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Multi-step reservoir inflow prediction using a rolling window strategy and decomposed LSTM 基于滚动窗策略和分解LSTM的多步油藏流入预测
IF 4.3 Q1 WATER RESOURCES Pub Date : 2026-03-01 Epub Date: 2025-11-07 DOI: 10.1016/j.wse.2025.11.001
Wandee Thaisiam , Pongbavorn Rattanapant , Pawit Kraisornnukhor , Papis Wongchaisuwat
Effective management of multi-purpose reservoirs requires precise planning and accurate data to balance competing objectives and constraints. Reservoir inflow forecasting is critical in this process, with deep learning models increasingly applied across various time scales, from hourly to annual predictions. This study integrated a two-layer stacked long short-term memory network with decomposed data and a rolling window technique to enhance multi-day reservoir inflow forecasting accuracy. The proposed framework was applied to the Lam Takhong Dam in northeastern Thailand, a tropical monsoon region characterized by distinct wet and dry seasons. The dataset included daily reservoir inflow, river discharge, and average rainfall records spanning multiple years. Four forecasting strategies were compared for up to 7-d predictions: multi-step prediction, rolling prediction, multi-step prediction with decomposition, and rolling prediction with decomposition. The results indicated that while all models performed similarly for short-term predictions, accuracy declined over longer forecasting horizons. The rolling window approach with decomposition consistently outperformed others, achieving an average correlation coefficient of 0.92 and an average Nash–Sutcliffe model efficiency coefficient of 0.78 at the 7-d forecasting horizon. These findings demonstrate the practical advantages of integrating decomposition into a dynamic forecasting framework, particularly in reducing error accumulation in extended hydrological predictions.
多用途水库的有效管理需要精确的规划和准确的数据来平衡相互竞争的目标和制约因素。在这一过程中,油藏流入预测至关重要,深度学习模型越来越多地应用于各种时间尺度,从每小时到每年的预测。该研究将分解数据的两层堆叠长短期记忆网络与滚动窗口技术相结合,提高了多日水库入库预测的准确性。所提出的框架应用于泰国东北部的林塔洪大坝,这是一个以干湿季节明显为特征的热带季风区。该数据集包括每日水库入水量、河流流量和多年平均降雨量记录。比较了4种预测策略:多步预测、滚动预测、多步分解预测和滚动分解预测。结果表明,虽然所有模型在短期预测中表现相似,但在较长的预测范围内,准确性有所下降。带分解的滚动窗口方法一直优于其他方法,在7天预测范围内实现了平均相关系数0.92和平均纳什-苏特克利夫模型效率系数0.78。这些发现证明了将分解整合到动态预测框架中的实际优势,特别是在减少扩展水文预测中的误差积累方面。
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引用次数: 0
Biodiversity and water conservation challenges in urban blue–green infrastructure under climate extremes 极端气候条件下城市蓝绿色基础设施的生物多样性和水资源保护挑战
IF 4.3 Q1 WATER RESOURCES Pub Date : 2026-03-01 Epub Date: 2025-12-07 DOI: 10.1016/j.wse.2025.11.004
Pascaline Nyirabuhoro , Jean Claude Ndayishimiye , Ning Rui , Damir Saldaev , Yuri Mazei , Xiao-fei Gao
Urban blue–green infrastructure (UBGI) is essential to addressing urbanization challenges. However, its potential to mitigate climate extremes remains unclear. This study assessed biodiversity and water conservation challenges in UBGI using testate amoebae (TA) as indicators of ecosystem health. The studied UBGI consists of 0.67 km2 of forested hills and 3 668 m2 of ponds, located in the 55 800-km2 city cluster in the Pearl River Delta, South China. The analysis incorporated a two-year (June 2021 and June 2022) dataset, comprising TA records from 27 soil samples, 30 pond water samples, and 30 pond sediment samples; 27 microspatial factors, including five factors representing weather conditions (WC), eight factors for air quality (AQ), and 14 factors for water quality (WQ); and four climate extreme scenarios (heatwaves, droughts, typhoons, and floods). Biodiversity and water quality concerns linked to interactions between urban emissions and aquatic ecosystems within UBGI were illuminated in the following three key findings: (1) biotope connectivity enabled redistributions of soil-specific TA (six out of 42 species) along hillslopes (moisture gradient) and pond lengths (hydrological gradient); (2) TA showed strong biotope adaptation, with stochastic processes explaining 69.3% of community variations in water and 78.8% in sediment; and (3) UBGI showed limited effectiveness in mitigating urban emissions, such as CO and NH3, particularly when TA were adversely impacted by WC driven by climate extremes and when WQ was adversely influenced by AQ. The findings suggest that TA are reliable bioindicators, informing UBGI performance and supporting climate-resilient interventions to monitor cross-border pollution and its effects at the biotope level.
城市蓝绿基础设施是应对城市化挑战的关键。然而,它缓解极端气候的潜力仍不清楚。本研究利用遗存变形虫(TA)作为生态系统健康指标,评估了UBGI生物多样性和水资源保护面临的挑战。研究的UBGI由0.67 km2的森林丘陵和3 668 m2的池塘组成,位于中国南方珠江三角洲55800 km2的城市群。该分析纳入了一个为期两年(2021年6月和2022年6月)的数据集,包括27个土壤样本、30个池塘水样和30个池塘沉积物样本的TA记录;27个微空间因子,包括5个天气因子、8个空气质量因子和14个水质因子;以及四种极端气候情景(热浪、干旱、台风和洪水)。以下三个主要发现阐明了与城市排放和水生生态系统之间相互作用相关的生物多样性和水质问题:(1)生物群落连通性使土壤特异性TA(42个物种中的6个)沿着山坡(湿度梯度)和池塘长度(水文梯度)重新分布;(2) TA表现出较强的生境适应性,水体和沉积物群落的随机变化分别占69.3%和78.8%;(3)在缓解CO和NH3等城市排放方面,特别是当极端气候驱动的用水量对TA产生不利影响和AQ对WQ产生不利影响时,UBGI的有效性有限。研究结果表明,TA是可靠的生物指标,可以为UBGI的绩效提供信息,并支持气候适应型干预措施,以监测跨界污染及其在生物群落水平上的影响。
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引用次数: 0
Performance of different biocarriers in MBBR and SBBR systems for wastewater treatment: A review 不同生物载体在MBBR和SBBR污水处理系统中的性能研究进展
IF 4.3 Q1 WATER RESOURCES Pub Date : 2026-03-01 Epub Date: 2026-01-12 DOI: 10.1016/j.wse.2026.01.001
Krishna Kumar , Raman Sharma , S.K. Goyal
Biocarriers play a critical role in moving bed biofilm reactor (MBBR) and sequencing batch biofilm reactor (SBBR) wastewater treatment systems by providing surfaces for biofilm development. Although a wide variety of carrier materials and geometries are used, the literature remains fragmented, with most studies focusing on individual carriers and lacking a systematic understanding of how carrier characteristics govern treatment performance across different operational conditions. Additionally, review articles comparing biocarrier efficacy in synthetic wastewater systems are limited. This review article synthesizes the performance of various biocarriers in synthetic wastewater treatment and evaluates their efficiency in reducing chemical oxygen demand (COD), ammonia, and total nitrogen (TN). Reported removal efficiencies range from 68% to 96% for COD, up to 99% for ammonia, and 40.0%–97.5% for TN, depending on carrier design and reactor configuration. Carrier-specific surface areas typically range from 250 m2/m3 to 2 800 m2/m3. Analysis reveals that performance is significantly influenced by carrier features such as shape, material, surface roughness, porosity, and specific surface area. Notably, carriers with higher porosity and rough surfaces generally promote superior biofilm formation and pollutant removal, although optimization of surface area may compromise mechanical strength and long-term durability. Operational parameters, such as loading rate, filling ratio, and temperature, also interact with carrier design to determine overall treatment efficiency. While existing studies offer valuable insights, comparative research that links design parameters to treatment performance across varying conditions remains scarce. Future studies should prioritize quantifying relationships between carrier geometry, material properties, and biological activity, as well as developing standardized testing protocols to enable more reliable cross-study comparisons.
生物载体在移动床生物膜反应器(MBBR)和序批式生物膜反应器(SBBR)废水处理系统中发挥着至关重要的作用,为生物膜的形成提供了表面。尽管使用了各种各样的载体材料和几何形状,但文献仍然是碎片化的,大多数研究都集中在单个载体上,缺乏对载体特性如何在不同操作条件下影响处理性能的系统理解。此外,比较生物载体在合成废水系统中的功效的综述文章有限。本文综述了各种生物载体在合成废水处理中的性能,并评价了它们在降低化学需氧量(COD)、氨和总氮(TN)方面的效果。据报道,根据载体设计和反应器配置,COD去除率为68% ~ 96%,氨去除率为99%,TN去除率为40.0% ~ 97.5%。航母的比表面积通常在250 m2/m3到2 800 m2/m3之间。分析表明,载体的形状、材料、表面粗糙度、孔隙率和比表面积等特征对其性能有显著影响。值得注意的是,高孔隙率和粗糙表面的载体通常会促进更好的生物膜形成和污染物去除,尽管表面积的优化可能会损害机械强度和长期耐久性。操作参数,如装载率、填充率和温度,也与载体设计相互作用,以确定整体处理效率。虽然现有的研究提供了有价值的见解,但将设计参数与不同条件下的处理性能联系起来的比较研究仍然很少。未来的研究应优先量化载体几何形状、材料特性和生物活性之间的关系,并制定标准化的测试方案,以实现更可靠的交叉研究比较。
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引用次数: 0
Enhancing mean flow characteristics and reducing turbulence in channel transition using honeycomb 利用蜂窝技术提高平均流动特性,减少通道过渡湍流
IF 4.3 Q1 WATER RESOURCES Pub Date : 2026-03-01 Epub Date: 2025-12-22 DOI: 10.1016/j.wse.2025.12.005
Mustafa Alkayed , Behzad Lak , S. Samuel Li
An open-channel transition is needed in most water conveyance channels to connect channel sections with different cross-sectional shapes, areas, bottom slopes, or their combinations. However, these transitions inherently create adverse pressure gradients, flow separation, turbulent eddies, and energy losses, presenting a long-standing hydraulic issue. This study investigated a warped transition (WT), a transition type favored for its smooth linking geometry, which connected a small rectangular upstream channel section to a large downstream trapezoidal section, and evaluated the effectiveness of installing a honeycomb in the WT in reducing turbulence and improving flow characteristics and hydraulic efficiency. The three-dimensional velocity field of turbulent flow was measured using an acoustic Doppler velocimeter. The results showed that the honeycomb effectively improved mean flow properties by enhancing the uniformity of primary flow and reducing the strength of secondary currents and reversed flow. The cell size of the honeycomb limited the formation of larger energy-bearing turbulent eddies. Compared to a conventional WT without a honeycomb, the modified transition exhibited less severe flow separation and lower turbulence intensities. Implementing a honeycomb is a practical and inexpensive intervention for both existing and new transitions. The findings of this study provide valuable insights for improving the design of water conveyance channels.
在大多数输水河道中,为了连接具有不同横截面形状、面积、底部坡度或其组合的河道段,需要采用明渠过渡。然而,这些转变本身就会产生不利的压力梯度、流动分离、湍流涡流和能量损失,这是一个长期存在的水力问题。本研究研究了翘曲过渡(WT),这是一种以其光滑的连接几何形状而受到青睐的过渡类型,它将上游的小矩形段连接到下游的大梯形段,并评估了在WT中安装蜂窝在减少湍流和改善流动特性和水力效率方面的有效性。用多普勒测速仪测量了湍流的三维速度场。结果表明,蜂窝通过增强一次流的均匀性,降低二次流和逆流的强度,有效地改善了平均流动性能。蜂窝的单元大小限制了更大的承载能量的湍流漩涡的形成。与没有蜂窝的传统小波相比,改进的转捩表现出更小的流动分离和更低的湍流强度。对于现有的和新的转换,实现蜂窝是一种实用且廉价的干预。研究结果为改进输水渠道的设计提供了有价值的见解。
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引用次数: 0
Landslide dam breaching under combined hydraulic loads: Experimental insights into surge–overflow synergy 联合水力荷载下的滑坡溃坝:涌浪-溢流协同作用的实验见解
IF 4.3 Q1 WATER RESOURCES Pub Date : 2026-03-01 Epub Date: 2025-11-07 DOI: 10.1016/j.wse.2025.11.003
Jie Liu , Ming-jian Liao , Lei Fu , Dai-xin Deng , Hong Xiao
Landslide dam breaching poses severe threats to downstream communities and infrastructure, making the understanding of their failure mechanisms under complex hydraulic conditions crucial for disaster risk mitigation. This study systematically investigated the breaching hydraulics of a landslide dam under two scenarios: (1) overflow-only conditions and (2) combined surge wave and overflow conditions, through 12 controlled flume experiments (eight small-scale and four large-scale tests). Comparative analysis revealed critical differences in dam failure characteristics. Under overflow-only conditions, the breaching process followed conventional hydraulic erosion patterns, while the combined surge–overflow scenario exhibited significantly different behaviors. Experimental results showed that surge wave action increased total discharge by 2.3–4.9 times that in overflow-only conditions, and prolonged breach development. The interaction between surge waves and overflow produced complex hydrodynamics characterized by water level fluctuations, partial blockage, and reduced flow efficiency. Whether surge waves can trigger failure of a critically overtopped landslide dam depends on simultaneous satisfaction of three conditions: (1) ΔH > 0 (where ΔH is the difference between the highest surge wave level and effective dam height), (2) ξf/Wc > 0.092 (where ξf is the wave height of the first surge wave overtopping the dam and Wc is the dam crest width along the flow direction), and (3) NE > 10.5 (where NE is the number of effective secondary wave erosion events). The timing between surge arrival and overflow peak discharge predominantly controlled total outflow volume, with early surge-wave superposition causing the most severe discharge impacts. These findings provide a new quantitative framework for assessing landslide dam stability under complex loading conditions.
滑坡溃坝对下游社区和基础设施构成严重威胁,了解其在复杂水力条件下的溃坝破坏机制对减轻灾害风险至关重要。本研究通过12个控制水槽试验(8个小型试验和4个大型试验),系统研究了(1)单纯溢流和(2)涌波与溢流相结合两种情况下滑坡坝的溃坝水力特性。对比分析揭示了大坝溃坝特征的关键差异。仅溢流条件下,溃口过程遵循常规水力侵蚀模式,而浪涌-溢流联合条件下溃口行为明显不同。试验结果表明,浪涌波作用使总流量增加2.3 ~ 4.9倍,使决口发育时间延长。涌浪与溢流的相互作用产生了复杂的水动力,表现为水位波动、部分堵塞和流动效率降低。涌浪能否引发故障的严重滑坡坝越过取决于同时满足三个条件:(1)ΔH在0(ΔH是最高水击波水平之间的差异和有效的大坝高度),(2)ξf / Wc在0.092(ξf是第一涌波的波高超过大坝和Wc坝顶宽度沿流动方向),和(3)NE在10.5 (NE是有效的二级波侵蚀事件)的数量。涌浪到达和溢流峰值流量之间的时间控制了总流出量,早期涌浪叠加造成的流量影响最为严重。这些发现为评价复杂荷载条件下滑坡坝的稳定性提供了新的定量框架。
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引用次数: 0
Advances in coupling machine learning with hydrological simulation: A review 机器学习与水文模拟耦合研究进展综述
IF 4.3 Q1 WATER RESOURCES Pub Date : 2026-03-01 Epub Date: 2026-01-12 DOI: 10.1016/j.wse.2026.01.002
Yu-fei Yan , Han-xiao Liu , Shu Xu , Qiong-lin Wang , Yu-hui Yang , Qing-qing Chen , Chen-yang Wang , Tian-ling Qin
Accurate and efficient hydrological simulation is critically important to sustainable water resources management amidst escalating climate change. As an indispensable scientific tool, hydrological modeling employs mathematical frameworks and computational techniques to quantitatively characterize hydrological processes, thereby playing a vital role in water resources assessment, the prediction and management of extreme hydrological events, and climate change impact evaluation. This review article systematically synthesizes recent advances in traditional hydrological models while critically examining their inherent methodological limitations. It further delineates the evolutionary trajectory of machine learning (ML) techniques in hydrological simulation and highlights the comparative advantages of data-driven ML approaches over conventional paradigms. Through a rigorous analysis of contemporary research, this review article establishes that coupling physically-based hydrological models with data-driven ML architectures represents the most promising pathway for overcoming fundamental bottlenecks in hydrological simulation. Furthermore, this review article concludes by identifying persistent challenges within existing coupling frameworks and projecting key future research directions in this rapidly evolving field.
在气候变化日益加剧的背景下,准确、高效的水文模拟对水资源的可持续管理至关重要。水文建模作为一种不可或缺的科学工具,利用数学框架和计算技术对水文过程进行定量表征,在水资源评价、极端水文事件预测与管理、气候变化影响评价等方面发挥着重要作用。这篇综述文章系统地综合了传统水文模型的最新进展,同时严格审查了其固有的方法局限性。它进一步描述了水文模拟中机器学习(ML)技术的进化轨迹,并强调了数据驱动的ML方法相对于传统范例的比较优势。通过对当代研究的严格分析,这篇综述文章确立了将基于物理的水文模型与数据驱动的ML架构相结合是克服水文模拟基本瓶颈的最有希望的途径。此外,本文总结了现有耦合框架中持续存在的挑战,并预测了这一快速发展领域未来的关键研究方向。
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引用次数: 0
Integrating process-based and deep learning models for flood simulation in karst basins 基于过程和深度学习的喀斯特流域洪水模拟集成模型
IF 4.3 Q1 WATER RESOURCES Pub Date : 2026-03-01 Epub Date: 2025-12-03 DOI: 10.1016/j.wse.2025.11.005
Bin-quan Li , Yi-jie Xia , Si-ji Tao , Yun-yao Chen , Jian-fei Zhao , Zhong-min Liang
Flood process simulation in karst basins is challenging due to complex runoff generation and concentration mechanisms, often resulting in low accuracy. This study investigated two typical karst basins (the Maiweng and Liudong river basins) in Guizhou Province, China, and developed two hydrological models for flood simulation: the karst-Xin'anjiang (Karst-XAJ) model, a modified Xin'anjiang (XAJ) hydrological model adapted for karst runoff characteristics, and the long short-term memory (LSTM) deep learning model. Their performances were compared, and their results were integrated using Bayesian model averaging (BMA). The Karst-XAJ model accurately simulated flood peak time and runoff depth but showed limited peak flow accuracy. The LSTM model performed well within a 2-h computational window, with accuracy declining for longer computational windows (3–4 h) yet maintaining a Nash–Sutcliffe model efficiency coefficient above 0.7. The BMA approach further enhanced simulation accuracy beyond individual models. Overall, both models effectively captured flood dynamics in karst basins, with the LSTM model achieving superior precision. This study offers a novel framework for simulating flood processes in karst regions with complex runoff processes.
由于岩溶流域产流和集流机制复杂,其洪水过程模拟具有一定的挑战性,往往精度较低。本文以贵州省两个典型的喀斯特流域(麦云河流域和柳东河流域)为研究对象,建立了喀斯特-新安江(喀斯特-XAJ)水文模型、适应喀斯特径流特征的改进新安江(XAJ)水文模型和长短期记忆(LSTM)深度学习模型。对它们的性能进行比较,并使用贝叶斯模型平均(BMA)对结果进行综合。喀斯特- xaj模型能较好地模拟洪峰时间和径流深度,但洪峰流量精度有限。LSTM模型在2小时的计算窗口内表现良好,在更长的计算窗口(3-4小时)内精度下降,但仍保持Nash-Sutcliffe模型效率系数在0.7以上。BMA方法进一步提高了单个模型的仿真精度。总体而言,两种模型都能有效捕获喀斯特流域的洪水动态,其中LSTM模型的精度更高。该研究为模拟具有复杂径流过程的喀斯特地区的洪水过程提供了一个新的框架。
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引用次数: 0
External groundwater recharge of Tianchi Lake in Changbai Mountain 长白山天池地下水外源补给
IF 4.3 Q1 WATER RESOURCES Pub Date : 2026-03-01 Epub Date: 2025-12-22 DOI: 10.1016/j.wse.2025.12.003
Wang Wang , Jia-qi Chen , Jian-sheng Chen , Yi-tong Zhang
Water sources in volcanic regions have long been a focal point in hydrogeology. Tianchi Lake of the Changbai Mountain in Northeast China, the world's highest volcanic lake, has historically faced water imbalance issues. This study offered a comprehensive analysis of the water sources of Tianchi Lake, examining water volume, hydrodynamics, hydrochemistry, and isotopic evidence. Flow simulations of the Changbai Mountain waterfall during the glacial period indicated that besides local precipitation stored within the mountain during the non-freezing period, other groundwater sources were involved. Additionally, the volume of spring water and the geological structures in the Tianchi Lake area suggested that even expanding the watershed boundary cannot fully account for water balance within the region. Comparative analysis of hydrogen and oxygen isotopes in groundwater and local precipitation within the Changbai Mountain region revealed that external water recharged Tianchi Lake via deep circulation, sustaining the stable flow of Tianchi Lake and its surrounding springs. This study provides valuable insights into the mechanisms and recharge processes of groundwater circulation in volcanic regions.
火山地区的水源一直是水文地质学研究的热点。中国东北长白山的天池是世界上海拔最高的火山湖,历史上一直面临着水资源不平衡的问题。本研究从水量、水动力、水化学、同位素等方面对天池水源进行了综合分析。对长白山冰期瀑布的流量模拟表明,除了非冻结期的局地降水外,还涉及其他地下水来源。此外,天池地区的泉水体积和地质构造表明,即使扩大流域边界也不能完全解释区域内的水平衡。长白山地区地下水氢、氧同位素与局地降水对比分析表明,外部水通过深层循环补给天池,维持了天池及其周边泉水的稳定流动。该研究为火山区地下水循环的机理和补给过程提供了有价值的认识。
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引用次数: 0
Prediction of turbulent flow over a single square cylinder using generative artificial intelligence 利用生成式人工智能预测单个方形圆柱体上的湍流
IF 4.3 Q1 WATER RESOURCES Pub Date : 2026-03-01 Epub Date: 2025-12-29 DOI: 10.1016/j.wse.2025.12.004
Ngoc Thi Huynh , Anh Thu Thi Phan , Tan Tai Trieu , Ho Hong Duy Nguyen , Thanh Nhan Nguyen
Turbulent flow around bluff bodies like square cylinders involves complex vortex shedding and flow separation, challenging traditional computational methods. This study developed a novel approach using a generative artificial intelligence (GenAI) model to predict turbulent flow over a single square cylinder. The GenAI model was trained using high-fidelity simulation data generated from an advanced differentiable physics framework (PhiFlow), which can efficiently capture the nonlinear dynamics of turbulent flow. Flow predictions from the GenAI model were validated against numerical results, demonstrating high accuracy in capturing key flow characteristics, including vortex shedding frequency. Stability and spatial–temporal frequency analyses revealed strong agreement between the diffusion model and numerical simulations. This study highlights the potential of GenAI models to significantly enhance the prediction and analysis of turbulent flow, offering a powerful tool for fluid dynamics research and engineering applications.
方形圆柱体等钝体的紊流涉及复杂的旋涡脱落和流动分离,对传统的计算方法提出了挑战。本研究开发了一种新的方法,使用生成式人工智能(GenAI)模型来预测单个方形圆柱体上的湍流。GenAI模型使用先进的可微物理框架(PhiFlow)生成的高保真仿真数据进行训练,该框架可以有效地捕获湍流的非线性动力学。根据数值结果验证了GenAI模型的流动预测,证明了在捕获关键流动特征(包括旋涡脱落频率)方面的高精度。稳定性和时空频率分析表明,扩散模型与数值模拟结果非常吻合。本研究强调了GenAI模型在湍流预测和分析方面的潜力,为流体动力学研究和工程应用提供了强有力的工具。
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引用次数: 0
Trapping of cadmium(II) and nickel(II) from aqueous solutions using functionalized Albizia lebbeck seed pods: Isotherm, kinetic, and thermodynamic studies 利用功能化的小檗籽荚从水溶液中捕获镉(II)和镍(II):等温线、动力学和热力学研究
IF 4.3 Q1 WATER RESOURCES Pub Date : 2026-03-01 Epub Date: 2025-12-11 DOI: 10.1016/j.wse.2025.12.001
Alimoh Helen Alabi , Sarah Egbemolimi Lawanson , Peter Olusakin Oladoye , Mercy Wojuola , Kehinde Abiola Arasi , Kehinde Shola Obayomi
Heavy metal contamination poses significant risks to human health and ecosystems due to its persistence and high toxicity. Consequently, the urgent removal of heavy metals from the environment is imperative. This study evaluated the adsorptive performance of unmodified (UAPS) and citric acid modified (MAPS) Albizia lebbeck seed pods as low-cost adsorbents for removing Cd2+ and Ni2+ from aqueous solutions. The physicochemical properties of the adsorbents were characterized using Fourier transform infrared spectrometry and scanning electron microscopy to examine surface chemistry and morphology. Batch adsorption experiments were conducted to assess the effects of pH, initial metal ion concentration, adsorbent dosage, and contact time. Optimal adsorption occurred at pH of 2, with an equilibrium time of 15 min for both UAPS and MAPS. The Temkin model best described the experimental data, with UAPS exhibiting higher maximum adsorption capacities (2.587 mg/g for Cd2+ adsorption and 25.900 mg/g for Ni2+ adsorption) than MAPS (1.488 mg/g for Cd2+ adsorption and 1.400 mg/g for Ni2+ adsorption). Thermodynamic and kinetic analyses revealed that the adsorption process was spontaneous, endothermic, and well explained by the pseudo-second-order model. Adsorption–desorption experiments demonstrated strong adsorbent reusability over four cycles (with removal efficiencies greater than 60%). Overall, these findings indicate that UAPS is more effective in removing Cd2+ and Ni2+ and exhibits a stronger affinity for Ni2+.
重金属污染由于其持久性和高毒性,对人类健康和生态系统构成重大风险。因此,迫切需要从环境中清除重金属。本研究考察了未改性(UAPS)和柠檬酸改性(MAPS)合集子豆荚对水中Cd2+和Ni2+的吸附性能。采用傅里叶变换红外光谱法和扫描电镜对吸附剂的表面化学和形貌进行表征。通过批量吸附实验考察了pH、初始金属离子浓度、吸附剂用量、接触时间等因素对吸附效果的影响。UAPS和MAPS的最佳吸附条件为pH = 2,平衡时间均为15 min。Temkin模型最好地描述了实验数据,UAPS的最大吸附量(Cd2+吸附量为2.587 mg/g, Ni2+吸附量为25.900 mg/g)高于MAPS (Cd2+吸附量为1.488 mg/g, Ni2+吸附量为1.400 mg/g)。热力学和动力学分析表明,吸附过程是自发的,吸热的,并且可以用伪二阶模型很好地解释。吸附-解吸实验表明,吸附剂在四个循环中具有很强的可重复使用性(去除效率大于60%)。综上所述,这些发现表明UAPS在去除Cd2+和Ni2+方面更有效,并且对Ni2+具有更强的亲和力。
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Water science and engineering
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