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Advances in modification approaches for Mg-based hydrogen storage materials 镁基储氢材料改性方法研究进展
Q3 Energy Pub Date : 2026-02-01 DOI: 10.1016/S1872-5813(25)60596-2
Shuang CHENG , Fei LI , Yuqi WANG , Xiangyi WANG , Sinan GUAN , Yi WANG , Yue WANG , Guancheng OU , Ming XU
As one of the most promising new energy sources, hydrogen energy is expected to usher in a full-fledged “hydrogen economy” in the 21st century. Compared with traditional high-pressure gaseous and cryogenic liquid hydrogen storage methods, solid-state chemical hydrogen storage shows significant advantages in safety, high efficiency, and cost-effectiveness. Magnesium-based lightweight hydrogen storage materials have attracted widespread attention due to their high gravimetric hydrogen storage density (7.6%) and favorable reversibility. However, their sluggish reaction kinetics and stringent operating conditions (with H2 release temperatures exceeding 350 °C and H2 absorption pressures above 4 MPa) pose major challenges for practical applications. Domestic and international researchers have conducted in-depth studies to address these issues, achieving substantial progress in the modification of magnesium-based hydrogen storage alloys. This paper systematically elaborates on major modification techniques such as alloying, nanostructuring, and catalytic material doping, providing a comprehensive analysis of the strengths and limitations of each approach. Furthermore, it offers prospects for the future development of magnesium-based hydrogen storage materials by integrating current theoretical and experimental research findings.
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氢能作为最具发展前景的新能源之一,有望在21世纪迎来全面的“氢经济”。与传统的高压气体和低温液态氢储存方法相比,固态化学储氢在安全、高效和成本效益方面具有显著优势。镁基轻质储氢材料因其较高的储氢密度(7.6%)和良好的可逆性而受到广泛关注。然而,它们缓慢的反应动力学和严格的操作条件(H2释放温度超过350℃,H2吸收压力超过4 MPa)对实际应用构成了重大挑战。国内外研究人员对这些问题进行了深入的研究,在镁基储氢合金的改性方面取得了实质性进展。本文系统地阐述了合金化、纳米结构和催化材料掺杂等主要改性技术,并对每种方法的优点和局限性进行了全面分析。结合目前的理论和实验研究成果,展望了镁基储氢材料的发展前景。下载:下载高分辨率图片(135KB)下载:下载全尺寸图片
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引用次数: 0
Revealing urban lingering pattern at lake front: A spatial information mapping approach through public participatory GIS 揭示滨湖城市滞留格局:基于公众参与式GIS的空间信息制图方法
IF 3.6 1区 艺术学 0 ARCHITECTURE Pub Date : 2026-02-01 DOI: 10.1016/j.foar.2025.03.012
Surabhi Mehrotra, Arshi Parashar, Yogesh K. Garg, Samiksha Muddamwar, Shefna Shihabudeen
“Urban lingering” implies an extended stay of users in urban public spaces, which has physical, emotional, and social benefits. In recent times, lingering in public spaces has been increasingly taken over by sedentary lifestyles and the growing influence of social media. Hence, this paper attempts to identify the key factors contributing to urban lingering in public spaces to enhance users' experiences during their stay. For this, contributing factors to urban lingering were identified from literature and measured in five selected recreational public spaces in Bhopal City, the capital of Madhya Pradesh in India. Relationships between Lingering Factor (LF) and contributing factors were then established for male and female users. Public Participatory Geographic Information System (PPGIS) and questionnaire surveys were employed for spatial mapping and perception modeling. The findings of primary surveys indicate that the feeling of safety, parking availability, pleasing design, and memorability of the public space together strongly influence LF across all user groups (R2 = 0.47, p value < 0.05). Data revealed that for male users, adequately sized spaces and lighting contribute to their lingering behavior (R2 = 0.56, p value < 0.05), whereas for female users, accessibility and activities in public spaces are significant contributors to their lingering (R2 = 0.48, p value < 0.05). The differences in the contributing factors to urban LF between male and female users confirm that users’ needs in public spaces thus present variation in preferences across space and the presented approach could be considered in planning infrastructure policies to enhance overall wellbeing.
“城市逗留”意味着使用者在城市公共空间中停留的时间延长,这具有身体、情感和社会效益。近年来,久坐不动的生活方式和社交媒体日益增长的影响力越来越多地取代了在公共场所逗留的习惯。因此,本文试图找出导致城市逗留在公共空间的关键因素,以提高用户在逗留期间的体验。为此,从文献中确定了城市逗留的影响因素,并在印度中央邦首府博帕尔市的五个选定的娱乐公共空间中进行了测量。在男性和女性用户中建立逗留因子与影响因素之间的关系。利用公众参与式地理信息系统(PPGIS)和问卷调查进行空间制图和感知建模。初步调查结果表明,安全感觉、停车可用性、令人愉悦的设计和公共空间的可记忆性共同强烈影响所有用户群体的LF (R2 = 0.47, p值<; 0.05)。数据显示,对于男性用户来说,适当大小的空间和照明有助于他们的逗留行为(R2 = 0.56, p值<; 0.05),而对于女性用户来说,公共空间的可达性和活动是他们逗留行为的重要因素(R2 = 0.48, p值<; 0.05)。男性和女性用户对城市LF的影响因素的差异证实了用户在公共空间的需求,因此在空间偏好上存在差异,本文提出的方法可以在规划基础设施政策时加以考虑,以提高整体幸福感。
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引用次数: 0
Spatial planning interventions for winter sunbathing: Optimizing neighborhood open spaces for the elderly in Jiande, China 冬季日光浴的空间规划干预:中国建德老年人社区开放空间的优化
IF 3.6 1区 艺术学 0 ARCHITECTURE Pub Date : 2026-02-01 DOI: 10.1016/j.foar.2025.04.008
Zhen Xu , Ziqun Lin , Lifei Wang , Ziqi Shang , Chayn Sun
As global aging accelerates, addressing older adults’ winter sunbathing—a culturally and significant practice enhancing well-being—remains underexplored in spatial planning. This study identifies and optimizes neighborhood open spaces (NOS) for winter sunbathing to improve elderly quality of life and social inclusion. We developed a framework integrating sunlight exposure (≥3 h), wind conditions (≤ 2 m/s), and walkability assessments. Analyzing 5.64 km2 of Jiande, China, we identified 495 climatically suitable NOS. Findings reveal stark spatial disparities: older neighborhoods offer better access, while newer gated developments face shortages, exacerbated by topography-driven east-west climatic divides. Over 75 % of elderly residents rely on small, fragmented spaces, with informal areas filling planning gaps. High-rise developments increase wind exposure, limiting outdoor activity and further restricting suitable NOS. The study underscores the potential of informal spaces, such as vacant lots and underutilized areas, in addressing planning deficiencies. It highlights the critical role of spatial planning interventions in promoting aging in place, equitable access, and climate-responsive urban design. The proposed framework offers a transferable approach for integrating climate-sensitive, age-friendly design into global urban planning, fostering healthier and more inclusive cities for aging populations.
随着全球老龄化的加速,老年人的冬季日光浴——一种文化上和重要的增强幸福感的做法——在空间规划中仍未得到充分探索。本研究确定并优化冬季日光浴的社区开放空间,以提高老年人的生活质量和社会包容性。我们开发了一个综合日照(≥3小时)、风力条件(≤2米/秒)和步行性评估的框架。通过对中国建德5.64 km2的分析,我们确定了495个气候适宜的NOS。研究结果显示了明显的空间差异:老社区提供了更好的通道,而新的封闭式开发项目面临短缺,地形驱动的东西气候差异加剧了这一问题。超过75%的老年居民依赖于小而分散的空间,非正式的区域填补了规划空白。高层发展增加了风的暴露,限制了户外活动,并进一步限制了合适的NOS。该研究强调了非正式空间(如空地和未充分利用的地区)在解决规划缺陷方面的潜力。它强调了空间规划干预在促进老龄化、公平获取和气候响应型城市设计方面的关键作用。拟议的框架提供了一种可转移的方法,将气候敏感型、老年人友好型设计纳入全球城市规划,为老年人打造更健康、更具包容性的城市。
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引用次数: 0
Public transport vs. private vehicles: Spatial heterogeneity of accessibility to urban centers 公共交通与私家车:城市中心可达性的空间异质性
IF 3.6 1区 艺术学 0 ARCHITECTURE Pub Date : 2026-02-01 DOI: 10.1016/j.foar.2025.05.001
Yanyi Zhu, Youpei Hu
Urban transportation systems critically influence energy consumption and carbon emissions. To evaluate urban accessibility, it is essential to systematically compare the spatiotemporal efficiency of public transport and private vehicles. However, traditional methods are limited by data acquisition and computation costs. This study proposes a novel, cost-effective framework using open-source map data and Python-based routing tools to compare the spatiotemporal efficiency of public transport and private vehicles. Utilizing real-time traffic data, we establish automated processing workflows to analyze spatial heterogeneity in accessibility across central urban areas of Nanjing, with comparisons to Shanghai and Hangzhou. Key findings include: (1) Taking Nanjing as a case study, the research evaluates public transport accessibility in eastern China's riverfront economic zone using key indicators like travel time ratios, advantage areas, and walking transfer time. Spatial differentiation maps were used to clearly delineate underdeveloped public transport areas in Nanjing; (2) Despite differences in urban form and structure, all three cities exhibit similar characteristics: comparable travel time ratios, concentration of public transport advantages within 10 km of the city center, and a notably high share of walking transfer time; (3) The framework provides a scalable tool for analyzing spatial accessibility heterogeneity, supporting evidence-based public transport policy development.
城市交通系统严重影响能源消耗和碳排放。为了评价城市可达性,有必要系统地比较公共交通和私家车的时空效率。然而,传统的方法受到数据采集和计算成本的限制。本研究提出了一个新颖的、具有成本效益的框架,使用开源地图数据和基于python的路由工具来比较公共交通和私家车的时空效率。利用实时交通数据,建立自动化处理流程,分析南京中心城区可达性的空间异质性,并与上海和杭州进行比较。主要研究成果包括:①以南京市为例,采用出行时间比、优势区域、步行换乘时间等关键指标对东部滨江经济带公共交通可达性进行评价。利用空间分异图对南京市公共交通欠发达区域进行了清晰的圈定;(2)尽管城市形态和结构存在差异,但3个城市的出行时间比相似,公共交通优势集中在市中心10 km以内,步行换乘时间占比明显较高;(3)该框架为空间可达性异质性分析提供了可扩展的工具,支持循证公共交通政策的制定。
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引用次数: 0
Energy absorption properties and failure modes of flexible UHMWPE foam protective sandwich structure subjected to low-velocity impact 低速冲击下柔性超高分子量聚乙烯泡沫保护夹层结构的吸能特性及破坏模式
IF 5.9 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-01 DOI: 10.1016/j.dt.2025.09.027
Xiaoke Liu , Kejing Yu , Pengwan Chen
Flexible materials play a crucial role in protecting against behind armour blunt trauma (BABT). However, their compliance complicates the understanding of failure mechanisms and energy absorption. This study used a combined experimental and numerical approach to investigate the response and failure modes of a flexible ultra-high-molecular-weight polyethylene (UHMWPE) foam protective sandwich structure (UFPSS) under low-velocity impact (LVI). A finite element (FE) model, accounting for nonlinear large deformation and strain-rate-dependent material behavior, was developed for a woven-UFPSS (featuring a plain-woven fabric structure) subjected to a 50 J impact. Experimental and numerical results showed strong agreement in peak force (error < 5%), maximum displacement (error < 6%), and buffer time (error < 8%). The impact's kinetic energy was mainly converted into internal energy of the fabric and foam materials (∼50%), viscous dissipation in the foam core (12%–15%), frictional work at the contact interfaces (5%–6%), and work by the pneumatic fixture clamping force (∼38%). This study provides the first investigation of the LVI performance of sandwich structures with all soft material layers, offering significant insights for the application of compliant materials in protective fields.
柔性材料在装甲钝性损伤防护中起着至关重要的作用。然而,它们的顺应性使对失效机制和能量吸收的理解复杂化。采用实验与数值相结合的方法,研究了柔性超高分子量聚乙烯(UHMWPE)泡沫保护夹层结构(UFPSS)在低速碰撞(LVI)下的响应与破坏模式。针对50 J的冲击,建立了考虑非线性大变形和应变率相关材料行为的有限元(FE)模型。实验和数值结果表明,峰值力(误差<; 5%)、最大位移(误差<; 6%)和缓冲时间(误差<; 8%)具有很强的一致性。冲击的动能主要转化为织物和泡沫材料的内能(~ 50%)、泡沫芯中的粘性耗散(12% ~ 15%)、接触界面处的摩擦功(5% ~ 6%)和气动夹具夹紧力的功(~ 38%)。本研究首次对全软质材料层夹层结构的LVI性能进行了研究,为柔性材料在防护领域的应用提供了重要的见解。
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引用次数: 0
Cascading failure modeling and survivability analysis of weak-communication underwater unmanned swarm networks 水下弱通信无人群网络级联故障建模及生存性分析
IF 5.9 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-01 DOI: 10.1016/j.dt.2025.09.022
Yifan Yuan , Xiaohong Shen , Lin Sun , Ke He , Yongsheng Yan , Haiyan Wang
Cascading failures pose a serious threat to the survivability of underwater unmanned swarm networks (UUSNs), significantly limiting their service ability in collaborative missions such as military reconnaissance and environmental monitoring. Existing failure models primarily focus on power grids and traffic systems, and don't address the unique challenges of weak-communication UUSNs. In UUSNs, cascading failure present a complex and dynamic process driven by the coupling of unstable acoustic channels, passive node drift, adversarial attacks, and network heterogeneity. To address these challenges, a directed weighted graph model of UUSNs is first developed, in which node positions are updated according to ocean-current–driven drift and link weights reflect the probability of successful acoustic transmission. Building on this UUSNs graph model, a cascading failure model is proposed that integrates a normal–failure–recovery state-cycle mechanism, multiple attack strategies, and routing-based load redistribution. Finally, under a five-level connectivity UUSNs scheme, simulations are conducted to analyze how dynamic topology, network load, node recovery delay, and attack modes jointly affect network survivability. The main findings are: (1) moderate node drift can improve survivability by activating weak links; (2) based-energy routing (BER) outperform based-depth routing (BDR) in harsh conditions; (3) node self-recovery time is critical to network survivability; (4) traditional degree-based critical node metrics are inadequate for weak-communication UUSNs. These results provide a theoretical foundation for designing robust survivability mechanisms in weak-communication UUSNs.
级联故障严重威胁着水下无人群网络(UUSNs)的生存能力,极大地限制了其在军事侦察和环境监测等协同任务中的服务能力。现有的故障模型主要集中在电网和交通系统上,并没有解决弱通信usn的独特挑战。在uusn中,级联故障是一个复杂的动态过程,由不稳定的声学通道、被动节点漂移、对抗性攻击和网络异质性耦合驱动。为了解决这些挑战,首先开发了uusn的有向加权图模型,其中节点位置根据洋流驱动的漂移更新,链路权重反映了声波成功传输的概率。在此UUSNs图模型的基础上,提出了一种级联故障模型,该模型集成了正常-故障-恢复状态循环机制、多种攻击策略和基于路由的负载重新分配。最后,在五级连接UUSNs方案下,通过仿真分析动态拓扑、网络负载、节点恢复延迟和攻击方式对网络生存能力的共同影响。研究结果表明:(1)适度的节点漂移可以通过激活薄弱环节来提高生存能力;(2)在恶劣条件下,基于能量路由(BER)优于基于深度路由(BDR);(3)节点自恢复时间对网络生存能力至关重要;(4)传统的基于度的关键节点指标不适用于弱通信usn。这些结果为设计弱通信uusn的鲁棒生存机制提供了理论基础。
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引用次数: 0
Command-agent: Reconstructing warfare simulation and command decision-making using large language models 命令代理:使用大型语言模型重建战争模拟和指挥决策
IF 5.9 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-01 DOI: 10.1016/j.dt.2025.09.004
Mengwei Zhang , Minchi Kuang , Heng Shi , Jihong Zhu , Jingyu Zhu , Xiao Jiang
War rehearsals have become increasingly important in national security due to the growing complexity of international affairs. However, traditional rehearsal methods, such as military chess simulations, are inefficient and inflexible, with particularly pronounced limitations in command and decision-making. The overwhelming volume of information and high decision complexity hinder the realization of autonomous and agile command and control. To address this challenge, an intelligent warfare simulation framework named Command-Agent is proposed, which deeply integrates large language models (LLMs) with digital twin battlefields. By constructing a highly realistic battlefield environment through real-time simulation and multi-source data fusion, the natural language interaction capabilities of LLMs are leveraged to lower the command threshold and to enable autonomous command through the Observe–Orient–Decide–Act (OODA) feedback loop. Within the Command-Agent framework, a multi-model collaborative architecture is further adopted to decouple the decision-generation and command-execution functions of LLMs. By combining specialized models such as DeepSeek-R1 and MCTool, the limitations of single-model capabilities are overcome. MCTool is a lightweight execution model fine-tuned for military Function Calling tasks. The framework also introduces a Vector Knowledge Base to mitigate hallucinations commonly exhibited by LLMs. Experimental results demonstrate that Command-Agent not only enables natural language-driven simulation and control but also deeply understands commander intent. Leveraging the multi-model collaborative architecture, during red-blue UAV confrontations involving 2 to 8 UAVs, the integrated score is improved by an average of 41.8% compared to the single-agent system (MCTool), accompanied by a 161.8% optimization in the battle loss ratio. Furthermore, when compared with multi-agent systems lacking the knowledge base, the inclusion of the Vector Knowledge Base further improves overall performance by 16.8%. In comparison with the general model (Qwen2.5–7B), the fine-tuned MCTool leads by 5% in execution efficiency. Therefore, the proposed Command-Agent introduces a novel perspective to the military command system and offers a feasible solution for intelligent battlefield decision-making.
随着国际事务的日益复杂,军事演习在国家安全中的重要性日益凸显。然而,传统的演练方法,如军事象棋模拟,效率低下,缺乏灵活性,在指挥和决策方面有特别明显的局限性。海量的信息和高决策复杂性阻碍了自主敏捷指挥控制的实现。为了应对这一挑战,提出了一种名为Command-Agent的智能战争仿真框架,该框架将大型语言模型(llm)与数字孪生战场深度集成。通过实时仿真和多源数据融合构建高度逼真的战场环境,利用llm的自然语言交互能力降低指挥阈值,并通过观察-定向-决定-行动(OODA)反馈回路实现自主指挥。在命令代理框架内,进一步采用多模型协同架构,将llm的决策生成和命令执行功能解耦。通过结合DeepSeek-R1和MCTool等专业模型,克服了单一模型能力的局限性。MCTool是一种轻量级的执行模型,专为军事函数调用任务进行了微调。该框架还引入了一个矢量知识库,以减轻法学硕士通常表现出的幻觉。实验结果表明,Command-Agent不仅能够实现自然语言驱动的仿真和控制,而且能够深刻理解指挥官的意图。利用多模型协同架构,在2 ~ 8架无人机的红蓝无人机对抗中,综合得分比单智能体系统(MCTool)平均提高41.8%,战损率优化161.8%。此外,与缺乏知识库的多智能体系统相比,向量知识库的加入进一步提高了整体性能16.8%。与通用模型(Qwen2.5-7B)相比,经过微调的MCTool的执行效率提高了5%。因此,该方法为军事指挥系统引入了一种新的视角,为战场智能决策提供了一种可行的解决方案。
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引用次数: 0
Interaction of nursing efficiency and spatial design in different departments: An agent-based modeling approach 不同科室护理效率与空间设计的互动:基于主体的建模方法
IF 3.6 1区 艺术学 0 ARCHITECTURE Pub Date : 2026-02-01 DOI: 10.1016/j.foar.2025.04.001
Xiaodong Xuan, Qi Wu, Leiming Yang, Wen Cao, Zixu Zhang, Yihe Zheng
The spatial design of nursing units can significantly enhance nurses' work efficiency. However, existing studies primarily focus on optimizing space for individual department, often overlooking the diverse spatial needs of different departments due to variations in work content. In this study, questionnaires were collected from 456 nurses across five departments of nursing units in 14 general hospitals, and semi-structured interviews and behavioral observations were conducted in the same five departments of nursing units in one hospital to assess spatial design and work efficiency, thus evaluating the impact of specialized design on departmental performance. Additionally, agent-based modeling (ABM) was utilized to simulate nursing efficiency in each department, comparing spatial arrangements before and after optimization by simulating nurses' behaviors. Results indicated obvious differences in spatial needs among departments, suggesting that standardized nursing unit designs fail to meet specific departmental needs, resulting in low satisfaction of nurses. Adjusting the spatial environments of nursing units based on departmental differences can improve efficiency. This study proposes optimization strategies for the spatial environments of nursing units in different departments, aiming to enhance nursing efficiency, job satisfaction, and reduce occupational stress.
护理单元的空间设计可以显著提高护士的工作效率。然而,现有的研究主要侧重于单个部门的空间优化,往往忽略了由于工作内容的变化,不同部门的空间需求存在差异。本研究通过对14家综合医院护理单位5个科室的456名护士进行问卷调查,并对某医院护理单位5个科室进行半结构化访谈和行为观察,评估空间设计和工作效率,从而评估专业化设计对科室绩效的影响。利用agent-based modeling (ABM)模拟各科室的护理效率,通过模拟护士行为,比较优化前后的空间安排。结果显示科室间空间需求存在明显差异,说明规范化护理单元设计不能满足科室需求,导致护士满意度较低。根据科室差异调整护理单元的空间环境,可以提高效率。本研究针对不同科室护理单元的空间环境提出优化策略,旨在提高护理效率、工作满意度、降低职业压力。
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引用次数: 0
Real-time decision support for bolter recovery safety: Long short-term memory network-driven aircraft sequencing 锚杆回收安全的实时决策支持:长短期记忆网络驱动的飞机排序
IF 5.9 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-01 DOI: 10.1016/j.dt.2025.09.038
Wei Han , Changjiu Li , Xichao Su , Yong Zhang , Fang Guo , Tongtong Yu , Xuan Li
The highly dynamic nature, strong uncertainty, and coupled multiple safety constraints inherent in carrier aircraft recovery operations pose severe challenges for real-time decision-making. Addressing bolter scenarios, this study proposes an intelligent decision-making framework based on a deep long short-term memory Q-network. This framework transforms the real-time sequencing for bolter recovery problem into a partially observable Markov decision process. It employs a stacked long short-term memory network to accurately capture the long-range temporal dependencies of bolter event chains and fuel consumption. Furthermore, it integrates a prioritized experience replay training mechanism to construct a safe and adaptive scheduling system capable of millisecond-level real-time decision-making. Experimental demonstrates that, within large-scale mass recovery scenarios, the framework achieves zero safety violations in static environments and maintains a fuel safety violation rate below 10% in dynamic scenarios, with single-step decision times at the millisecond level. The model exhibits strong generalization capability, effectively responding to unforeseen emergent situations—such as multiple bolters and fuel emergencies—without requiring retraining. This provides robust support for efficient carrier-based aircraft recovery operations.
舰载机回收作业的高动态性、强不确定性以及耦合的多重安全约束对实时决策提出了严峻挑战。本研究提出了一种基于深度长短期记忆q网络的智能决策框架。该框架将锚杆回收问题的实时排序转化为部分可观察的马尔可夫决策过程。它采用堆叠的长短期记忆网络来准确捕获螺栓事件链和燃料消耗的长期时间依赖性。并集成了优先级的经验重播训练机制,构建了安全、自适应的调度系统,能够进行毫秒级的实时决策。实验表明,在大规模质量回收场景下,该框架在静态环境下实现零安全违规,在动态场景下将燃料安全违规率保持在10%以下,单步决策时间为毫秒级。该模型显示出强大的泛化能力,能够有效地响应不可预见的紧急情况,如多个螺栓和燃料紧急情况,而无需再培训。这为有效的舰载飞机回收作业提供了强有力的支持。
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引用次数: 0
Research progress on the kinetics of methane-carbon dioxide reforming catalyzed by nickel-based catalysts 镍基催化剂催化甲烷-二氧化碳重整动力学研究进展
Q3 Energy Pub Date : 2026-02-01 DOI: 10.1016/S1872-5813(25)60609-8
Jingtao HU, Jie WU, Bangqiang DENG, Dawei LIU, Long XU
Under the backdrop of “Carbon Peak and Carbon Neutrality” (dual carbon) goal in China, the methane-carbon dioxide reforming reaction has attracted considerable attention due to its environmental benefits of converting two greenhouse gases (methane and carbon dioxide) into syngas and its promising industrial applications. Nickel (Ni)-based catalysts, with high catalytic activity, low cost, and abundant resources, are considered ideal candidates for industrial applications. In this article, three reaction kinetic models were briefly introduced, namely the Power-Law (PL) model, the Eley-Rideal (ER) model, and the Langmuir-Hinshelwood-Hougen-Watson (LHHW) model. Based on the LHHW model, the reaction kinetics and mechanisms of different catalytic systems were systematically discussed, including the properties of supports, the doping of noble metals and transition metals, the role of promoters, and the influence of the geometric and electronic structures of Ni on the reaction mechanism. Furthermore, the kinetics of carbon deposition and elimination on various catalysts were analyzed. Based on the reaction rate expressions for carbon elimination, the reasons for the high activity of transition metal iron (Fe)-doped catalysts and core-shell structured catalysts in carbon elimination were explained. Based on the detailed collation and comparative analysis of the reaction mechanisms and kinetic characteristics across diverse Ni-based catalytic systems, a theoretical guidance for the designing of high-performance catalysts was provided in this work.
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在中国“碳峰值和碳中和”(双碳)目标的背景下,甲烷-二氧化碳重整反应因其将两种温室气体(甲烷和二氧化碳)转化为合成气的环境效益和具有广阔的工业应用前景而备受关注。镍基催化剂具有催化活性高、成本低、资源丰富等优点,是工业应用的理想选择。本文简要介绍了三种反应动力学模型,即幂律(PL)模型、Eley-Rideal (ER)模型和Langmuir-Hinshelwood-Hougen-Watson (LHHW)模型。基于LHHW模型,系统地讨论了不同催化体系的反应动力学和反应机理,包括载体的性质、贵金属和过渡金属的掺杂、促进剂的作用以及Ni的几何和电子结构对反应机理的影响。此外,还分析了不同催化剂上碳沉积和消除的动力学。根据碳消除反应速率表达式,解释了过渡金属铁掺杂催化剂和核壳结构催化剂碳消除活性高的原因。通过对不同镍基催化体系的反应机理和动力学特性的详细整理和比较分析,为高性能催化剂的设计提供理论指导。下载:下载高清图片(182KB)下载:下载全尺寸图片
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