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Performance comparison of full-scale ramjet and scramjet using boron-based propellant 采用硼基推进剂的全尺寸冲压发动机与超燃冲压发动机性能比较
IF 5.9 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-01 DOI: 10.1016/j.dt.2025.08.013
Xianju Wu , Zhijun Wei , Yun Wang , Ling zhou , Yunhui Wang , Ningfei Wang
This study investigates the performance boundaries of ramjet and scramjet engines fueled by boron-based propellant through full-scale engine modeling and three-dimensional computational fluid dynamics simulations. Results show that the performance boundary between ramjets and scramjets occurs near Mach 7. Specifically, at Mach 6, the ramjet exhibits a 1290 m/s higher specific impulse than the scramjet; however, at Mach 7, their performance becomes comparable. The ramjet's higher static temperature promotes boron particle vaporization and B2O2 dissociation, limiting the total temperature increase, unlike in scramjets. The boron vapor mass fraction significantly impacts this temperature difference, with ramjets exhibiting values 8.5 and 3.9 times higher than scramjets at Mach 6 and Mach 7, respectively. Despite lower total temperatures, ramjets achieve more efficient boron combustion due to the combined effects of higher pressures and longer particle residence times. These findings offer valuable insights for engine designers in selecting ramjet or scramjet configurations for boron-fueled propulsion systems.
通过全尺寸发动机建模和三维计算流体动力学仿真,研究了以硼基推进剂为燃料的冲压发动机和超燃冲压发动机的性能边界。结果表明,冲压发动机和超燃冲压发动机的性能边界出现在马赫数7附近。具体来说,在6马赫时,冲压发动机比超燃冲压发动机的比冲高1290 m/s;然而,在7马赫时,它们的性能变得相当。与超燃冲压发动机不同,冲压发动机较高的静态温度促进硼颗粒汽化和B2O2解离,限制了总温度的升高。硼蒸气质量分数对温度差异有显著影响,在6马赫和7马赫时,冲压发动机的温度差异分别是超燃冲压发动机的8.5倍和3.9倍。尽管总温度较低,但由于更高的压力和更长的颗粒停留时间的综合作用,冲压发动机可以实现更有效的硼燃烧。这些发现为发动机设计师在选择冲压发动机或超燃冲压发动机配置的硼燃料推进系统提供了有价值的见解。
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引用次数: 0
Electromagnetic dynamic self-piercing riveting (ED-SPR): A novel approach for enhanced dissimilar material joining 电磁动态自穿铆接(ED-SPR):一种增强异种材料连接的新方法
IF 5.9 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-01 DOI: 10.1016/j.dt.2025.09.028
Yuejie Cao , Xiaoyan Tang , Xiang Li , Zhonghuan Huang , Wenjie Yin , Xiangyu Huang , Hongtu Zhang , Zengqiang Cao
This study introduces electromagnetic dynamic self-piercing riveting (ED-SPR), an innovative technique that integrates electromagnetic riveting principles with static self-piercing riveting (S-SPR) for high-performance structural joints. A dedicated methodology and experimental apparatus for ED-SPR were systematically designed and validated. Quantitative comparative analyses between ED-SPR and S-SPR were conducted on three critical material combinations: CFRP/Al, low-strength steel HC340LA/Al, and high-strength steel DP590/Al. Key findings demonstrate that the electromagnetic-driven process reduces installation resistance by 60% and achieves a 30% larger interlock distance at the joint base compared to S-SPR. These quantitative advantages directly contribute to an approximately 30% increase in load-bearing capacity and superior damage tolerance in ED-SPR joints, as evidenced by tensile-shear testing of single-lap joints. Furthermore, distinct failure modes were observed: ED-SPR joints exhibited top plate pull-out failure in CFRP/Al and DP590/Al configurations, contrasting with the predominant rivet pull-out failure in S-SPR counterparts. Surface morphology and damage evolution were characterized via scanning electron microscopy (SEM) on post-assembly and tensile-failed specimens. The study establishes a foundation for optimizing electromagnetic-driven riveting parameters to mitigate CFRP delamination and further enhance joint reliability in vehicle body and aircraft fuselage structures.
本研究介绍了电磁动态自穿孔铆接(ED-SPR),这是一种将电磁铆接原理与静态自穿孔铆接(S-SPR)相结合的创新技术,用于高性能结构接头。系统地设计和验证了ED-SPR的专用方法和实验装置。对CFRP/Al、低强度钢HC340LA/Al和高强度钢DP590/Al三种关键材料组合进行了ED-SPR和S-SPR的定量比较分析。关键研究结果表明,与S-SPR相比,电磁驱动过程将安装阻力降低了60%,并使节口处的联锁距离增加了30%。这些数量上的优势直接导致ED-SPR接头的承载能力提高了约30%,并且具有优异的损伤容限,这一点在单搭接接头的拉伸-剪切试验中得到了证明。此外,还观察到不同的破坏模式:CFRP/Al和DP590/Al配置的ED-SPR节点表现出顶板拔出破坏,与S-SPR对应的铆钉拔出破坏形成鲜明对比。通过扫描电子显微镜(SEM)对组装后和拉伸破坏试样的表面形貌和损伤演化进行了表征。该研究为优化电磁驱动铆接参数,减轻碳纤维布脱层,进一步提高车身与机身结构的连接可靠性奠定了基础。
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引用次数: 0
Hypervelocity impact response and protection for the track steels of rocket sled system via light-gas gun experiments 火箭滑橇系统轨道钢的超高速冲击响应及防护
IF 5.9 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-01 DOI: 10.1016/j.dt.2025.09.016
Siwei Zhao , Yi Zeng , Xuewen Zhou , Weixing Zhao , Botao Xie , Jianbin Jing , Yan Chen , Yilun Liu
Hypervelocity rocket sled systems are critical for testing advanced military technologies, yet track damage at speeds exceeding Mach 5 remains a significant challenge for system reliability and performance. In this study, we investigated the hypervelocity impact response and protection for high-strength U71Mn or bainitic steel used in rocket sled tracks. Flyer plate impact experiments using a two-stage light-gas gun were conducted to study the hypervelocity collision response, followed by the microstructural characterization via optical microscope, scanning electron microscopy equipped with electron backscatter diffraction to reveal underlying damage mechanisms. Then, the calibrated thermal-mechanical coupled finite element simulations using the Johnson-Cook constitutive model and Mie-Grüneisen equation of state were carried out. Results indicated that bainitic steel exhibits superior impact resistance with predominantly smooth scratch-dominated damage due to its higher ductility. In contrast, U71Mn suffered significant material spallation and crack propagation arising from brittle fracture mechanisms. Zinc-rich epoxy primer coatings effectively mitigated stress concentration and temperature rise in the substrate at impacting velocities below 2.4 km/s, so as to suppress the microstructural damage such as adiabatic shear bands and dynamic recrystallization. However, coating protection diminished at ultra-high-speed impacts due to the coating failure. Dimensional analysis established quantitative relationships of the gouge damage size to projectile mass, impact velocity, and material yield strength. This study provides in-depth insights into damage mechanisms in hypervelocity rail systems, demonstrating that bainitic steel combined with protective coatings can significantly enhance impact resistance and system reliability, offering valuable guidance for the design and optimization of hypervelocity testing platforms.
超高速火箭滑橇系统对于测试先进的军事技术至关重要,然而,超过5马赫的速度对系统可靠性和性能来说仍然是一个重大挑战。本文研究了高强度U71Mn和贝氏体钢用于火箭滑轨的超高速冲击响应和防护性能。利用两级光气枪对飞片进行了超高速撞击实验,并利用光学显微镜、扫描电镜和电子背散射衍射技术对飞片进行了微观结构表征,揭示了飞片的损伤机理。然后,采用Johnson-Cook本构模型和mie - gr neisen状态方程进行了标定后的热-力耦合有限元模拟。结果表明,贝氏体钢具有较高的延展性,具有较好的抗冲击性能,损伤以光滑划痕为主。相比之下,U71Mn由于脆性断裂机制出现了明显的材料剥落和裂纹扩展。富锌环氧底漆能有效减缓冲击速度低于2.4 km/s时基体中的应力集中和温升,从而抑制绝热剪切带和动态再结晶等微观组织损伤。然而,由于涂层失效,涂层保护在超高速撞击下减弱。量纲分析建立了凿击损伤尺寸与弹丸质量、冲击速度和材料屈服强度之间的定量关系。本研究深入探讨了超高速轨道系统的损伤机理,表明贝氏体钢结合防护涂层可显著提高系统的抗冲击性和可靠性,为超高速试验平台的设计和优化提供了有价值的指导。
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引用次数: 0
Characterization of ultrahigh-strain-rate compressive behaviors in single 10-μm scale fibers using a micro-scale Hopkinson bar method 微尺度Hopkinson棒法表征10 μm单纤维的超高应变速率压缩行为
IF 5.9 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-01 DOI: 10.1016/j.dt.2025.09.023
Liang Ma , Lingxin Hu , Haoxiang Wang , Yichao Yuan , Jian Wei , Xiaoxin Zhao , Kunkun Zeng , Yuze Zhao , Zhiyin Zhao , Jiagui Liu , Shizhao Chen , Jinling Gao
High-performance fiber fabrics and composites experienced transverse compression deformation at ultrahigh strain rates near the impact point when subjected to high-velocity impacts, which significantly affected their ballistic limits. In this paper, a fiber-scale experimental method for characterizing ultrahigh strain-rate transverse compression behavior was proposed. To begin with, in order to measure the extremely low stress and strain in small specimens, the conventional Hopkinson bar was reduced to the hundred-micron scale, thereby achieving wave impedance matching with single fibers. In addition, tangential and normal laser Doppler velocimetry (LDV) methods were employed to realize non-contact, high-precision, and high-speed axial velocity measurements of micron-scale incident and transmission bars, respectively. Meanwhile, a microscopic observation system was used to facilitate the installation of miniature fiber samples. The experimental setup and procedures were introduced, and the system accuracy was verified through sample-free loading tests based on one-dimensional stress wave propagation theory. Dynamic compression experiments on Graphene-UHMWPE fibers were carried out, followed by post-compression microstructural characterization via scanning electron microscopy (SEM). Results demonstrated that successful mechanical characterization was achieved at strain rates exceeding 105, an order of magnitude higher than the previously reported maximum rates. Furthermore, during the loading process, the fibers underwent uniform compression deformation while exhibiting pronounced strain-rate effects. This method offers a novel approach for dynamic mechanical characterization of microscale single fibers, enabling the development of comprehensive strain-rate-dependent material models to guide the design of advanced composites and high-performance fibers.
高性能纤维织物和复合材料在受到高速撞击时,在撞击点附近以超高应变率发生横向压缩变形,这显著影响了其弹道极限。本文提出了一种表征超高应变率横向压缩特性的纤维尺度实验方法。首先,为了测量小试件的极低应力应变,将传统的霍普金森杆缩小到百微米尺度,从而实现与单纤维的波阻抗匹配。此外,采用切向激光多普勒测速法和法向激光多普勒测速法分别实现了微米尺度入射杆和透射杆的非接触、高精度和高速轴向速度测量。同时,为了方便微型纤维样品的安装,采用了显微观察系统。介绍了试验装置和步骤,并通过基于一维应力波传播理论的无试样加载试验验证了系统的准确性。对石墨烯-超高分子量聚乙烯纤维进行了动态压缩实验,并通过扫描电镜(SEM)对压缩后的微观结构进行了表征。结果表明,在应变速率超过105(比先前报道的最大速率高一个数量级)的情况下,成功地实现了力学表征。此外,在加载过程中,纤维表现出均匀的压缩变形,并表现出明显的应变率效应。该方法为微尺度单纤维的动态力学表征提供了一种新的方法,使综合应变率相关材料模型的发展能够指导高级复合材料和高性能纤维的设计。
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引用次数: 0
Reimagining tourism pedestrian street aesthetics through machine learning: Understanding the role of spatial form based on a case study in Luoyang, China 通过机器学习重塑旅游步行街美学:理解空间形式的作用——以中国洛阳为例
IF 3.6 1区 艺术学 0 ARCHITECTURE Pub Date : 2026-02-01 DOI: 10.1016/j.foar.2025.06.001
Xin Gao , Hirofumi Ueda , Meng Qu , Guang Li , Xiaojin Li , Menglin Xu
Pedestrian streets are vital for urban livability, tourism, and cultural identity. This research examines how human-perspective spatial form influences aesthetic perception, using a tourist street in central Luoyang as a case site. Based on perceptual evaluations from participants in Luoyang and Xi'an, the research isolates key structural elements and reveals the underlying relationship between spatial form and tourist aesthetic preferences. Deep learning models were used to extract spatial indicators from real-world streetscapes, aligning them with abstracted representations. Modelling the extracted indicators with a Generalized Additive Model (GAM), the study enables large-scale analysis and captures both individual spatial characteristics and their interactive effects on aesthetic perception. This approach not only models complex nonlinear relationships but also provides a solid foundation for aesthetic prediction and assessment. The findings identify the proportion of sky (PS), ground area (PG), and spatial depth (D) as key factors influencing aesthetic judgments, while the proportion of vertical elements (PV) and the ground-to-vertical ratio (G/V) show high multicollinearity. Additionally, street-level average aesthetics tend to be rated higher than point-wise average aesthetics. These insights allow for the layout and adjustment of spatial form by balancing the aesthetic preferences of local and non-local visitors, ultimately enhancing pedestrian street aesthetics.
步行街对城市宜居性、旅游和文化认同至关重要。本研究以洛阳市中心的一条旅游街道为案例场地,探讨以人为视角的空间形态如何影响审美感知。基于洛阳和西安参与者的感知评价,研究分离了关键的结构要素,揭示了空间形式与游客审美偏好之间的潜在关系。使用深度学习模型从现实世界的街景中提取空间指标,并将其与抽象表征对齐。该研究利用广义可加模型(GAM)对提取的指标进行建模,实现了大规模分析,并捕获了个体空间特征及其对审美感知的交互影响。该方法不仅对复杂的非线性关系进行了建模,而且为美学预测和评价提供了坚实的基础。结果表明,天空比例(PS)、地面面积比例(PG)和空间深度比例(D)是影响审美判断的关键因素,而垂直元素比例(PV)和地垂比(G/V)表现出高度的多重共线性。此外,街道水平的平均美学往往比点平均美学更高。这些见解允许通过平衡本地和非本地游客的审美偏好来布局和调整空间形式,最终增强步行街的美学。
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引用次数: 0
A cultural geographic perspective on the site selection of Tibetan Buddhist monasteries in mountainous regions of China 中国山区藏传佛教寺院选址的文化地理学视角
IF 3.6 1区 艺术学 0 ARCHITECTURE Pub Date : 2026-02-01 DOI: 10.1016/j.foar.2025.04.010
Yange Wang, Pengju Zhang
The site selection of Tibetan Buddhist monasteries in ancient China was determined by a comprehensive evaluation of multiple factors, and numerous studies have demonstrated that religious culture and geography play major roles; however, this information is primarily derived from qualitative research or case studies. In this paper, based on the locations of 1307 Tibetan Buddhist monasteries in mountainous regions of China, we quantified 11 cultural and geographical factors and applied clustering and principal component analysis to explore the factors influencing site selection. The results indicate that Tibetan Buddhist monasteries in mountainous regions of China can be classified into 3 clusters based on the determinants of their site selection, which correspond to the 3 primary functional uses of monasteries, and they showed distinct site selection considerations of geographical factors. Cluster 1 demonstrates adaptive alignment with plateau topography, with aspect, slope and altitude as primary factors, cluster 2 prioritizes accessibility for lay worshippers, prioritizing proximity to water sources, transportation networks and settlements, cluster 3 emphasizes spiritual isolation for monastic purification, predominantly influenced by sunlight priority in the morning. Unlike earlier research, this study revealed the influence of religious culture on the site selection of Tibetan Buddhist monasteries are not statistically significant. These results serve as a new reference for the study of Tibetan Buddhist monastery site selection.
中国古代藏传佛教寺院的选址是多种因素综合评价的结果,大量研究表明,宗教文化和地理因素在其中起主要作用;然而,这些信息主要来自定性研究或案例研究。本文以中国山区1307座藏传佛教寺院为研究对象,量化了11个文化和地理因素,运用聚类和主成分分析方法探讨了影响寺院选址的因素。研究结果表明,根据藏传佛教寺院选址的决定因素,中国山地藏传佛教寺院可划分为3个集群,对应于寺院的3种主要功能用途,并表现出不同的地理因素选址考量。集群1展示了与高原地形的适应性对齐,以朝向、坡度和海拔为主要因素;集群2优先考虑外行信徒的可达性,优先考虑靠近水源、交通网络和定居点;集群3强调寺院净化的精神隔离,主要受早晨阳光的优先影响。与以往的研究不同,本研究发现宗教文化对藏传佛教寺院选址的影响不具有统计学意义。研究结果为藏传佛教寺院选址研究提供了新的参考。
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引用次数: 0
Investigating visual stress within family and domestic violence refuges in Australia 调查澳大利亚家庭和家庭暴力庇护所内的视觉压力
IF 3.6 1区 艺术学 0 ARCHITECTURE Pub Date : 2026-02-01 DOI: 10.1016/j.foar.2025.05.004
Heather Mitcheltree , Cleo Valentine , Ian Hosking , Arnold Wilkins , Minna Sunikka-Blank , Koen Steemers
Family and domestic violence (FDV) is an issue that impacts on the health and wellbeing of women and children worldwide. Research shows that trauma-exposed individuals commonly experience heightened sensitivity to sensory triggers within the environmental milieu. Despite interest in trauma-informed design, the impact of visual stress has largely gone unexplored in the design of FDV refuges. This research utilises a novel visual stress analysis tool (ViStA) to examine the presence of potential visual stressors within two purpose-built FDV refuges in Australia. ViStA enables an assessment of visual stress, taking into account the complex interplay of size, spatial frequency, duty cycle, and contrast in the overall visual experience. Through an analysis of refuge images (n = 60), this study mapped the presence potential visual stressors. Through this analysis it was found that ‘high contrast linear elements’ were the most common potential visual stressors in both refuges. Common features among the spaces with the highest peak residuals were “perforated panelling” and “highly patterned surfaces”. Additionally, visual stressors were able to be categorised into eight primary functional categories of architectural features. The exploratory nature of this research underlines its importance as a foundational step towards developing evidence-based design practices for trauma-informed environments.
家庭和家庭暴力是一个影响全世界妇女和儿童健康和福祉的问题。研究表明,创伤暴露的个体通常对环境中的感官触发物高度敏感。尽管人们对创伤性设计很感兴趣,但在FDV避难所的设计中,视觉压力的影响在很大程度上没有得到探索。本研究利用一种新颖的视觉压力分析工具(ViStA)来检查澳大利亚两个专门建造的FDV避难所中潜在视觉压力源的存在。ViStA能够评估视觉压力,考虑到整体视觉体验中尺寸、空间频率、占空比和对比度的复杂相互作用。通过对避难图像(n = 60)的分析,本研究绘制了潜在视觉应激源的存在。通过分析发现,“高对比度线性元素”是两个避难所中最常见的潜在视觉压力源。峰值残差最高的空间的共同特征是“穿孔板”和“高度图案化的表面”。此外,视觉压力源可以被划分为八个主要的建筑功能类别。本研究的探索性强调了其作为为创伤知情环境开发循证设计实践的基础步骤的重要性。
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引用次数: 0
Autonomous dispatch trajectory planning of carrier-based vehicles: An iterative safe dispatch corridor framework 舰载车辆自主调度轨迹规划:迭代安全调度通道框架
IF 5.9 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-01 DOI: 10.1016/j.dt.2025.09.006
Keyan Li , Xin Li , Yu Wu , Zhilong Deng , Yan Wang , Yishuo Meng , Bai Li , Xichao Su , Lei Wang , Xinwei Wang
As carrier aircraft sortie frequency and flight deck operational density increase, autonomous dispatch trajectory planning for carrier-based vehicles demands efficient, safe, and kinematically feasible solutions. This paper presents an Iterative Safe Dispatch Corridor (iSDC) framework, addressing the suboptimality of the traditional SDC method caused by static corridor construction and redundant obstacle exploration. First, a Kinodynamic-Informed-Bidirectional Rapidly-exploring Random Tree Star (KIB-RRT∗) algorithm is proposed for the front-end coarse planning. By integrating bidirectional tree expansion, goal-biased elliptical sampling, and artificial potential field guidance, it reduces unnecessary exploration near concave obstacles and generates kinematically admissible paths. Secondly, the traditional SDC is implemented in an iterative manner, and the obtained trajectory in the current iteration is fed into the next iteration for corridor generation, thus progressively improving the quality of within-corridor constraints. For tractors, a reverse-motion penalty function is incorporated into the back-end optimizer to prioritize forward driving, aligning with mechanical constraints and human operational preferences. Numerical validations on the data of Gerald R. Ford-class carrier demonstrate that the KIB-RRT∗ reduces average computational time by 75% and expansion nodes by 25% compared to conventional RRT∗ algorithms. Meanwhile, the iSDC framework yields more time-efficient trajectories for both carrier aircraft and tractors, with the dispatch time reduced by 31.3% and tractor reverse motion proportion decreased by 23.4% relative to traditional SDC. The presented framework offers a scalable solution for autonomous dispatch in confined and safety-critical environment, and an illustrative animation is available at bilibili.com/video/BV1tZ7Zz6Eyz. Moreover, the framework can be easily extended to three-dimension scenarios, and thus applicable for trajectory planning of aerial and underwater vehicles.
随着舰载机出动频率和飞行甲板操作密度的增加,舰载机自主调度轨迹规划需要高效、安全、运动学可行的解决方案。本文提出了一种迭代安全调度走廊(iSDC)框架,解决了传统SDC方法由于静态走廊建设和冗余障碍物探测而导致的次优性问题。首先,提出了一种动态知情双向快速探索随机树星(KIB-RRT *)算法用于前端粗规划。通过将双向树展开、目标偏置椭圆采样和人工势场引导相结合,减少了在凹障碍物附近不必要的探索,生成了运动上可接受的路径。其次,传统的SDC以迭代的方式实现,将当前迭代中获得的轨迹输入到下一次迭代中进行廊道生成,从而逐步提高了廊道内约束的质量。对于拖拉机,后端优化器中加入了反向运动惩罚功能,以优先考虑向前驾驶,使机械约束和人类操作偏好保持一致。对Gerald R. ford级航母数据的数值验证表明,与传统的RRT∗算法相比,KIB-RRT∗算法平均计算时间减少75%,扩展节点减少25%。与此同时,iSDC框架为舰载机和牵引车提供了更省时的轨迹,与传统的SDC相比,调度时间减少了31.3%,牵引车反向运动比例减少了23.4%。所提出的框架为密闭和安全关键环境中的自主调度提供了可扩展的解决方案,并且可以在bilibili.com/video/BV1tZ7Zz6Eyz上获得说明性动画。此外,该框架可以很容易地扩展到三维场景,因此适用于空中和水下航行器的轨迹规划。
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引用次数: 0
A new form-evolving approach for adaptive tree-like structures using feature region principal stress lines method 基于特征区主应力线的自适应树状结构形式演化新方法
IF 3.6 1区 艺术学 0 ARCHITECTURE Pub Date : 2026-02-01 DOI: 10.1016/j.foar.2025.03.008
Ziying Shi, Hang Dai, Yuchi Shen
This paper introduces a concept that adapts natural tree growth mechanisms through an adaptive, hierarchical subdivision of the in-plane design domain, utilizing principal stress lines (PSLs) extracted from feature regions (FRPSLs). The approach integrates architectural interactive design with structural logic, enabling the creation of free-form tree-like structures. A naturally curved tree-like structure is obtained through the superimposition of these patterns and iterative form evolution, with the final shape representing the outward expression of internal forces. Unlike traditional form-finding methods that rely solely on external vertical loading or single load conditions, this method considers vertical plus bi-directional horizontal forces by applying them to generate PSLs patterns. A naturally curved tree-like structure is obtained through the superimposition of these patterns and iterative form evolution, with the final shape representing the outward expression of internal forces. Numerical examples and design cases demonstrate that the proposed method effectively balances aesthetic needs with structural performance, offering a new approach for generating free-form tree-like structures. The results highlight its potential to provide more architectural alternatives with asymmetric, curvilinear forms without compromising structural integrity.
本文介绍了一种概念,该概念通过利用从特征区域(frpsl)提取的主应力线(psl)对平面内设计域进行自适应分层细分,以适应自然树生长机制。该方法将建筑交互设计与结构逻辑集成在一起,从而能够创建自由形式的树状结构。通过这些图案的叠加和形式的迭代演化,得到了一个自然弯曲的树状结构,最终的形状代表了内力的向外表达。与传统的仅依赖外部垂直载荷或单一载荷条件的寻形方法不同,该方法通过应用垂直和双向水平力来生成psl模式。通过这些图案的叠加和形式的迭代演化,得到了一个自然弯曲的树状结构,最终的形状代表了内力的向外表达。数值算例和设计实例表明,该方法有效地平衡了美学需求和结构性能,为生成自由形状的树状结构提供了一种新的方法。结果突出了它的潜力,在不影响结构完整性的情况下,以不对称的曲线形式提供更多的建筑选择。
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引用次数: 0
Coupling of methanol and long chain alkanes on molecular sieves with CHA structures 甲醇与长链烷烃在CHA结构分子筛上的偶联
Q3 Energy Pub Date : 2026-02-01 DOI: 10.1016/S1872-5813(25)60603-7
Chuang YANG , Kangjun WANG , Jinzhe LI , Zhongmin LIU
The coupling reactions of methanol and long-chain alkanes (n-dodecane, n-tetradecane and n-hexadecane) over CHA-type molecular sieves were studied in a fixed bed reactor. Over SAPO-34 and SSZ-13, it was found that the induction period of methanol conversion was shortened by the introduction of long-chain alkanes. However, the addition of long-chain alkanes had little influence on the product distribution. Polymethylbenzenes and the derivatives were the main retained species on spent SSZ-13 catalyst, while adamantanes were the main retained species on SAPO-34. This indicates that coking species formation was mainly related to the further transformation of long-chain alkane/methanol coupling products at acid sites of the molecular sieve. These findings provide valuable information of long chain alkanes conversion and methanol reaction behavior of induction period over small pore CHA molecular sieves.
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在固定床反应器上研究了甲醇与长链烷烃(正十二烷、正十四烷和正十六烷)在cha型分子筛上的偶联反应。在SAPO-34和SSZ-13上,发现长链烷烃的引入缩短了甲醇转化的诱导期。而长链烷烃的加入对产物分布影响不大。多甲基苯及其衍生物是SSZ-13催化剂上的主要残留物质,金刚烷是SAPO-34催化剂上的主要残留物质。这表明,焦化物的形成主要与分子筛酸性部位长链烷烃/甲醇偶联产物的进一步转化有关。这些结果为长链烷烃在小孔CHA分子筛上的转化和诱导期甲醇反应行为提供了有价值的信息。下载:下载高分辨率图片(65KB)下载:下载全尺寸图片
{"title":"Coupling of methanol and long chain alkanes on molecular sieves with CHA structures","authors":"Chuang YANG ,&nbsp;Kangjun WANG ,&nbsp;Jinzhe LI ,&nbsp;Zhongmin LIU","doi":"10.1016/S1872-5813(25)60603-7","DOIUrl":"10.1016/S1872-5813(25)60603-7","url":null,"abstract":"<div><div>The coupling reactions of methanol and long-chain alkanes (<em>n</em>-dodecane, <em>n</em>-tetradecane and <em>n</em>-hexadecane) over CHA-type molecular sieves were studied in a fixed bed reactor. Over SAPO-34 and SSZ-13, it was found that the induction period of methanol conversion was shortened by the introduction of long-chain alkanes. However, the addition of long-chain alkanes had little influence on the product distribution. Polymethylbenzenes and the derivatives were the main retained species on spent SSZ-13 catalyst, while adamantanes were the main retained species on SAPO-34. This indicates that coking species formation was mainly related to the further transformation of long-chain alkane/methanol coupling products at acid sites of the molecular sieve. These findings provide valuable information of long chain alkanes conversion and methanol reaction behavior of induction period over small pore CHA molecular sieves.\u0000\t\t\t\t<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (65KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":15956,"journal":{"name":"燃料化学学报","volume":"54 2","pages":"Article 20250054"},"PeriodicalIF":0.0,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146172826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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