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Effect of Laminar Flow on the Corrosion Activity of AA6061-T6 in Seawater 层流对AA6061-T6在海水中腐蚀活性的影响
Pub Date : 2020-01-24 DOI: 10.3390/met10020175
G. Acosta, L. Veleva, L. Chávez, J. L. Lopez
The electrochemical behaviour and surface changes on AA6061-T6 alloy exposed to Caribbean seawater from the Cozumel Channel for 30 days under laminar flow (0.1 ms−1) were studied, these contrasting then with stationary conditions. Open circuit potential monitoring and electrochemical current fluctuations, considered as electrochemical noise (EN), were employed as two nondestructive methods. The calculated corrosion current, based on Rn, was one order higher in laminar flow. The fluctuations of current were transformed in the frequency domain. Their power spectral density (PSD) plots were obtained in order to gain information concerning the dynamic of the spontaneous release of energy during the corrosion process. The value of the exponent β in PSD graphs suggested that the localised corrosion on AA6061-T6 surface occurs as a persistent stationary process, which dynamic is controlled by oxygen diffusion. The changes in the morphology and elemental composition of the formed layers revealed that the localised attacks occurred in the vicinity of intermetallic particles rich in Fe and Cu, which act as cathodes.
研究了AA6061-T6合金在Cozumel海峡加勒比海海水层流(0.1 ms−1)条件下暴露30天的电化学行为和表面变化,并与固定条件进行了对比。开路电位监测和电化学电流波动被认为是电化学噪声,是两种无损检测方法。在层流中,计算得到的腐蚀电流以Rn为基准高一个数量级。对电流的波动进行频域变换。为了获得腐蚀过程中能量自发释放的动态信息,绘制了它们的功率谱密度(PSD)图。PSD图的β指数表明,AA6061-T6表面的局部腐蚀是一个持续的平稳过程,动力学上受氧扩散控制。形成层的形貌和元素组成的变化表明,局部攻击发生在富铁和富铜的金属间颗粒附近,这些金属间颗粒充当阴极。
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引用次数: 4
Bases of Combustion Instability 燃烧不稳定的基础
Pub Date : 2020-01-13 DOI: 10.5772/intechopen.90017
V. Biryukov
Combustible systems generally consist of two types of chemically interacting components during combustion: an oxidizing agent (oxygen, fluorine, chlorine, their compounds) and fuel (hydrogen, hydrocarbons, nitrogen and hydrogen compounds, aluminum, etc.). The chemical properties of the components, their phase state, and their physical structure are essential when choosing the methods for supplying the components and organizing the processes in the combustion chambers, but they relatively weakly affect the basic laws of combustion processes. In the theory of combustion, the problems of burning homogeneous, premixed, gaseous components are studied in most detail. The concepts and methods of the theory of combustion are used in other areas of science and technology when considering exothermic processes with high heat generation. The separation of the issues of flame stability into diffusion-thermal and hydrodynamic problems, which is often encountered in theoretical works, is conditional and is caused by the desire to reduce the mathematical difficulties that arise when solving the problem in the general formulation. In fact, flame instability is determined by the influence of both transport processes in the flame (diffusion-thermal processes), depending on its structure, and hydrodynamic processes, i.e., the effects of gas flow. The determination of the concentration limits of flame propagation, ignition, and extinction, spontaneous instability of the flame front, the transition of combustion to detonation, and the excitation of oscillations during combustion are practical problems of the theory of combustion. Acoustic combustion instability can be considered as a self-oscillating process in which the feedback providing the energy necessary for maintaining undamped wave motions from a nonperiodic heat source (combustion process) is realized through the action of sound (acoustic) waves on combustion; in this case, the parameters of the wave motions, amplitude, waveform, and frequency, are determined by the internal properties of the system itself. This chapter provides a sequence of parametric estimates of acoustic instability during combustion in cylindrical chambers.
可燃系统在燃烧过程中通常由两种化学相互作用的组分组成:氧化剂(氧、氟、氯及其化合物)和燃料(氢、碳氢化合物、氮和氢化合物、铝等)。组份的化学性质、相态和物理结构是选择组份供应方式和组织燃烧过程的必要条件,但对燃烧过程基本规律的影响相对较弱。在燃烧理论中,最详细地研究了均质、预混和气态组分燃烧的问题。燃烧理论的概念和方法在考虑高热量产生的放热过程时被用于其他科学和技术领域。在理论工作中经常遇到的将火焰稳定性问题分离为扩散热和流体动力问题是有条件的,并且是为了减少在一般公式中解决问题时出现的数学困难。事实上,火焰的不稳定性是由火焰中的传递过程(取决于其结构的扩散-热过程)和流体动力学过程(即气体流动的影响)的影响决定的。火焰传播、着火和熄灭的浓度限值的确定,火焰锋面的自发不稳定性,燃烧向爆轰的过渡,以及燃烧过程中振荡的激发,都是燃烧理论中的实际问题。声燃烧不稳定性可以被认为是一个自振荡过程,在这个过程中,通过声音(声波)对燃烧的作用,反馈提供了维持非周期热源(燃烧过程)的无阻尼波动所必需的能量;在这种情况下,波动的参数,振幅,波形和频率,是由系统本身的内部特性决定的。本章提供了一系列圆柱形室燃烧过程中声学不稳定性的参数估计。
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引用次数: 0
DNS for Turbulent Premixed Combustion 湍流预混燃烧的DNS
Pub Date : 2020-01-02 DOI: 10.5772/intechopen.90632
Dipal M Patel, M. Agelin-Chaab
Most of practical combustion occurs in turbulent flows which involve strong coupling between turbulence and chemical processes. The heat release from combustion alters the fluid properties such as density and viscosity and in turns affects the turbulence. Direct numerical simulations (DNS) provides a tool for obtaining both temporally and spatially resolved data in three dimension (3D). This chapter presents a brief overview of importance of DNS in turbulent combustion, the role of turbulence and identifies different combustion modes. The mathematical formulation and numerical implementation for DNS are introduced. The second half of this chapter presents DNS results for ignition in both homogeneous and stratified mixtures. It has been found that minimum ignition energy is required to obtain successful ignition in different turbulence regimes. An increase in turbulent velocity fluctuation may leads to a misfire. Additionally the difference between growing flames and those which are quenched by turbulence have been discussed with the help of the reaction–diffusion balance analysis. Furthermore, the turbulence intensity and length scale of the mixture inhomogeneity have important influences on achieving self-sustained combustion following successful ignition events.
大多数实际燃烧发生在湍流中,湍流与化学过程之间存在强耦合。燃烧释放的热量改变了流体的特性,如密度和粘度,进而影响了湍流。直接数值模拟(DNS)提供了一种获得三维(3D)时间和空间解析数据的工具。本章简要概述了DNS在湍流燃烧中的重要性,湍流的作用,并确定了不同的燃烧模式。介绍了DNS的数学公式和数值实现。本章的后半部分介绍了在均匀和分层混合物中点火的DNS结果。已经发现,在不同的湍流状态下,获得成功点火需要最小的点火能量。湍流速度波动的增加可能导致失火。此外,利用反应-扩散平衡分析,讨论了生长火焰与湍流淬灭火焰的区别。此外,湍流强度和混合气不均匀性的长度尺度对成功点火后的自燃有重要影响。
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引用次数: 0
A Theoretical Review of Rotating Detonation Engines 旋转爆震发动机的理论综述
Pub Date : 2019-12-18 DOI: 10.5772/intechopen.90470
I. J. Shaw, J. Kildare, M. Evans, A. Chinnici, Ciaran A.M. Sparks, S. Rubaiyat, R. Chin, P. Medwell
Rotating detonation engines are a novel device for generating thrust from combustion, in a highly efficient, yet mechanically simple form. This chapter presents a detailed literature review of rotating detonation engines. Particular focus is placed on the theoretical aspects and the fundamental operating principles of these engines. The review covers both experimental and computational studies, in order to identify gaps in current understanding. This will allow the identification of future work that is required to further develop rotating detonation engines.
旋转爆震发动机是一种利用燃烧产生推力的新装置,它效率很高,但机械结构简单。本章对旋转爆震发动机进行了详细的文献综述。特别的重点是放在理论方面和这些发动机的基本操作原则。这篇综述涵盖了实验和计算研究,以确定当前理解中的差距。这将有助于确定进一步开发旋转爆震发动机所需的未来工作。
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引用次数: 2
Turbulent Flow Simulations 湍流模拟
Pub Date : 2019-11-21 DOI: 10.5772/intechopen.90251
L. Habeeb, Riyadh S. Al-Turaihi
This chapter consists of four sections; Introduction, Boundary and initial conditions, Setting of nonuniformly spaced grid, and Simulation approach. The fields of the fluctuating velocity describe the turbulent flows. Such fluctuations blend the transported quantities, like species concentration, energy, and momentum and make the transported quantity fluctuations in addition. Because such fluctuations have a small scale and high frequency, so they are very computationally costly for simulation straightforward in the virtual engineering computations. Alternatively, the instantaneous accurate governing equations can be time-averaged, ensemble-averaged, or in different way handled for removing the small scales, causing a modified group of equations, which are computationally less costly for solving.
本章共分四节;介绍,边界和初始条件,设置非均匀间隔网格,仿真方法。波动速度场描述了紊流。这种波动混合了输运量,如物种浓度、能量和动量,并使输运量也发生波动。由于这种波动具有小尺度和高频率的特点,因此在虚拟工程计算中,对其进行直接模拟的计算成本非常高。或者,瞬时精确的控制方程可以是时间平均的,集合平均的,或者以不同的方式处理,以去除小尺度,产生一组修改的方程,这在计算上求解成本更低。
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引用次数: 0
A Unique Volume Balance Approach for Verifying the Three-Dimensional Hydrodynamic Numerical Models in Surface Waterbody Simulation 一种独特的体积平衡方法在地表水体模拟中验证三维水动力数值模型
Pub Date : 2019-10-19 DOI: 10.5772/intechopen.89691
H. A. Al-Zubaidi, S. Wells
The hydrodynamic numerical modeling is increasingly becoming a widely used tool for simulating the surface waterbodies including rivers, lakes, and reservoirs. A challenging step in any model development is the verification tests, especially at the early stage of development. In this study, a unique approach was developed by implementing the volume balance principle in order to verify the three-dimensional hydrodynamic models for surface waterbody simulation. A developed and verified three-dimensional hydrodynamic and water quality model, called W3, was employed by setting a case study model to be verified using the volume balance technique. The model was qualified by calculating the error in the accumulated water volume within the domain every time step. Results showed that the volume balance reached a constant error over the simulation period, indicating a robust model setup.
水动力数值模拟正日益成为模拟河流、湖泊、水库等地表水体的一种广泛应用的工具。任何模型开发中的一个具有挑战性的步骤是验证测试,特别是在开发的早期阶段。为了验证地表水体模拟的三维水动力模型,本文采用体积平衡原理,提出了一种独特的方法。采用已开发并验证的三维水动力和水质模型W3,通过设置一个案例研究模型,使用体积平衡技术进行验证。通过计算各时间步内累积水量的误差对模型进行了验证。结果表明,在模拟期间,体积平衡达到恒定误差,表明模型建立稳健。
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引用次数: 0
Propagation of Shock Waves in Two Rooms Communicating through an Opening 通过开口连通的两个房间中冲击波的传播
Pub Date : 2019-06-27 DOI: 10.5772/INTECHOPEN.87190
I. Sochet, K. Gault, L. Hakenholz
Confined explosions represent a serious safety hazard as significant damage to humans and structures is observed, unlike in free-field explosions. An experimental small-scale study investigated the blast wave in a single-story building. The blast waves were generated by the detonation of a gaseous charge. The building was divided into two rooms by a movable wall which could be positioned at three different locations. The presence of an opening in this movable wall means that two rooms were considered: a transmitter room (TR) and a receptor room (RR). The configuration without the movable wall was also studied. Pressure profiles recorded with pressure gauges at ground level and on the wall presented numerous reflections. The damage effects were severe since the maximum overpressure never fell below 0.2 bar. Although this study is limited to a small scale and gaseous detonation charge, the results can be applied to a large scale and for a TNT charge.
与自由场爆炸不同,密闭爆炸会对人体和建筑物造成严重损害,因此具有严重的安全隐患。小型实验研究了单层建筑中的爆炸冲击波。爆炸波是由气体炸药爆炸产生的。建筑被可移动的墙分为两个房间,可以定位在三个不同的位置。在这个可移动的墙上有一个开口,这意味着考虑了两个房间:一个发送室(TR)和一个接收室(RR)。对无活动壁面的结构进行了研究。在地面和墙上用压力表记录的压力剖面显示了许多反射。由于最大超压从未低于0.2 bar,因此损坏效果非常严重。虽然本研究仅限于小型气体爆轰药,但其结果可应用于大型TNT爆轰药。
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引用次数: 3
Determination of the Velocity of the Detonation Wave and the Conditions for the Appearance of Spherical Detonation during the Interaction of Hydrogen with Oxygen 氢氧相互作用中爆震波速度的测定及球形爆轰的形成条件
Pub Date : 2018-11-05 DOI: 10.5772/INTECHOPEN.81792
M. Polatayko
The well-known formula for the flat detonation wave velocity derived from the Hugoniot system of equations faces difficulties, if being applied to a spherical reactor. A similar formula has been obtained in the framework of the theory of explosion in reacting gas media with the use of a special model describing the transition of an explosive wave in the detonation. The derived formula is very simple, being also more suitable for studying the limiting processes of volume detonation. The conditions for the transition of a shock wave to a detonation wave are studied. Initial detonation conditions required for fast chemical reactions to take place at the front of a spherical explosive wave have been determined. A simple relation describing the critical detonation temperature for various pressures in the hydrogen-oxygen mixture was obtained. Using the known formulas for a shock transition, the critical temperature was coupled with the initial conditions in a static environment, such as the pressure, temperature, and hydrogen content in the mixture.
由Hugoniot方程组导出的著名的平爆波速度公式,如果应用于球形反应堆,将面临困难。在反应气体介质爆炸理论的框架下,利用描述爆炸波在爆轰过程中的过渡的特殊模型,得到了一个类似的公式。导出的公式非常简单,也更适合研究体积爆轰的极限过程。研究了激波向爆震波过渡的条件。在球形爆炸波前发生快速化学反应所需的初始爆轰条件已经确定。得到了不同压力下氢氧混合物临界爆轰温度的简单关系式。使用已知的激波转变公式,将临界温度与静态环境中的初始条件(如压力、温度和混合物中的氢含量)耦合在一起。
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Direct Numerical Simulations - An Introduction and Applications
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