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Study on Thermal Physical Properties of 304 Stainless Steel at High Temperature 304不锈钢高温热物理性能的研究
Pub Date : 2014-01-01 DOI: 10.1533/9780081002254.458
D. Fan
The DIL402Cthermal dilatometer and STA449Cthermal analyzer were employed to test the linear expansion and contraction coefficient,specific heat cpand DSC curve of 304stainless steel.The result shows that the range of linear expansion coefficient was 20.970 0×10-6~21.571 2×10-6 K-1 during heating and the range of linear contraction coefficient was 21.252 8×10-6~21.947 1×10-6 K-1 during cooling.The linear expansion and contraction coefficient were higher than other materials,so the 304stainless steel belong to the crack sensitive steel.The curve of cposcillates obviously during the 900~1 400℃as temperature raise.Because of the transformation of crystalline shape occurs,the defects of casting blank occur easily.A endothermic peak exists obviously at 1 420.8℃during the DSC test.The sample began to melt at 1 420.8℃and the peak temperature was 1 438.86℃in the heating step.The sample began to solidify at 1 439℃and the peak temperature was 1 435.6℃in the cooling step.During the 1 439~ 1 100℃as temperature fell,the curve of DSC was unsmooth,the thermostability was bad and phase change occurs. These factors cause the initial solidified shell non-homogeneous.These temperature points belong to the upper of crystallizer,so the casting blank causes crackle easily during this temperature range.
采用dil402c热膨胀仪和sta449c热分析仪对304不锈钢进行了热胀冷缩系数、比热系数和DSC曲线的测试。结果表明:加热时的线性膨胀系数范围为20.970 0×10-6~21.571 2×10-6 K-1,冷却时的线性收缩系数范围为21.252 8×10-6~21.947 1×10-6 K-1。304不锈钢的线胀系数和线缩系数均高于其他材料,属于裂纹敏感钢。在900~1 400℃温度范围内,随着温度的升高,温度曲线有明显的振荡。由于结晶形态的转变,铸件毛坯容易产生缺陷。DSC测试中,在1420.8℃处存在明显的吸热峰。样品在1 420.8℃开始熔化,加热阶段的峰值温度为1 438.86℃。样品在1 439℃开始凝固,冷却阶段的峰值温度为1 435.6℃。在1 439~ 1 100℃温度范围内,随着温度的下降,DSC曲线不光滑,热稳定性差,发生相变。这些因素导致初始凝固壳不均匀。这些温度点属于结晶器的上部,在此温度范围内铸件毛坯容易产生裂纹。
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中国有色冶金
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