首页 > 最新文献

Advances in Glass Science and Technology最新文献

英文 中文
Applications of Glass Fibers in 3D Preform Composites 玻璃纤维在3D预成型复合材料中的应用
Pub Date : 2018-06-06 DOI: 10.5772/INTECHOPEN.73293
K. Bilisik, G. Kaya, H. Ozdemir, M. Korkmaz, G. Erdogan
E-glass three dimensional (3D) stitched preform composites have been developed for several industrial applications due to their high mechanical performance and damage tolerance properties. Although some in-plane properties of the stitched E-glass composite structure are slightly lower than in laminated composite, its mode-I delamination failure is improved. This was achieved by using the out-of-plane directional stitched fibers. Recently, some nanoparticles as single-walled nanotubes (SWNT) or multiwalled nanotubes (MWNT) or nanofibers (NF) were added to the glass fabric structure or stitched preform during consolidation process. This further enhances the thermo-mechanical impact properties of the E-glass fiber composites.
电子玻璃三维(3D)缝合预制复合材料由于其高机械性能和损伤容限性能,已被开发用于几种工业应用。虽然缝合e-玻璃复合材料结构的某些面内性能略低于层合复合材料,但其i型脱层破坏得到改善。这是通过使用面外定向缝合纤维实现的。近年来,在固结过程中,一些纳米颗粒如单壁纳米管(SWNT)、多壁纳米管(MWNT)或纳米纤维(NF)被添加到玻璃织物结构或缝合预制体中。这进一步提高了e -玻璃纤维复合材料的热机械冲击性能。
{"title":"Applications of Glass Fibers in 3D Preform Composites","authors":"K. Bilisik, G. Kaya, H. Ozdemir, M. Korkmaz, G. Erdogan","doi":"10.5772/INTECHOPEN.73293","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.73293","url":null,"abstract":"E-glass three dimensional (3D) stitched preform composites have been developed for several industrial applications due to their high mechanical performance and damage tolerance properties. Although some in-plane properties of the stitched E-glass composite structure are slightly lower than in laminated composite, its mode-I delamination failure is improved. This was achieved by using the out-of-plane directional stitched fibers. Recently, some nanoparticles as single-walled nanotubes (SWNT) or multiwalled nanotubes (MWNT) or nanofibers (NF) were added to the glass fabric structure or stitched preform during consolidation process. This further enhances the thermo-mechanical impact properties of the E-glass fiber composites.","PeriodicalId":118101,"journal":{"name":"Advances in Glass Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114205648","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Application of Glass Beads in Building Exterior Wall Surface Materials 玻璃微珠在建筑外墙表面材料中的应用
Pub Date : 2018-06-06 DOI: 10.5772/INTECHOPEN.73292
J. Yuan
Glass beads are solid glass spheres. Because of their high strength, chemical stability, low thermal expansion, and good flowability, they are manufactured from colorless glass for many industrial purposes. In recent years, the urban heat island (UHI) phenomenon has become very serious in urban centers. Heat emitted from exterior walls of buildings accounts for a relatively large proportion of total anthropogenic waste heat. Retroreflective (RR) materials are researched worldwide for the potential in application to building exterior wall surface instead of normal diffuse highly reflective (DHR) materials to resist the UHI. Glass beads are the common main components of these RR materials. Glass beads have different refractive indices and diameters. The classification and reflection principles of glass beads, experimental analysis on the optical properties and thermal performance of glass bead RR materials are elaborated in detail in this chapter. In addition, if these glass bead RR materials are used in building facades, when the incident angle of the sun is very high, the facade will produce a large specular reflection to the road, which may cause adverse effects on pedestrians. Therefore, theoretical and technical aspects of preventing the specular reflection from glass bead RR materials should be studied and implemented.
玻璃珠是固体玻璃球。由于它们的高强度、化学稳定性、低热膨胀和良好的流动性,它们是由无色玻璃制成的,用于许多工业用途。近年来,城市中心地区的城市热岛现象日益严重。建筑外墙散发的热量在人为废热总量中占比较大的比例。在世界范围内,人们都在研究逆反射材料(RR)代替普通漫反射材料(DHR)在建筑外墙表面的应用潜力。玻璃珠是这些RR材料的常见主要成分。玻璃珠具有不同的折射率和直径。本章详细阐述了玻璃微珠的分类和反射原理,并对玻璃微珠RR材料的光学性能和热性能进行了实验分析。此外,如果在建筑立面中使用这些玻璃珠RR材料,当太阳的入射角很高时,立面会对道路产生较大的镜面反射,可能会对行人造成不利影响。因此,防止玻璃珠RR材料镜面反射的理论和技术方面需要进行研究和实现。
{"title":"Application of Glass Beads in Building Exterior Wall Surface Materials","authors":"J. Yuan","doi":"10.5772/INTECHOPEN.73292","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.73292","url":null,"abstract":"Glass beads are solid glass spheres. Because of their high strength, chemical stability, low thermal expansion, and good flowability, they are manufactured from colorless glass for many industrial purposes. In recent years, the urban heat island (UHI) phenomenon has become very serious in urban centers. Heat emitted from exterior walls of buildings accounts for a relatively large proportion of total anthropogenic waste heat. Retroreflective (RR) materials are researched worldwide for the potential in application to building exterior wall surface instead of normal diffuse highly reflective (DHR) materials to resist the UHI. Glass beads are the common main components of these RR materials. Glass beads have different refractive indices and diameters. The classification and reflection principles of glass beads, experimental analysis on the optical properties and thermal performance of glass bead RR materials are elaborated in detail in this chapter. In addition, if these glass bead RR materials are used in building facades, when the incident angle of the sun is very high, the facade will produce a large specular reflection to the road, which may cause adverse effects on pedestrians. Therefore, theoretical and technical aspects of preventing the specular reflection from glass bead RR materials should be studied and implemented.","PeriodicalId":118101,"journal":{"name":"Advances in Glass Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128239663","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Optical Glass: A High-Tech Base Material as Key Enabler for Photonics 光学玻璃:作为光子学关键推动者的高科技基础材料
Pub Date : 2018-06-06 DOI: 10.5772/INTECHOPEN.73925
U. Petzold
Optical glass is the base material for the fabrication of spherical lenses, aspheres, prisms, beam splitters, optical fibers, axicons, or other optical components. The photonic indus try relies on such components and so on optical glass. Photonics is a key enabling tech - nology for many market segments and applications. The requirements for optical glass are the highest transmission and tight tolerances of not only the optical properties such as refraction and dispersion but also the mechanical properties such as sufficient size and low stress content. In order to achieve the above mentioned specification, a sophis - ticated melting technology, hot forming processes, annealing procedure, and measure ment devices are required. This chapter discusses the most relevant information of these processes.
光学玻璃是制造球面透镜、非球面透镜、棱镜、分束器、光纤、轴轴或其他光学元件的基础材料。光子工业试图依靠光学玻璃等元件。光子学是许多细分市场和应用的关键使能技术。对光学玻璃的要求不仅是具有最高的透光性和严格的公差,如折射和色散等光学性能,而且要求具有足够的尺寸和低应力含量等力学性能。为了达到上述规格,需要先进的熔化技术、热成形工艺、退火工艺和测量设备。本章讨论了这些过程中最相关的信息。
{"title":"Optical Glass: A High-Tech Base Material as Key Enabler for Photonics","authors":"U. Petzold","doi":"10.5772/INTECHOPEN.73925","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.73925","url":null,"abstract":"Optical glass is the base material for the fabrication of spherical lenses, aspheres, prisms, beam splitters, optical fibers, axicons, or other optical components. The photonic indus try relies on such components and so on optical glass. Photonics is a key enabling tech - nology for many market segments and applications. The requirements for optical glass are the highest transmission and tight tolerances of not only the optical properties such as refraction and dispersion but also the mechanical properties such as sufficient size and low stress content. In order to achieve the above mentioned specification, a sophis - ticated melting technology, hot forming processes, annealing procedure, and measure ment devices are required. This chapter discusses the most relevant information of these processes.","PeriodicalId":118101,"journal":{"name":"Advances in Glass Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116978633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Crystallization Kinetics of Bi2O3-SiO2 Binary System Bi2O3-SiO2二元体系结晶动力学研究
Pub Date : 2018-06-06 DOI: 10.5772/INTECHOPEN.74177
Hongwei Guo
The Bi2O3-SiO2 glasses were prepared by the melt cooling method. The non-isothermal crystallization kinetics and phase transformation kinetics of the BS glasses were analyzed by the Kissinger and Augis-Bennett equations by means of differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The results show that three main crystal phases, namely Bi12SiO20, Bi2SiO5, and Bi4Si3O12 are generated sequentially in the heat treatment process. The corresponding activation energy is 150.6, 474.9, and 340.3 kJ/mol. The average crystallization index is 2.5, 2.1, and 2.2. The crystal phases generated by volume nucleation grow in a one-dimensional pattern, and the metastable Bi2SiO5 can be transformed into Bi4Si3O12, which is in a more stable phase.
采用熔融冷却法制备了Bi2O3-SiO2玻璃。采用差示扫描量热法(DSC)和x射线衍射法(XRD),采用Kissinger方程和Augis-Bennett方程分析了BS玻璃的非等温结晶动力学和相变动力学。结果表明:热处理过程中依次生成了Bi12SiO20、Bi2SiO5和Bi4Si3O12三种主要晶相;对应的活化能分别为150.6、474.9和340.3 kJ/mol。平均结晶指数分别为2.5、2.1和2.2。体积成核生成的晶相以一维方式生长,亚稳的Bi2SiO5可以转变为Bi4Si3O12,而Bi4Si3O12处于更稳定的相。
{"title":"Crystallization Kinetics of Bi2O3-SiO2 Binary System","authors":"Hongwei Guo","doi":"10.5772/INTECHOPEN.74177","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.74177","url":null,"abstract":"The Bi2O3-SiO2 glasses were prepared by the melt cooling method. The non-isothermal crystallization kinetics and phase transformation kinetics of the BS glasses were analyzed by the Kissinger and Augis-Bennett equations by means of differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The results show that three main crystal phases, namely Bi12SiO20, Bi2SiO5, and Bi4Si3O12 are generated sequentially in the heat treatment process. The corresponding activation energy is 150.6, 474.9, and 340.3 kJ/mol. The average crystallization index is 2.5, 2.1, and 2.2. The crystal phases generated by volume nucleation grow in a one-dimensional pattern, and the metastable Bi2SiO5 can be transformed into Bi4Si3O12, which is in a more stable phase.","PeriodicalId":118101,"journal":{"name":"Advances in Glass Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132623696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
The Nature of the Defects in Phosphate-Based Glasses Induced by Gamma Radiation 伽玛辐射致磷酸盐基玻璃缺陷的性质
Pub Date : 2018-06-06 DOI: 10.5772/INTECHOPEN.74178
Quanlong He, Pengfei Wang, Min Lu, B. Peng
Final optics assembly is one of the most important parts in high energy and large-scale laser systems like US National Ignition Facility and SG III in China. Those final optics assembly are facing some severe tests, like the laser-induced damage caused by 3ω (351 nm) laser irradiation. Meanwhile, the irradiation of gamma ray and X-rays, will also cause the changes of optical properties in the investigated multi-component phos- phate glasses that have potential use in novel color separation optics in high power laser facilities. These changes of optical properties are associated with the defects induced by gamma radiation. In details, some defects contribute to the absorption in the UV region, which will deteriorate their UV performance. However, some of the induced defects can be eliminated by thermal treatment due to the release and capture of the electrons in conduction band. Besides, the doped Fe, Co, B, Ce and Sb will also affect the defect-state in phosphate-based glasses. In details, gamma radiation resistances of the phosphate glass can be greatly improved by CeO 2 and Sb 2 O 3 co-doping, and the introduction of B 2 O 3 reduces the connectivity of phosphate chains and thus increases the concentration of PO 3 -EC and PO 4 -EC defects.
最终光学组件是美国国家点火装置和中国SG III等高能和大型激光系统的重要组成部分之一。这些最终的光学组件面临着一些严峻的考验,比如由3ω (351nm)激光照射引起的激光损伤。同时,在伽玛射线和x射线的照射下,所研究的多组分php - phate玻璃的光学性质也会发生变化,在高功率激光设备的新型分色光学器件中具有潜在的应用前景。这些光学性质的变化与伽马辐射引起的缺陷有关。具体来说,一些缺陷会导致紫外区的吸收,从而降低其紫外性能。然而,由于导电带中电子的释放和捕获,一些诱导缺陷可以通过热处理消除。此外,Fe、Co、B、Ce和Sb的掺杂也会影响磷酸盐基玻璃的缺陷状态。其中,ceo2和sb2o3共掺杂可显著提高磷酸盐玻璃的抗伽马辐射能力,而b2o3的引入降低了磷酸链的连通性,从而增加了po3 -EC和po4 -EC缺陷的浓度。
{"title":"The Nature of the Defects in Phosphate-Based Glasses Induced by Gamma Radiation","authors":"Quanlong He, Pengfei Wang, Min Lu, B. Peng","doi":"10.5772/INTECHOPEN.74178","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.74178","url":null,"abstract":"Final optics assembly is one of the most important parts in high energy and large-scale laser systems like US National Ignition Facility and SG III in China. Those final optics assembly are facing some severe tests, like the laser-induced damage caused by 3ω (351 nm) laser irradiation. Meanwhile, the irradiation of gamma ray and X-rays, will also cause the changes of optical properties in the investigated multi-component phos- phate glasses that have potential use in novel color separation optics in high power laser facilities. These changes of optical properties are associated with the defects induced by gamma radiation. In details, some defects contribute to the absorption in the UV region, which will deteriorate their UV performance. However, some of the induced defects can be eliminated by thermal treatment due to the release and capture of the electrons in conduction band. Besides, the doped Fe, Co, B, Ce and Sb will also affect the defect-state in phosphate-based glasses. In details, gamma radiation resistances of the phosphate glass can be greatly improved by CeO 2 and Sb 2 O 3 co-doping, and the introduction of B 2 O 3 reduces the connectivity of phosphate chains and thus increases the concentration of PO 3 -EC and PO 4 -EC defects.","PeriodicalId":118101,"journal":{"name":"Advances in Glass Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129539314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Seal Glass for Solid Oxide Fuel Cells 固体氧化物燃料电池密封玻璃
Pub Date : 2018-06-06 DOI: 10.5772/INTECHOPEN.74180
M. Suklueng
Barium calcium aluminum boro-silicate glass (BCABS) is used as a sealant for Solid Oxide Fuel Cells (SOFCs) to protect against air and hydrogen gas leaking at 800 (cid:1) C. One major problem is the chemical reaction of this glass with barium oxide and other materials in the composition such as Ba-Y-Co-Fe (BYCF) and Ba-Sr-Co-Fe (cathode) used in the fuel cell components, leading to the formation and spreading of barium aluminosilicate glass on the cathode surface in the fuel cell. This investigation indicated that adding 0.4 mol% ZrO 2 to BCABS prevents the formation of barium aluminosilicate glass. Generally, the sealing glass of fuel cells must show high resistivity for no disturbance to electricity from the fuel cell system when generating the electron. The 0.4 mol% ZrO 2 to BCABS is generated with resistivity of 4 M Ω that is useful for SOFCs technology. The thermal expansion coefficient (TEC) in SOFCs is the major condition for producing the cell layers. The thermal expan- sion coefficient of SOFCs based on each layer (cathode, electrolyte, anode, interconnect and sealant) should be closed to prevent broken cells. The thermal expansion coefficient is 12.40 (cid:3) 10 (cid:4) 6 / o C matched with the TEC of the GDC 10 electrolyte. Therefore, BCABS glass with 0.4 mol%ZrO 2 generated a novel composite for SOFCs.
钡钙铝boro-silicate玻璃(bcab)被用作密封剂固体氧化物燃料电池(sofc)来防止空气和氢气泄漏800 (cid): 1) c的一个主要问题是玻璃的化学反应与氧化钡和其他材料的成分如Ba-Y-Co-Fe (BYCF)和Ba-Sr-Co-Fe(阴极)用于燃料电池组件,导致钡铝硅酸盐玻璃的形成和传播在燃料电池阴极表面。研究表明,在BCABS中加入0.4 mol%的zro2可以防止钡铝硅酸盐玻璃的形成。一般来说,燃料电池的密封玻璃必须具有高电阻率,以便在产生电子时不会对燃料电池系统的电产生干扰。生成的0.4 mol% zro2到BCABS的电阻率为4 M Ω,这对SOFCs技术很有用。sofc的热膨胀系数(TEC)是形成电池层的主要条件。sofc的每一层(阴极、电解液、阳极、互连和密封剂)的热膨胀系数都应该是封闭的,以防止电池破裂。热膨胀系数为12.40 (cid:3) 10 (cid:4) 6 / o C,与gdc10电解质的TEC相匹配。因此,含有0.4 mol% zro2的BCABS玻璃产生了一种新型的sofc复合材料。
{"title":"Seal Glass for Solid Oxide Fuel Cells","authors":"M. Suklueng","doi":"10.5772/INTECHOPEN.74180","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.74180","url":null,"abstract":"Barium calcium aluminum boro-silicate glass (BCABS) is used as a sealant for Solid Oxide Fuel Cells (SOFCs) to protect against air and hydrogen gas leaking at 800 (cid:1) C. One major problem is the chemical reaction of this glass with barium oxide and other materials in the composition such as Ba-Y-Co-Fe (BYCF) and Ba-Sr-Co-Fe (cathode) used in the fuel cell components, leading to the formation and spreading of barium aluminosilicate glass on the cathode surface in the fuel cell. This investigation indicated that adding 0.4 mol% ZrO 2 to BCABS prevents the formation of barium aluminosilicate glass. Generally, the sealing glass of fuel cells must show high resistivity for no disturbance to electricity from the fuel cell system when generating the electron. The 0.4 mol% ZrO 2 to BCABS is generated with resistivity of 4 M Ω that is useful for SOFCs technology. The thermal expansion coefficient (TEC) in SOFCs is the major condition for producing the cell layers. The thermal expan- sion coefficient of SOFCs based on each layer (cathode, electrolyte, anode, interconnect and sealant) should be closed to prevent broken cells. The thermal expansion coefficient is 12.40 (cid:3) 10 (cid:4) 6 / o C matched with the TEC of the GDC 10 electrolyte. Therefore, BCABS glass with 0.4 mol%ZrO 2 generated a novel composite for SOFCs.","PeriodicalId":118101,"journal":{"name":"Advances in Glass Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126266101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structure and Physical Properties of 59B2O3–10Na2O–(30 − x)CdO–xZnO–1CuO (0 ≤ x ≤ 30) Glass System 59B2O3-10Na2O -(30−x) CdO-xZnO-1CuO(0≤x≤30)玻璃体系的结构与物理性能
Pub Date : 2018-06-06 DOI: 10.5772/INTECHOPEN.73865
L. Ravangave, G. N. Devde
A series of stable and transparent glasses with the composition 59B2O3–10Na2O–(30 − x) CdO–xZnO–1CuO (0 ≤ x ≤ 30) (where x = 0, 7.5, 15, 22.5, and 30 mol%) were prepared by conventional melt-quenching technique. These glasses were characterized using X-ray diffraction (XRD), Fourier-transform infrared (FTIR) and Raman spectroscopes, differential scanning calorimetry (DSC), optical absorption, and electron paramagnetic resonance (EPR). XRD and DSC analysis confirmed the glassy nature of the prepared samples. The physical properties such as density (ρ), molar volume (Vm), oxygen packing density (OPD), and the molar volume of oxygen (Vo) were calculated and discussed. FTIR and Raman studies showed that the glass network consists of BO3 and BO4 units in various borate groups. From DSC, it was found that the glass transition temperature (Tg) varies nonlinearly with the addition of ZnO content in place of CdO. Both EPR and optical absorption results have confirmed that the Cu2+ ions are in octahedral coordination with a strong tetrahedral distortion. The changes in various spectroscopic properties of Cu2+ ions in the glasses such as spin-Hamiltonian parameters ( ) and bonding coefficients (α2, β1, and β2) were understood with the help of FTIR and Raman studies.
采用常规熔淬法制备了59B2O3-10Na2O -(30−x) CdO-xZnO-1CuO(0≤x≤30)(其中x = 0、7.5、15、22.5和30 mol%)的稳定透明玻璃。利用x射线衍射(XRD)、傅里叶变换红外(FTIR)和拉曼光谱仪、差示扫描量热法(DSC)、光学吸收和电子顺磁共振(EPR)对这些玻璃进行了表征。XRD和DSC分析证实了所制备样品的玻璃性质。计算并讨论了氧的密度(ρ)、摩尔体积(Vm)、氧堆积密度(OPD)和氧的摩尔体积(Vo)等物理性质。红外光谱(FTIR)和拉曼光谱(Raman)研究表明,玻璃网络由不同硼酸基团中的BO3和BO4单元组成。DSC分析发现,玻璃化转变温度(Tg)随ZnO含量代替CdO的加入呈非线性变化。EPR和光吸收结果均证实了Cu2+离子呈八面体配位,具有较强的四面体畸变。通过FTIR和拉曼光谱研究,了解了Cu2+离子在玻璃中的各种光谱性质的变化,如自旋哈密顿参数()和键合系数(α2、β1和β2)。
{"title":"Structure and Physical Properties of 59B2O3–10Na2O–(30 − x)CdO–xZnO–1CuO (0 ≤ x ≤ 30) Glass System","authors":"L. Ravangave, G. N. Devde","doi":"10.5772/INTECHOPEN.73865","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.73865","url":null,"abstract":"A series of stable and transparent glasses with the composition 59B2O3–10Na2O–(30 − x) CdO–xZnO–1CuO (0 ≤ x ≤ 30) (where x = 0, 7.5, 15, 22.5, and 30 mol%) were prepared by conventional melt-quenching technique. These glasses were characterized using X-ray diffraction (XRD), Fourier-transform infrared (FTIR) and Raman spectroscopes, differential scanning calorimetry (DSC), optical absorption, and electron paramagnetic resonance (EPR). XRD and DSC analysis confirmed the glassy nature of the prepared samples. The physical properties such as density (ρ), molar volume (Vm), oxygen packing density (OPD), and the molar volume of oxygen (Vo) were calculated and discussed. FTIR and Raman studies showed that the glass network consists of BO3 and BO4 units in various borate groups. From DSC, it was found that the glass transition temperature (Tg) varies nonlinearly with the addition of ZnO content in place of CdO. Both EPR and optical absorption results have confirmed that the Cu2+ ions are in octahedral coordination with a strong tetrahedral distortion. The changes in various spectroscopic properties of Cu2+ ions in the glasses such as spin-Hamiltonian parameters ( ) and bonding coefficients (α2, β1, and β2) were understood with the help of FTIR and Raman studies.","PeriodicalId":118101,"journal":{"name":"Advances in Glass Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125000764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Nonsilica Oxide Glass Fiber Laser Sources: Part II 非氧化硅玻璃光纤激光源:第二部分
Pub Date : 2018-06-06 DOI: 10.5772/INTECHOPEN.74664
Xiushan Zhu, A. Chavez-Pirson, D. Milanese, J. Lousteau, N. Boetti, D. Pugliese, N. Peyghambarian
Nonsilica oxide glasses have been developed and studied for many years as promising alternatives to the most used silica glass for the development of optical fiber lasers with unique characteristics. Their main properties and compositions, alongside the optical fiber fabrication principle, have been previously reviewed in part I. This chapter will review the development of optical fiber lasers operating in the infrared wavelength region based on nonsilica glass fiber materials, either phosphate, germanate or tellurite.
非氧化硅玻璃以其独特的特性,作为最常用的二氧化硅玻璃的替代品,已经被开发和研究了多年。它们的主要性质和组成,以及光纤的制造原理,已经在前面的第一部分中进行了回顾。本章将回顾基于非硅玻璃纤维材料(磷酸盐、锗酸盐或碲酸盐)的红外波长区域光纤激光器的发展。
{"title":"Nonsilica Oxide Glass Fiber Laser Sources: Part II","authors":"Xiushan Zhu, A. Chavez-Pirson, D. Milanese, J. Lousteau, N. Boetti, D. Pugliese, N. Peyghambarian","doi":"10.5772/INTECHOPEN.74664","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.74664","url":null,"abstract":"Nonsilica oxide glasses have been developed and studied for many years as promising alternatives to the most used silica glass for the development of optical fiber lasers with unique characteristics. Their main properties and compositions, alongside the optical fiber fabrication principle, have been previously reviewed in part I. This chapter will review the development of optical fiber lasers operating in the infrared wavelength region based on nonsilica glass fiber materials, either phosphate, germanate or tellurite.","PeriodicalId":118101,"journal":{"name":"Advances in Glass Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131275948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Glass Patterning: Technologies and Applications 玻璃图案:技术与应用
Pub Date : 2018-02-10 DOI: 10.5772/INTECHOPEN.74179
N. Toan, N. Inomata, M. Toda, T. Ono
In this work, we review the progress in recent studies on glass patterning including technologies and applications. Four technologies for glass micromachining including wet etching, sandblasting, reactive ion etching, and glass reflow process are analyzed. Advantages as well as disadvantages of each method are presented and discussed in light of the experiments. Various microsystem applications using the above glass patterning technologies like thermal sensors, hermetically packaged capacitive silicon resonators, optical modulator devices, glass microfluidics, micro-heaters, and vacuum-sealed capacitive micromachined ultrasonic transducer arrays are reported.
本文综述了近年来玻璃图案化的研究进展,包括技术和应用。分析了湿法蚀刻、喷砂、反应离子蚀刻和玻璃回流四种玻璃微加工工艺。结合实验,提出并讨论了每种方法的优缺点。本文还报道了使用上述玻璃图像化技术的各种微系统应用,如热传感器、密封封装电容硅谐振器、光调制器器件、玻璃微流体、微加热器和真空密封电容微机械超声换能器阵列。
{"title":"Glass Patterning: Technologies and Applications","authors":"N. Toan, N. Inomata, M. Toda, T. Ono","doi":"10.5772/INTECHOPEN.74179","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.74179","url":null,"abstract":"In this work, we review the progress in recent studies on glass patterning including technologies and applications. Four technologies for glass micromachining including wet etching, sandblasting, reactive ion etching, and glass reflow process are analyzed. Advantages as well as disadvantages of each method are presented and discussed in light of the experiments. Various microsystem applications using the above glass patterning technologies like thermal sensors, hermetically packaged capacitive silicon resonators, optical modulator devices, glass microfluidics, micro-heaters, and vacuum-sealed capacitive micromachined ultrasonic transducer arrays are reported.","PeriodicalId":118101,"journal":{"name":"Advances in Glass Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134506193","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
期刊
Advances in Glass Science and Technology
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1