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A Combined Decision System for Critical Success Factors and Influential Parts of Blockchain Technology b区块链技术关键成功因素与影响部分的组合决策系统
IF 1.4 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-08-06 DOI: 10.1007/s40995-025-01844-8
Mehdi Ajalli

This paper aims to identify and evaluate the CSFs in the acceptance of blockchain technology (BCT) in Iranian Rubber Industry and rank the influential parts (IPs) of BCT in the Industry by the opinions of 120 experts and simultaneously applying fuzzy Delphi and SWARA (Step-wise Weight Assessment Ratio Analysis) and ARAS (A new additive ratio assessment). A developed model of the CSFs and IP of the BCT in the industry was proposed. The results indicate that 10 CSF from the 31 CSF have a very strong impact on the 9 parts. In the following, the weight of the CSFs was extracted. The analysis showed that the sixth CSFs, (F6: Cyber-Security, Trustable Collaborations and Reliability) was placed in first priority. Also, the 8th CSFs (F8: Experience and Knowledge), was ranked in last. At the end of the research, 9 IPs of the BCT in the Industry were evaluated. The final analysis proves that that the first part (A1: Customer Segments) is ranked first, and the eights part (A8; Key Partners) is ranked last. The proposed integrated conceptual model of this research can be very useful in identifying and evaluating the CSFs of BCT and the valuable IPs of this technology in the rubber industry and other related industries.

本文旨在识别和评价伊朗橡胶工业对区块链技术(BCT)接受的影响因素,并通过120名专家的意见,同时应用模糊德尔福和逐步权重评价比分析法(SWARA)和ARAS(一种新的添加剂比例评价法)对BCT在行业中的影响部分(IPs)进行排名。在此基础上,提出了BCT的CSFs和IP在业界的发展模型。结果表明,31个脑脊液中的10个脑脊液对9个部位的影响非常强。在下文中,提取csf的权重。分析表明,第六个CSFs (F6:网络安全、可信赖协作和可靠性)被放在首位。此外,第8项CSFs (F8: Experience and Knowledge)排名最后。在研究的最后,对行业内的9个BCT ip进行了评估。最终的分析证明,第一部分(A1: Customer Segments)排名第一,第八部分(A8; Key Partners)排名最后。本研究提出的综合概念模型可用于识别和评估BCT的CSFs以及该技术在橡胶工业和其他相关行业中的有价值的知识产权。
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引用次数: 0
Air Quality Index Prediction: Comparative Study Based on Various Hyper Parameter Tuning 空气质量指数预测:基于各种超参数整定的比较研究
IF 1.4 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-16 DOI: 10.1007/s40995-025-01842-w
Sazia Tabasum Mim, Faria Alam, Nusrat Sharmin

The optimization of machine learning models to air quality index (AQI) prediction through hyperparameter tuning is the main emphasis of this study. To help with health risk awareness and regulatory actions, AQIs are essential for evaluating and informing the public about air quality. To improve AQI predictions, machine learning models such as Decision Tree (DT), Random Forest (RF), eXtreme Gradient Boosting (XGBoost), Light Gradient Boosting Machine (LightGBM), and Multilayer Perceptron (MLP) have been used in the literature. Hyperparameters have a major impact on these models performance and must be carefully adjusted for best outcomes. In this paper, DT, RF, XGBoost, LightGBM, and MLP were fine-tuned using a variety of hyperparameter Optimization approaches, including Grid Search Cross-Validation (GridSearchCV), Random Search Cross-Validation (RandomSearchCV), Simulated Annealing (SA), and Genetic Algorithms (GA). The article provides a thorough analysis of different techniques, highlighting their effects on model efficiency and forecast accuracy. The results provide insightful information about the efficacy of various machine learning models and hyperparameter tuning strategies in the context of air quality forecasting. According to experimental findings, ensemble models such as XGBoost and LightGBM fared better than others in terms of computational efficiency and prediction accuracy. As compared to grid-based searches, evolutionary tuning techniques like GA and SA produced better parameter sets faster. The study concludes that XGBoost provides the best overall results for AQI forecasting when tweaked via GA, and that appropriate hyperparameter optimization greatly enhances model performance. These results offer important information for creating reliable prediction models that will aid in environmental monitoring and policy formation.

通过超参数调谐优化机器学习模型来预测空气质量指数(AQI)是本研究的重点。为了帮助提高健康风险意识和采取监管行动,空气质量指数对于评估和向公众通报空气质量至关重要。为了改进AQI预测,机器学习模型如决策树(DT)、随机森林(RF)、极端梯度增强(XGBoost)、光梯度增强机(LightGBM)和多层感知器(MLP)已在文献中使用。超参数对这些模型的性能有重大影响,必须仔细调整以获得最佳结果。在本文中,DT, RF, XGBoost, LightGBM和MLP使用各种超参数优化方法进行微调,包括网格搜索交叉验证(GridSearchCV),随机搜索交叉验证(RandomSearchCV),模拟退火(SA)和遗传算法(GA)。本文对不同的技术进行了深入的分析,强调了它们对模型效率和预测精度的影响。结果提供了关于空气质量预测背景下各种机器学习模型和超参数调整策略有效性的深刻信息。根据实验结果,XGBoost和LightGBM等集成模型在计算效率和预测精度方面都优于其他模型。与基于网格的搜索相比,像GA和SA这样的进化调优技术可以更快地产生更好的参数集。研究表明,通过遗传算法进行调整后,XGBoost提供了最佳的AQI预测结果,适当的超参数优化大大提高了模型的性能。这些结果为建立可靠的预测模型提供了重要信息,这些模型将有助于环境监测和政策制定。
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引用次数: 0
Commutativity of Prime Ring with Permuting Generalized ((alpha ,beta )) n-Derivation 具有置换广义((alpha ,beta )) n-导数的素环的交换性
IF 1.4 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-14 DOI: 10.1007/s40995-025-01835-9
Wasim Ahmed, Muzibur Rahman Mozumder, Adnan Abbasi

We study the commutativity of prime ring (mathfrak {R}) on the action of permuting maps says, permuting ((alpha ,beta )) n-derivations, and permuting generalized ((alpha ,beta )) n-derivations. In this paper, we also generalized the result of Ashraf (Southeast Asian Bull. Math. 38:321–332, 2014), Theorem 2.6). Further, we also investigate some more results on the mentioned permuting maps with the help of traces.

研究了素环(mathfrak {R})在置换映射、置换((alpha ,beta )) n导和置换广义((alpha ,beta )) n导作用下的交换性。在本文中,我们也推广了Ashraf(东南亚牛)的结果。数学。38:21 1 - 332,2014),定理2.6)。此外,我们还利用迹线对上述排列图进行了进一步的研究。
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引用次数: 0
Study the Anti-Corrosion Behavior of Gamma Alumina and Reduced Graphene Oxide on Native Acid Producing Bacterial Strain: A Comparative Study γ -氧化铝和还原氧化石墨烯对天然产酸菌的抗腐蚀行为的比较研究
IF 1.4 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-10 DOI: 10.1007/s40995-025-01843-9
Mohsen Markazi, Javad Shabani Shayeh, Behnam Rasekh

Microbiologically influenced corrosion (MIC) poses serious troubles in the oil and gas industry, resulting in both economic and environmental issues. The use of biocides and anti-corrosion materials is the main solution to control the bio-corrosion. Recently, nanomaterials have been introduced as a new generation of both biocides and anti-corrosions effective in controlling the bio-corrosion. In this study, the MIC effect of Clostridium and Citrobacter as an APB consortia was studied by electrochemical methods, and the anti-corrosion effects of graphene oxide and gamma alumina powder were conducted on ASTM106 grade B stainless steel alloy. The corrosion morphology was studied using surface analysis methods. The corrosion behavior of steel in different mediums including the presence and absence of Acid Producing Bacteria (APB) and the nanostructures was investigated via electrochemical impedance spectroscopy and Tafel polarization techniques. Corrosion test result indicated that the addition of the nanostructure increased the charge transfer resistance, resulting in the reduction of corrosion rate by 81–87 percent. This is attributed to preventing the production of biofilm by the nanostructure and the formation of a protective film in the presence of graphene oxide Nano-sheets. The optimized concentration for both was determined as 0.5 mg/mL.

微生物影响腐蚀(MIC)是油气行业面临的一个严重问题,既会造成经济问题,也会造成环境问题。使用杀菌剂和防腐材料是控制生物腐蚀的主要解决方案。近年来,纳米材料作为控制生物腐蚀的新一代杀菌剂和防腐剂被引入。本研究通过电化学方法研究了Clostridium和Citrobacter作为APB菌群的MIC效应,并研究了氧化石墨烯和γ -氧化铝粉末对ASTM106级B级不锈钢合金的防腐效果。采用表面分析方法对腐蚀形貌进行了研究。利用电化学阻抗谱和Tafel极化技术研究了钢在不同介质中的腐蚀行为,包括产酸菌(APB)的存在和不存在以及纳米结构的存在。腐蚀试验结果表明,纳米结构的加入增加了电荷传递阻力,使腐蚀速率降低了81 - 87%。这是由于纳米结构阻止了生物膜的产生,并且在氧化石墨烯纳米片的存在下形成了保护膜。两者的最佳浓度均为0.5 mg/mL。
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引用次数: 0
Robust and Second Order Accurate Numerical Schemes for Solving Volterra–Fredholm Integro-Differential Equations Involving a Small Parameter 求解小参数Volterra-Fredholm积分-微分方程的鲁棒二阶精确数值格式
IF 1.4 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-09 DOI: 10.1007/s40995-025-01841-x
A. Panda, J. Mohapatra, N. Raji Reddy

This study deals with efficient numerical schemes for solving singularly perturbed Volterra–Fredholm integro-differential equations. On the layer adapted Shishkin mesh, the numerical solution is calculated using the upwind finite difference scheme for the differential part and the quadrature rule for the integral parts. The method proves to be first-order convergent in the maximum norm. Then, using a post-processing technique we significantly enhance the accuracy from first-order to second order. Further, a hybrid scheme on the nonuniform mesh is also constructed and analyzed whose solution converges uniformly, independent of the perturbation parameter, and directly gives second order accuracy. The convergence analysis is carried out for all the schemes and the theoretical results are validated through some numerical tests. Finally, a comparison of the computational cost taken shows the efficiency of the proposed work.

本文研究了求解奇摄动Volterra-Fredholm积分微分方程的有效数值格式。在采用Shishkin网格的层上,对微分部分采用迎风有限差分格式,对积分部分采用正交规则进行数值求解。该方法在极大范数上是一阶收敛的。然后,使用后处理技术,我们将精度从一阶显著提高到二阶。在此基础上,构造并分析了非均匀网格上的混合格式,该格式的解均匀收敛,与扰动参数无关,并直接给出二阶精度。对所有方案进行了收敛性分析,并通过数值试验验证了理论结果。最后,通过计算成本的比较,证明了所提方法的有效性。
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引用次数: 0
Assessment of Phytoremediation Capacity and the Tolerance of Sorghum (Sorghum bicolor (L.) Moench) Seedlings to Hexavalent Chromium 高粱(Sorghum bicolor (L.))植物修复能力及耐受性评价Moench)幼苗到六价铬
IF 1.4 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-07 DOI: 10.1007/s40995-025-01838-6
Nail BenAmara, Mostefa Touati, Mohamed Hachi, Aissaoui Regadia, Brahimi Abdelkarim, Ahmed Hichem Hamzaoui, Hasna Ellouzi, Walid Zorrig

Hexavalent chromium (Cr (VI)), resulting from several industrial activities, has become a significant environmental concern due to its high levels in water, soil, and plant tissues. This study aimed to assess the ability of white sorghum (Poaceae) to tolerate and remediate Cr (VI)-contaminated soil. Plants were cultivated in plastic pots containing a mixture of (1:1:1) agricultural sand, soil, and compost, and were treated with different concentrations of chromium (0 PPM, 20 PPM, and 60 PPM). The main results revealed that chromium predominantly accumulated in the roots, with an accumulation rate of 184 mg/kg of dry matter. The bioaccumulation factor (BF) exceeded 1, accompanied by a high biomass production (12 g within 30 days). This indicates the capacity of sorghum seedlings to absorb and retain significant amounts of Cr (VI), likely through SO42− and HPO42− membrane transporters. Increased Cr concentrations induced a significant rise in cell electrolyte leakage, indicating the loss of cell membrane integrity. Additionally, exposure to chromium resulted in a significant increase in total soluble sugars and proline, as well as heightened activities of catalase (CAT) and peroxidase (POD) which serve to protect cellular components and mitigate damage from reactive oxygen species. The results from the correlation analysis and principal component analysis revealed a high degree of alignment with the analyses of individual traits, thereby validating the interrelationships among the parameters studied. These findings indicate that the tested sorghum variety can thrive in Cr (VI)-contaminated environments, effectively accumulate chromium in its roots, and convert it to its trivalent form, emphasizing its potential for phytoremediation. However, it is essential to ascertain the concentration of heavy metals in plants remains within recommended safe thresholds, particularly for plants that may enter the food chain.

六价铬(Cr (VI)),由于其在水、土壤和植物组织中的高含量,已成为一个重大的环境问题。本研究旨在评价白高粱(禾本科)对Cr (VI)污染土壤的耐受和修复能力。植物在塑料罐中种植,罐中含有(1:1:1)农用砂、土壤和堆肥的混合物,并用不同浓度的铬(0 PPM、20 PPM和60 PPM)进行处理。主要结果表明,铬主要在根系积累,干物质积累速率为184 mg/kg。生物积累因子(BF)超过1,生物量产量高(30天12 g)。这表明高粱幼苗吸收和保留大量Cr (VI)的能力,可能是通过SO42 -和HPO42 -膜转运体。铬浓度的增加导致细胞电解质泄漏显著增加,表明细胞膜完整性的丧失。此外,暴露于铬导致总可溶性糖和脯氨酸的显著增加,以及过氧化氢酶(CAT)和过氧化物酶(POD)的活性升高,过氧化氢酶(CAT)和过氧化物酶(POD)有助于保护细胞成分和减轻活性氧的损害。相关分析和主成分分析结果与个体性状分析结果高度一致,从而验证了所研究参数之间的相互关系。这些结果表明,所试高粱品种可以在Cr (VI)污染的环境中茁壮成长,并在其根部有效地积累铬,并将其转化为三价形式,强调了其植物修复的潜力。然而,必须确定植物中的重金属浓度保持在建议的安全阈值范围内,特别是可能进入食物链的植物。
{"title":"Assessment of Phytoremediation Capacity and the Tolerance of Sorghum (Sorghum bicolor (L.) Moench) Seedlings to Hexavalent Chromium","authors":"Nail BenAmara,&nbsp;Mostefa Touati,&nbsp;Mohamed Hachi,&nbsp;Aissaoui Regadia,&nbsp;Brahimi Abdelkarim,&nbsp;Ahmed Hichem Hamzaoui,&nbsp;Hasna Ellouzi,&nbsp;Walid Zorrig","doi":"10.1007/s40995-025-01838-6","DOIUrl":"10.1007/s40995-025-01838-6","url":null,"abstract":"<div><p>Hexavalent chromium (Cr (VI)), resulting from several industrial activities, has become a significant environmental concern due to its high levels in water, soil, and plant tissues. This study aimed to assess the ability of white sorghum (<i>Poaceae</i>) to tolerate and remediate Cr (VI)-contaminated soil. Plants were cultivated in plastic pots containing a mixture of (1:1:1) agricultural sand, soil, and compost, and were treated with different concentrations of chromium (0 PPM, 20 PPM, and 60 PPM). The main results revealed that chromium predominantly accumulated in the roots, with an accumulation rate of 184 mg/kg of dry matter. The bioaccumulation factor (BF) exceeded 1, accompanied by a high biomass production (12 g within 30 days). This indicates the capacity of sorghum seedlings to absorb and retain significant amounts of Cr (VI), likely through SO<sub>4</sub><sup>2−</sup> and HPO<sub>4</sub><sup>2−</sup> membrane transporters. Increased Cr concentrations induced a significant rise in cell electrolyte leakage, indicating the loss of cell membrane integrity. Additionally, exposure to chromium resulted in a significant increase in total soluble sugars and proline, as well as heightened activities of catalase (CAT) and peroxidase (POD) which serve to protect cellular components and mitigate damage from reactive oxygen species. The results from the correlation analysis and principal component analysis revealed a high degree of alignment with the analyses of individual traits, thereby validating the interrelationships among the parameters studied. These findings indicate that the tested sorghum variety can thrive in Cr (VI)-contaminated environments, effectively accumulate chromium in its roots, and convert it to its trivalent form, emphasizing its potential for phytoremediation. However, it is essential to ascertain the concentration of heavy metals in plants remains within recommended safe thresholds, particularly for plants that may enter the food chain.</p></div>","PeriodicalId":600,"journal":{"name":"Iranian Journal of Science and Technology, Transactions A: Science","volume":"49 6","pages":"1523 - 1535"},"PeriodicalIF":1.4,"publicationDate":"2025-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145625550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of Generalized Laguerre Polynomials in Solving Fractional Differential Equations 广义拉盖尔多项式在解分数阶微分方程中的应用
IF 1.4 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-02 DOI: 10.1007/s40995-025-01834-w
N. Goudarzian, M. Sh. Dahaghin, H. Hassani

In this article, a new class of basis functions called generalized Laguerre polynomials is introduced to solve equations in the form of the non-linear time fractional reaction-diffusion equation. To obtain a new numerical method, the fractional derivative in the equation is replaced using Caputo’s definition. Then, using operational matrices of fractional and ordinary derivatives, in order to improve the presented numerical method, the method of generalized Laguerre polynomials (GLPs) is introduced. The basis of obtaining an approximate solution in this method is that the approximate solution is considered as a linear combination of these basic functions in terms of coefficients and control parameters. By obtaining the values of coefficients and control parameters optimally using the method of Lagrange cofficients, the approximate solution is obtained. The advantage of this method is to use a small number of basis functions to obtain satisfactory results. On the other hand, the accuracy of the method is improved by increasing the number of sentences of basic functions. In the end, with the aim of confirming the correctness of the numerical results and proving the efficiency, we will test the GLPs method by presenting two examples.

本文引入了一类新的基函数——广义拉盖尔多项式,用于求解非线性时间分数阶反应扩散方程。为了得到一种新的数值方法,用卡普托的定义代替了方程中的分数阶导数。然后,利用分数阶导数和常阶导数的运算矩阵,引入了广义拉盖尔多项式(GLPs)方法,以改进现有的数值方法。该方法获得近似解的基础是将近似解视为这些基本函数在系数和控制参数方面的线性组合。利用拉格朗日系数法对各系数和控制参数进行最优求值,得到了近似解。该方法的优点是使用少量的基函数即可得到满意的结果。另一方面,通过增加基本功能句数来提高方法的准确率。最后,为了验证数值结果的正确性和效率,我们将通过两个实例对glp方法进行验证。
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引用次数: 0
Weighted Convergence and Applications to Approximation Theorems for Sequences of Monotone and Sublinear Operators 单调和次线性算子序列的加权收敛及其逼近定理的应用
IF 1.4 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-06-30 DOI: 10.1007/s40995-025-01839-5
Kamil Demirci, Fadime Dirik, Sevda Yıldız

In this paper, we utilize a convergence termed weighted convergence, which is expressed via weighted density. This extends asymptotic (also known in the literature as natural density and linear density) and logarithmic densities. We employ this to express and prove Korovkin-type theorems for sequences of operators that are monotone and sublinear (msLOs). To demonstrate the practical relevance of our results, illustrative examples that satisfy the conditions of our theorems are included. The rate of convergence for these msLOs is analysed using the modulus of continuity.

本文利用了一种称为加权收敛的收敛性,该收敛性用加权密度表示。这扩展了渐近密度(在文献中也称为自然密度和线性密度)和对数密度。我们用它来表示和证明单调和次线性算子序列的korovkin型定理。为了证明我们的结果的实际相关性,包括了满足我们的定理条件的说明性例子。用连续模量分析了这些最小线性网络的收敛速度。
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引用次数: 0
On the Commutant of Certain Multiplication Operators on Certain Banach Spaces of Functions 关于函数的某些巴拿赫空间上某些乘法算子的交换子
IF 1.4 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-06-26 DOI: 10.1007/s40995-025-01826-w
Mahshid Yarmohammadi, Bahram Khani Robati

Let (mathcal {X}) be a certain Banach space of analytic functions on the open unit disk (mathbb {D}) in the complex plane. Let p be an analytic polynomial and let (M_p) denote the operator of multiplication by p. Under certain conditions on p, we characterize the structure of the operator S such that (M_pS=SM_p). We determine the commutant of direct sum of certain multiplication operators on direct sum of certain spaces of functions. Assume that (psi) is an analytic automorphism of the unit disk, we also characterize the commutant of (M_{p(psi )}) under certain conditions on p.

设(mathcal {X})为复平面上开单元盘(mathbb {D})上解析函数的某个Banach空间。设p是一个解析多项式,设(M_p)表示与p相乘的算子。在p上的某些条件下,我们刻画了算子S的结构,使得(M_pS=SM_p)。我们确定了若干乘法算子在若干函数空间的直和上的对易性。假设(psi)是单位圆盘的解析自同构,我们也刻画了(M_{p(psi )})在一定条件下在p上的交换子。
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引用次数: 0
Influence of Potassium on Coke Formation and Catalytic Stability in the Propane Dehydrogenation Reaction Over Alkaline Modified Pt-Sn / γ-Al2O3 钾对碱性改性Pt-Sn / γ-Al2O3丙烷脱氢反应焦炭形成及催化稳定性的影响
IF 1.4 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-06-20 DOI: 10.1007/s40995-025-01845-7
Ghasem Kasaeian, Cavus Falamaki, Mehrdad Mozaffariana

Selective propane dehydrogenation is one of the commercialized technologies for the production of propylene and hydrogen. Here, alkaline (K) modified Pt-Sn /γ-Al2O3 catalysts were prepared via sequential incipient wetness impregnation method for the propane dehydrogenation reaction. They were characterized by BET, TEM, TPR, TPD-NH3, CO-dispersion, and TPO analysis’s. The catalytic performance towards propane dehydrogenation was assessed at an hourly gas space velocity of 10,000 cm3 (g.cat)−1 h− 1 at 580 °C up to 5 h time on stream at an absolute pressure of 1 bar. Results showed that the parent Pt-Sn/γ-Al2O3 catalyst exhibits 54.2% propane conversion at 580 °C with a poor selectivity towards propylene of 83.8%. Incorporation of K element generally increased selectivity towards propylene and decreased propane conversion. For a constant Pt and Sn content of 0.4 and 0.8 wt%, respectively, different catalysts with a K element content of 0.0, 0.3, 0.8, 1.5 and 2.5 wt% were synthesized. Optimal catalytic performance was observed for a 0.8 wt% K element content. Compared to the Pt-Sn/γ-Al2O3 sample, the optimum catalyst resulted in a 48.2% increase in propylene yield and a minimal decrease of only 3.6% in propane conversion.

丙烷选择性脱氢是生产丙烯和氢气的商业化技术之一。本文采用顺序湿浸渍法制备了碱性(K)改性Pt-Sn /γ-Al2O3催化剂,用于丙烷脱氢反应。通过BET、TEM、TPR、TPD-NH3、共分散和TPO分析对其进行了表征。对丙烷脱氢的催化性能进行了评估,在580°C下,每小时气体空间速度为10,000 cm3 (g.cat)−1 h−1,在绝对压力为1 bar的条件下运行5h。结果表明,母体Pt-Sn/γ-Al2O3催化剂在580℃下丙烷转化率为54.2%,丙烯选择性较差,为83.8%。K元素的加入通常增加了丙烯的选择性,降低了丙烷的转化率。在Pt和Sn含量分别为0.4和0.8 wt%的条件下,合成了K元素含量分别为0.0、0.3、0.8、1.5和2.5 wt%的催化剂。当K元素含量为0.8 wt%时,催化性能最佳。与Pt-Sn/γ-Al2O3样品相比,最佳催化剂使丙烯收率提高48.2%,丙烷转化率仅降低3.6%。
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引用次数: 0
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Iranian Journal of Science and Technology, Transactions A: Science
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