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Photocatalysis: Research and Potential最新文献

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SnS2 Quantum Dots Decorated MoS2 Nanosheets Enabling Efficient Photocatalytic H2 Evolution in CO2 Saturated Water SnS2量子点修饰的二硫化钼纳米片在CO2饱和水中实现高效光催化氢气析出
Pub Date : 1900-01-01 DOI: 10.35534/prp.2023.10003
Xuelian Chen, X. Luo, Lei Liu, Jing Ping, Songmei Sun
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引用次数: 0
Plasmon Enhanced Nickel(II) Catalyst for Photocatalytic Lignin Model Cleavage 等离子体增强镍(II)催化剂光催化木质素模型裂解
Pub Date : 1900-01-01 DOI: 10.35534/prp.2023.10002
Yichao Jin, Xiayan Wu, Sarina Sarina, Yingping Huang*Eric R Waclawik, Huai Yong Zhu
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引用次数: 1
Photocatalytic Efficiency of Suspended and Immobilized TiO2 P25 for Removing Myclobutanil, Penconazole and Their Commercial Formulations 悬浮和固定化TiO2 P25光催化去除丁腈、戊康唑及其商业配方的效率
Pub Date : 1900-01-01 DOI: 10.35534/prp.2023.10004
Ignace Christian M’Bra, N. Keller, A. Trokourey, D. Robert
: Fungicide application in viticulture is a major source of surface and groundwater contamination. It is therefore essential to find solutions to stop this environmental pollution. Heterogeneous photocatalysis is an advanced oxidation method for the degradation and mineralization of organic pollutants in water. TiO 2 P25 photocatalyst in suspension has been used for removing the fungicides Myclobutanil and Penconazol, and their respective commercial formulations Systhane and Topas, in contaminated water. The apparent kinetic constants k app of fungicides removal over 30 min batch treatment was higher for a mixture of pure molecules of Myclobutanil and Penconazol than for a mixture of their commercial formulations (17.5 × 10 −3 by comparison with 10.3 × 10 −3 min −1 for Myclobutanil, and 10.0 × 10 −3 by comparison with 2.80 × 10 −3 min −1 for Penconazol). TOC removal constants k TOC were similar for the two mixtures, due to the presence of mineral and organic additives in the commercial formulations. To easily recover the photocatalyst after fungicide removal, TiO 2 P25 has been supported on β-SiC foam. Fungicides degradation was lower with supported photocatalysts than with the suspension of photocatalyst nanoparticles (NPs) because of a lower concentration of active sites on the supported photocatalyst than in the catalyst suspension. However, catalyst recovery and reuse after fungicide removal is obviously easier with TiO 2 /β-SiC material than with a suspension of TiO 2 which requires long and expensive filtration operations.
葡萄栽培中使用的杀菌剂是地表水和地下水污染的主要来源。因此,找到阻止这种环境污染的解决方案是至关重要的。多相光催化是一种用于降解和矿化水中有机污染物的高级氧化方法。采用悬浮二氧化钛P25光催化剂对污染水中的杀菌剂丁腈和戊康唑及其商业配方Systhane和Topas进行了脱除。在30分钟的间歇处理过程中,纯丁腈和戊康唑的表观动力学常数k - app比其商业配方的混合物更高(丁腈和戊康唑的表观动力学常数k - app分别为17.5 × 10−3和10.0 × 10−3,前者为10.3 × 10−3 min−1,后者为2.80 × 10−3 min−1)。由于商业配方中存在矿物和有机添加剂,两种混合物的TOC去除常数k TOC相似。为了在去除杀菌剂后更容易地回收光催化剂,二氧化钛P25被负载在β-SiC泡沫上。由于负载型光催化剂上的活性位点浓度低于催化剂悬浮液,因此负载型光催化剂的杀菌剂降解率低于纳米光催化剂悬浮液。然而,与需要长时间和昂贵的过滤操作的二氧化钛悬浮液相比,二氧化钛/β-SiC材料明显更容易在杀菌剂去除后回收和再利用催化剂。
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引用次数: 0
Photocatalysis: Research and Potential—A New Means to Better Master Your Publishing Policy and Improve the Visibility of Your Articles 光催化:研究和潜力——一种更好地掌握你的出版政策和提高你的文章可见性的新手段
Pub Date : 1900-01-01 DOI: 10.35534/prp.2023.10001
P. Pichat
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引用次数: 0
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Photocatalysis: Research and Potential
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