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Principles of Thermodynamics最新文献

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Matter and Electromagnetic Fields 物质与电磁场
Pub Date : 2018-12-31 DOI: 10.1017/9781108620932.021
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引用次数: 0
Thermodynamic System and First Law 热力学系统和第一定律
Pub Date : 2018-12-31 DOI: 10.1017/9781108620932.013
J. Ansermet, S. Brechet
The definition of a thermodynamic system includes the characterisation of its enclosure. The system can be closed or open, adiabatic or diathermal, rigid or mobile. State variables may be extensive or intensive. State functions are functions of the state variables only. A system may be divided into subsystems separated by walls that can be impermeable or permeable, adiabatic or diathermal, fixed or mobile. The state of a system may be changed by mechanical processes or thermal processes, resulting in a thermal transfer, mass transfer or work. The first law is expressed in terms of the total energy that includes the kinetic energy, so that thermomechanical systems can be analysed, creating a conceptual link between classical mechanics and thermodynamics. By examining a damped harmonic oscillator in the framework of thermodynamics, the need for a non-mechanical state variable is revealed.
热力学系统的定义包括其外壳的特征。系统可以是封闭的或开放的,绝热的或非热的,刚性的或可移动的。状态变量可以是广泛的,也可以是密集的。状态函数只是状态变量的函数。一个系统可以被隔墙分隔成子系统,隔墙可以是不渗透的或渗透的,可以是绝热的或非绝热的,可以是固定的或可移动的。系统的状态可能因机械过程或热过程而改变,从而引起热传递、传质或做功。热力学第一定律是用包括动能在内的总能量来表示的,这样就可以分析热力学系统,在经典力学和热力学之间建立了概念上的联系。通过在热力学的框架下考察阻尼谐振子,揭示了对非机械状态变量的需要。
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引用次数: 0
Thermodynamic Potentials 热力学势
Pub Date : 2018-12-31 DOI: 10.1017/9781108620932.005
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引用次数: 2
Calorimetry 量热法
Pub Date : 2018-12-31 DOI: 10.1017/9781108620932.017
Michele Selvaggi Cern, p-p Colliders, A. Zaborowska, Z. Drasal, E. P. Codina, C. Neubuser, Tony Price, F. Moortgat, Heather Gray
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引用次数: 0
Index 指数
Pub Date : 2018-12-31 DOI: 10.1017/9781108620932.024
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引用次数: 0
Thermodynamics of Subsystems 子系统热力学
Pub Date : 2018-12-31 DOI: 10.1017/9781108620932.015
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引用次数: 0
Thermodynamics of Continuous Media 连续介质热力学
Pub Date : 2018-12-31 DOI: 10.1017/9781108620932.022
J. Ansermet, S. Brechet
Continuity equations are derived first for extensive scalar quantities, then extended to vectorial quantities. Thus, material derivatives, source densities and current densities are introduced. The formalism is applied to express the conservation of mass and charge. The continuity equation for linear momentum corresponds to Newton’s second law with a stress tensor included to account for deformations in continuous media. Evolution equations for energy are obtained. This approch yields a local Gibbs relation, the relationship betwen intenal energy current density, conductive and convective heat currents and an expression for the entropy source density in terms of generalised currents and forces. This presentation of the thermodynamics of continuous media ends with volume integrations formalises the conceptual link between the local description of continuous media with the description of simple systems subjected to thermal and mechanical processes.
首先推导了广义标量的连续性方程,然后将其推广到向量。因此,引入了材料导数、源密度和电流密度。用这种形式来表示质量和电荷守恒。线性动量的连续性方程对应于牛顿第二定律,其中包含了一个应力张量来解释连续介质中的变形。得到了能量的演化方程。这种方法产生了局部吉布斯关系,即内能电流密度、导电热流和对流热流之间的关系,以及熵源密度在广义电流和力方面的表达式。连续介质热力学的介绍以体积积分结束,形式化了连续介质的局部描述与受热和机械过程影响的简单系统的描述之间的概念联系。
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引用次数: 0
Heat Engines 热引擎
Pub Date : 2018-10-08 DOI: 10.1002/9781119974178.ch4
A. Malthe‐Sørenssen
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引用次数: 0
Chemistry and Electrochemistry 化学与电化学
Pub Date : 2018-10-02 DOI: 10.1017/9781108620932.009
K. Fic
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引用次数: 0
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Principles of Thermodynamics
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