(Phys.B 848 (2024) 138333)研究了同一类型的恒星构型,包括质量-半径关系为(alpha =1)。然而,我们研究了彩虹函数对对应于(alpha =0.8~text {and}~0.9)的这种假设DES的影响。在彩虹函数的作用下,我们主要关注了两个特征,如质量-半径关系和径向振荡。在计算了恒星的最大质量和相应半径值之后,我们将结果与GR和一些观测到的相对论恒星候选者进行了比较。此外,我们还计算了六种最低激发模式在彩虹函数变化中的频率,并展示了相应特征函数的行为。最终结果表明,我们提出的恒星结构在物理上是合理的,可以被置于与模型参数的某些固定值相对应的 "质量间隙 "区域。
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引用次数: 0
Impact of deposition temperature on carrier transportation of sprayed (040) oriented tin sulfide thin films for photovoltaic applications 沉积温度对用于光伏应用的喷涂 (040) 拉伸硫化锡薄膜载流子传输的影响
IF 2.5 Q2 MATERIALS SCIENCE, BIOMATERIALS Pub Date : 2024-11-12 DOI: 10.1007/s00339-024-08024-2
J. Vijaya Raja Sekaran, L. Amalraj, K. Vijayakumar

Sprayed thin coatings of tin sulphide (SnS) onto glass substrates utilizing tin chloride dehydrate and CS (NH2)2 as precursors, in various substrate temperatures (250–325 °C) in steps of 25 °C. The physical properties were studied for all the as prepared SnS thin films. The increased substrate temperature on the film shows the increased crystallinity along orthorhombic nature of (040) plane. The Debye-Scherer formula was used to determine the crystallite’s size, which ranged from 20 to 29 nm. The morphological, energy-dispersive X-ray spectroscopy (EDS) and 3D AFM micrographs were characterized to find the morphology and surface roughness of thin film. Optical transmittance spectra (500 nm–1100 nm) revealed that all films had direct band gap values with appropriate range of photo voltaic applications. In the FT-IR spectrum’s absorption band, the characteristic stretching vibration mode of SnS thin films were analysed. The film developed at 325 °C had the lowest electrical resistivity of 4.28 Ω cm with a hole concentration of around 1013 cm−3. As the temperature of growth of the thin film increased, the resistance rapidly reduced.

以脱水氯化锡和 CS (NH2)2 为前驱体,在不同的基底温度(250-325 ℃)下,以 25 ℃ 为单位,在玻璃基底上喷涂硫化锡 (SnS) 薄膜。研究了所有制备的 SnS 薄膜的物理性质。薄膜的基底温度升高,显示出 (040) 面的正交结晶度增加。使用 Debye-Scherer 公式确定了晶粒尺寸,其范围为 20 至 29 nm。通过形态学、能量色散 X 射线光谱(EDS)和三维原子力显微镜显微照片来了解薄膜的形态和表面粗糙度。光学透射光谱(500 nm-1100 nm)显示,所有薄膜的直接带隙值都符合光电应用的适当范围。在傅立叶变换红外光谱的吸收带中,分析了 SnS 薄膜的特征拉伸振动模式。在 325 °C 下生成的薄膜电阻率最低,为 4.28 Ω cm,空穴浓度约为 1013 cm-3。随着薄膜生长温度的升高,电阻率迅速降低。
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引用次数: 0
Temperature measurements of high-temperature surface in environments with interfering radiation using luminescence lifetime thermometry 利用发光寿命温度测量法测量有干扰辐射环境中高温表面的温度
IF 2 Q2 MATERIALS SCIENCE, BIOMATERIALS Pub Date : 2024-11-12 DOI: 10.1007/s00340-024-08350-6
Yusong Wu, Yuhang Zhang, Tairan Fu

Interfering radiation, such as self-emitting thermal radiation, infrared radiation from heating sources, and combustion gas radiation, significantly impacts the use of optical thermometry. How to improve the precision of temperature measurement in such an environment is a key issue. Therefore, this work aimed to quantitatively analyze the temperature measurement precision of luminescence lifetime thermometry for measuring the temperatures of hot components in environments with interfering radiation. In this paper, based on the quantitative analysis of measurement noise of optical signal and the error propagation theory, we proposed a theoretical model for predicting the temperature measurement precision of luminescence lifetime thermometry. Using blue LED as the interfering radiation source, the temperature measurement experiments of high-temperature surfaces under different interfering radiation intensities were carried out. By comparing the measured precision based on the standard deviation of repeated experiments with the predicted precision of the theoretical model proposed in this paper, the reliability of this theoretical model was verified. The experiments also revealed that the temperature measurement precision was linearly related to the square root of the measured signal intensity (i.e., the sum of luminescence signal and interfering radiation signal). With the increase of the background interfering radiation intensity, although the accuracy of temperature measurement did not change significantly, the measurement noise increases, resulting in a significant increase in random error of measured temperature. This work provides guidance for developing luminescence lifetime thermometers and their applications in environments with interfering radiation.

自发光热辐射、加热源红外辐射和燃烧气体辐射等干扰辐射严重影响了光学温度测量的使用。如何提高在这种环境下的温度测量精度是一个关键问题。因此,这项工作旨在定量分析发光寿命测温法在干扰辐射环境中测量高温部件温度的测温精度。本文基于对光信号测量噪声的定量分析和误差传播理论,提出了预测发光寿命测温法温度测量精度的理论模型。以蓝色 LED 为干扰辐射源,进行了不同干扰辐射强度下高温表面的温度测量实验。通过比较基于重复实验标准偏差的测量精度和本文提出的理论模型的预测精度,验证了该理论模型的可靠性。实验还表明,温度测量精度与测量信号强度(即发光信号与干扰辐射信号之和)的平方根呈线性关系。随着本底干扰辐射强度的增加,虽然温度测量精度没有明显变化,但测量噪声增大,导致测量温度的随机误差显著增加。这项工作为开发发光寿命温度计及其在干扰辐射环境中的应用提供了指导。
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引用次数: 0
SEIDR: modeling the competitive propagation of rumor and anti-rumor in complex networks with emotional infection theory SEIDR:用情绪感染理论模拟复杂网络中谣言和反谣言的竞争性传播
IF 2.8 Q2 MATERIALS SCIENCE, BIOMATERIALS Pub Date : 2024-11-11 DOI: 10.1140/epjp/s13360-024-05691-1
Chen Dong, Houcai Wang, Shiyu Zhou, Hanlin Zhong

Social networks have become the best medium for the unbridled dissemination of rumor, which arises with the crisis of environment and has serious negative functions on social stability and people’s daily life. At present, a series of models have been constructed to study the spreading dynamics of rumor. However, most of existing researches ignore the competitive relationships between rumor and anti-rumor, and the emotional tendencies that may occurs during the propagation process of rumor. In this work, we construct a Susceptible-Exposed-Infectious-Debunker-Recovered (SEIDR) model by adopting the emotional infection theory of users and the competitive mechanism between rumor and anti-rumor. Furthermore, we investigate the influence of debunking behaviors and varying emotional intensities on the propagation of rumor. Then, the stability behaviors of rumor-free and epidemic equilibriums are calculated according to Routh–Hurwitz stability criterion. Finally, numerical examples are carried out to describe the influence of different parameters and verify the validity of theoretical results.

社交网络已成为谣言肆意传播的最佳媒介,谣言随着环境危机而产生,对社会稳定和人们的日常生活产生了严重的负面作用。目前,人们已经构建了一系列模型来研究谣言的传播动态。然而,现有研究大多忽略了谣言与反谣言之间的竞争关系,以及谣言传播过程中可能出现的情绪化倾向。在这项工作中,我们采用用户情绪感染理论和谣言与反谣言之间的竞争机制,构建了 "易感-暴露-感染-揭穿-恢复"(SEIDR)模型。此外,我们还研究了揭穿行为和不同情绪强度对谣言传播的影响。然后,根据 Routh-Hurwitz 稳定性准则计算了无谣言均衡和流行均衡的稳定性。最后,通过数值示例描述了不同参数的影响,并验证了理论结果的正确性。
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引用次数: 0
Efficient hydrogen evolution reaction performance of Ni substituted WS2 nanoflakes 镍取代 WS2 纳米片的高效氢进化反应性能
IF 2.5 Q2 MATERIALS SCIENCE, BIOMATERIALS Pub Date : 2024-11-11 DOI: 10.1007/s00339-024-08050-0
Anju Joseph, Levna Chacko, K. C. Sanal, Nayely Pineda-Aguilar, M. Jasna, Aldrin Antony, P. M. Aneesh

We have investigated the structural, optical and electrocatalytic hydrogen evolution reaction (HER) performance of pristine, Co and Ni substituted WS2 nanoflakes synthesised by facile hydrothermal method. The XRD pattern confirms the formation of hexagonal WS2 for both pristine and substituted WS2 nanoflakes. The FESEM images validate the flake-like structure for both pristine and substituted WS2. In addition, we have also analysed the Raman and UV-Vis absorbance spectra of the samples. The electrocatalytic studies reveal that the nickel-substituted WS2 (Ni-WS2) nanoflakes show superior hydrogen evolution (HER) performance compared to cobalt-substituted WS2 (Co-WS2) nanoflakes. Hence, we have varied the Ni concentration and investigated the dependence of Ni content on the electrocatalytic performance. It is found that the electrocatalytic performance of the Ni-WS2 nanoflakes increases with an increase in Ni content owing to the modified edge structures. Thus, our studies suggest Ni substitution in WS2 nanostructures can boost electrocatalytic HER performance.

我们研究了通过简便水热法合成的原始、钴和镍取代的 WS2 纳米片的结构、光学和电催化氢进化反应(HER)性能。XRD 图谱证实了原始 WS2 纳米片和替代 WS2 纳米片都形成了六边形 WS2。FESEM 图像验证了原始 WS2 和取代 WS2 的片状结构。此外,我们还分析了样品的拉曼光谱和紫外可见吸收光谱。电催化研究表明,与钴取代的 WS2(Co-WS2)纳米片相比,镍取代的 WS2(Ni-WS2)纳米片显示出更优越的氢进化(HER)性能。因此,我们改变了镍的浓度,并研究了镍含量对电催化性能的影响。结果发现,由于边缘结构的改变,Ni-WS2 纳米片的电催化性能随着 Ni 含量的增加而提高。因此,我们的研究表明,在 WS2 纳米结构中取代镍可以提高电催化 HER 的性能。
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引用次数: 0
Fringe projection profilometry based on deep learning phase demodulation combined with temporal phase unwrapping 基于深度学习相位解调与时相解包的边缘投影轮廓测量法
IF 2 Q2 MATERIALS SCIENCE, BIOMATERIALS Pub Date : 2024-11-11 DOI: 10.1007/s00340-024-08356-0
Ze Li, Jianhua Wang, Yixin Ji, Suzhen Wang, Wen Zhang, Shuo Shan, Yanxi Yang

In fringe projection profilometry (FPP), phase shifting profilometry (PSP) combined with temporal phase unwrapping (TPU) algorithms can be used to reliably obtain 3D information from complex measured scenes. However, collecting too many fringe patterns for phase demodulation reduces measurement efficiency. Some studies have shown that deep learning techniques can achieve phase demodulation on single-frame fringe pattern, suggesting that combining deep learning-based phase demodulation with TPU could potentially enable high-speed, high-precision 3D measurements. In this paper, we propose the FPP based on deep learning phase demodulation combined with TPU to achieve 3D measurements using only three fringe patterns. Furthermore, based on different network input strategies and TPU algorithms, the proposed method has four different implementation processes. Comparative experiments analyze the impact of different network input strategies, TPU algorithms, and network structures on the accuracy of phase demodulation and unwrapping. The results demonstrate that using multiple fringe patterns with different frequencies as a joint input significantly improves the phase demodulation accuracy for various frequencies, particularly for lower frequencies, compared to using a single pattern with a neural network. In contrast, enhancing the network structure alone yields relatively modest improvements in phase demodulation accuracy compared to adjusting the input strategy. By analyzing phase demodulation and unwrapping errors, this paper provides guidance on selecting the appropriate implementation process for the proposed method under varying levels of noise interference.

在条纹投影轮廓仪(FPP)中,相移轮廓仪(PSP)与时相解耦(TPU)算法相结合,可用于从复杂的测量场景中可靠地获取三维信息。然而,收集过多的条纹图案进行相位解调会降低测量效率。一些研究表明,深度学习技术可以在单帧条纹模式上实现相位解调,这表明将基于深度学习的相位解调与 TPU 相结合有可能实现高速、高精度的三维测量。在本文中,我们提出了基于深度学习的相位解调与 TPU 相结合的 FPP,只需使用三个条纹图案就能实现三维测量。此外,基于不同的网络输入策略和 TPU 算法,所提出的方法有四种不同的实现过程。对比实验分析了不同网络输入策略、TPU 算法和网络结构对相位解调和解包精度的影响。结果表明,与使用神经网络的单一模式相比,使用多个不同频率的条纹模式作为联合输入可显著提高不同频率的相位解调精度,尤其是低频。相比之下,与调整输入策略相比,单独增强网络结构对相位解调精度的改善相对较小。通过分析相位解调和解包误差,本文为在不同程度的噪声干扰下为拟议方法选择合适的实施过程提供了指导。
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引用次数: 0
ZnO-doped BiOCl nanoparticles for visible-light-driven photocatalysis 用于可见光驱动光催化的 ZnO 掺杂 BiOCl 纳米粒子
IF 2.5 Q2 MATERIALS SCIENCE, BIOMATERIALS Pub Date : 2024-11-11 DOI: 10.1007/s00339-024-08043-z
Nitin S. Choudhari, Ravindra U. Mene, Pranav P. Bardapurkar, Sanjaykumar N. Dalvi

The escalating presence of organic pollutants from industrial activities necessitates urgent measures for their degradation, given their adverse effects on environmental health and ecosystem equilibrium. This study explores the synthesis and characterization of bismuth oxychloride (BiOCl) and zinc oxide (ZnO)-doped BiOCl nanoparticles for enhanced photocatalytic applications. BiOCl, a versatile material with applications in various sectors including cosmetics, pharmaceuticals, and photocatalysis, was synthesized using a novel chemical approach devoid of thermal treatments. ZnO doping induced notable changes in the optical properties of BiOCl, leading to enhanced light absorption within the visible spectrum. Characterization techniques such as X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and UV-visible spectroscopy were employed to analyze the structural and optical properties of the synthesized materials. XRD analysis confirmed the crystalline nature of BiOCl and doped ZnO, while SEM revealed the morphology and microstructure of the nanoparticles. EDX analysis confirmed the elemental composition of the samples, indicating the presence of Bi, O, Cl, and Zn. UV-visible spectroscopy revealed a red shift in the absorption edge upon ZnO doping, with Tauc curves indicating a direct bandgap of 3.26 eV for BiOCl and 3.35 eV for ZnO-doped BiOCl. This research highlights the potential of ZnO-doped BiOCl nanoparticles as efficient photocatalysts for environmental remediation applications.

鉴于工业活动中有机污染物对环境健康和生态系统平衡的不利影响,有必要采取紧急措施降解这些污染物。本研究探讨了氧氯化铋(BiOCl)和氧化锌(ZnO)掺杂的 BiOCl 纳米粒子的合成和表征,以增强其光催化应用。BiOCl 是一种多用途材料,可应用于化妆品、医药和光催化等多个领域。氧化锌的掺杂使 BiOCl 的光学特性发生了显著变化,从而增强了对可见光谱内光的吸收。研究人员采用了 X 射线衍射(XRD)、拉曼光谱、扫描电子显微镜(SEM)、能量色散 X 射线光谱(EDS)和紫外可见光谱等表征技术来分析合成材料的结构和光学特性。XRD 分析证实了 BiOCl 和掺杂 ZnO 的结晶性质,而 SEM 则揭示了纳米颗粒的形态和微观结构。EDX 分析证实了样品的元素组成,表明其中含有 Bi、O、Cl 和 Zn。紫外可见光谱显示,掺杂 ZnO 后,吸收边发生了红移,陶氏曲线表明 BiOCl 的直接带隙为 3.26 eV,而掺杂 ZnO 的 BiOCl 为 3.35 eV。这项研究凸显了氧化锌掺杂的 BiOCl 纳米粒子作为高效光催化剂在环境修复应用中的潜力。
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引用次数: 0
Impact of Cr3+ substitution on Co0.5Ni0.25Mg0.25Fe2−xCrxO4 nano ferrites: structural and magnetic characteristics Cr3+ 取代对 Co0.5Ni0.25Mg0.25Fe2-xCrxO4 纳米铁氧体的影响:结构和磁特性
IF 2.5 Q2 MATERIALS SCIENCE, BIOMATERIALS Pub Date : 2024-11-11 DOI: 10.1007/s00339-024-08054-w
G. V. Lakshmikanth, P. Missak Swarup Raju, S. Velmurugan

Co0.5Ni0.25Mg0.25Fe2−xCrxO4 (x = 0.0, 0.05, 0.1, 0.15, 0.2, and 0.25) nano ferrites are studied with different Cr3+ concentrations in terms of their synthesis, magnetic properties, and crystal structure. The doped and undoped nanoferrites were prepared using sol-gel auto-combustion. Structural and magnetic research used XRD, FESEM, FTIR, and magnetic data. X-ray diffraction (XRD) patterns of the synthetic samples confirm the presence of a cubic symmetry, crystalline, single-phase spinel structure (Fd-3 m space group). The lattice constant is 8.452 to 8.384 A, and the typical crystallite size is 34 to 24 nm. According to morphology studies conducted with field emission scanning electron microscopy (FESEM), grain size increases with concentration. The FTIR spectra observed vibrational bands identify the tetrahedral and octahedral interstitial complexes in the spinel structure, hence validating the creation of the spinel phase. Additionally, the magnetic hysteresis loop data shows that the saturation magnetization decreases with increasing Cr3+ content.

研究了不同 Cr3+ 浓度的 Co0.5Ni0.25Mg0.25Fe2-xCrxO4(x = 0.0、0.05、0.1、0.15、0.2 和 0.25)纳米铁氧体的合成、磁性能和晶体结构。掺杂和未掺杂的纳米铁氧体均采用溶胶-凝胶自动燃烧法制备。结构和磁性研究使用了 XRD、FESEM、FTIR 和磁性数据。合成样品的 X 射线衍射(XRD)图证实了立方对称、结晶、单相尖晶石结构(Fd-3 m 空间群)的存在。晶格常数为 8.452 至 8.384 A,典型晶粒大小为 34 至 24 nm。利用场发射扫描电子显微镜(FESEM)进行的形貌研究表明,晶粒尺寸随浓度的增加而增大。傅立叶变换红外光谱观察到的振动带确定了尖晶石结构中的四面体和八面体间隙复合物,从而验证了尖晶石相的产生。此外,磁滞回线数据显示,饱和磁化率随着 Cr3+ 含量的增加而降低。
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引用次数: 0
Structural and magnetic behavior of Mn-doped SnO2 nanorods for diluted magnetic semiconductors 用于稀释磁性半导体的掺锰二氧化锡纳米棒的结构和磁性行为
IF 2.5 Q2 MATERIALS SCIENCE, BIOMATERIALS Pub Date : 2024-11-11 DOI: 10.1007/s00339-024-08022-4
K. S. Usha, G. Vijaya Prasath, Sang Yeol Lee

The electrical and magnetic properties of low-dimensional materials like nanorods with defect-free lattice structures are remarkable; yet, structural defects, whether introduced purposefully or inadvertently, significantly modify the magnetic property. Thus, the existence of various cation or anion vacancies and interstitials in SnO2 may alter their magnetic properties. In this study, Sn1 − xMnxO2 nanoparticles (x = 0.00, 0.02, 0.04, and 0.06) were synthesised using chemical co-precipitation. The XRD pattern shows that manganese (Mn) ions were successfully incorporated into the tetragonal rutile crystal structure of tin oxide (SnO2). The 445 cm− 1 band in FTIR spectra indicates Sn–O bond stretching vibrations. The SEM image of SnO2 shows that Mn inclusion forms nanorods. Sn, Mn, and O in EDX demonstrate the synthesized material’s purity. Photoluminescence peaks about 405 and 421 nm are caused by oxygen vacancies and tin interstitials. An X-ray photoemission spectroscopic analysis indicates a predominance of Sn4+ with a slight presence of Sn2+ valence states, attributed to oxygen vacancies, which leads to the formation of Mn4+ and Mn2+ states in the synthesized material. Mn doped SnO2 samples’ magnetization versus magnetic field (M–H) curves at ambient temperature showed that increasing Mn concentration from 2 to 6% effectively caused ferromagnetic behaviour owing to Mn ions’ dominant magnetic interaction. To get ferromagnetic characteristics in these materials, the Mn dopant concentration must be properly optimized. The ferromagnetic characteristics of pure and Mn-doped SnO2 diluted magnetic semiconductors have also been widely studied.

具有无缺陷晶格结构的纳米棒等低维材料的电学和磁学特性非常显著;然而,无论是有意还是无意引入的结构缺陷都会显著改变磁性能。因此,SnO2 中各种阳离子或阴离子空位和间隙的存在可能会改变其磁性能。本研究采用化学共沉淀法合成了 Sn1 - xMnxO2 纳米粒子(x = 0.00、0.02、0.04 和 0.06)。XRD 图谱显示,锰(Mn)离子成功地融入了氧化锡(SnO2)的四方金红石晶体结构中。傅立叶变换红外光谱中的 445 cm- 1 波段表示 Sn-O 键的伸缩振动。二氧化锡的扫描电镜图像显示,锰的加入形成了纳米棒。EDX 中的锡、锰和 O 证明了合成材料的纯度。405 和 421 纳米波长的光致发光峰是由氧空位和锡间隙引起的。X 射线光发射光谱分析表明,Sn4+ 价态占主导地位,而 Sn2+ 价态略有存在,这归因于氧空位,从而在合成材料中形成了 Mn4+ 和 Mn2+ 态。掺锰的二氧化锰样品在环境温度下的磁化与磁场(M-H)曲线显示,由于锰离子的磁相互作用占主导地位,将锰浓度从 2% 提高到 6%,可有效地产生铁磁性。要在这些材料中获得铁磁特性,必须适当优化掺杂锰的浓度。对纯二氧化锰和掺杂锰的二氧化锰稀磁半导体的铁磁特性也进行了广泛的研究。
{"title":"Structural and magnetic behavior of Mn-doped SnO2 nanorods for diluted magnetic semiconductors","authors":"K. S. Usha,&nbsp;G. Vijaya Prasath,&nbsp;Sang Yeol Lee","doi":"10.1007/s00339-024-08022-4","DOIUrl":"10.1007/s00339-024-08022-4","url":null,"abstract":"<div><p>The electrical and magnetic properties of low-dimensional materials like nanorods with defect-free lattice structures are remarkable; yet, structural defects, whether introduced purposefully or inadvertently, significantly modify the magnetic property. Thus, the existence of various cation or anion vacancies and interstitials in SnO<sub>2</sub> may alter their magnetic properties. In this study, Sn<sub>1 − x</sub>Mn<sub>x</sub>O<sub>2</sub> nanoparticles (x = 0.00, 0.02, 0.04, and 0.06) were synthesised using chemical co-precipitation. The XRD pattern shows that manganese (Mn) ions were successfully incorporated into the tetragonal rutile crystal structure of tin oxide (SnO<sub>2</sub>). The 445 cm<sup>− 1</sup> band in FTIR spectra indicates Sn–O bond stretching vibrations. The SEM image of SnO<sub>2</sub> shows that Mn inclusion forms nanorods. Sn, Mn, and O in EDX demonstrate the synthesized material’s purity. Photoluminescence peaks about 405 and 421 nm are caused by oxygen vacancies and tin interstitials. An X-ray photoemission spectroscopic analysis indicates a predominance of Sn<sup>4+</sup> with a slight presence of Sn<sup>2+</sup> valence states, attributed to oxygen vacancies, which leads to the formation of Mn<sup>4+</sup> and Mn<sup>2+</sup> states in the synthesized material. Mn doped SnO<sub>2</sub> samples’ magnetization versus magnetic field (M–H) curves at ambient temperature showed that increasing Mn concentration from 2 to 6% effectively caused ferromagnetic behaviour owing to Mn ions’ dominant magnetic interaction. To get ferromagnetic characteristics in these materials, the Mn dopant concentration must be properly optimized. The ferromagnetic characteristics of pure and Mn-doped SnO<sub>2</sub> diluted magnetic semiconductors have also been widely studied.</p></div>","PeriodicalId":2,"journal":{"name":"ACS Applied Bio Materials","volume":"130 12","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142598921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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