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Assessment of Fluoride and selected heavy metals in food chain around Fluorspar mining Plant, Kenya 肯尼亚氟石矿厂周围食物链中氟化物和选定重金属的评估
Pub Date : 2019-01-06 DOI: 10.15580/GJEMPS.2019.1.020919029
Kibet J. Barmao, J. Cherutoi, Cheruiyot Y. Mitei, M. L. Were, A. Kiprop, Oindo G. Achieng’
The purpose of the research was to assess the levels of fluoride and selected heavy metals in caprine, mutton, and vegetation around the Fluorspar mining plant in Kerio Valley. Previous studies have reported contamination of water and soil by acidic factory discharges laced with hazardous heavy metals and fluoride in Kerio Valley, Kenya. However, there is no data on Fluoride and selected heavy metals in food chain around Fluorspar mining Plant. This formed the motivation behind the study to avail the data on the level of contamination. The experimental design was an entirely randomized design where mutton, caprine, and plant (leaves, grass, corn maize) samples were randomly collected from the three locations (Tumeiyo, Choff, and Kimwarer) in three replicates and Turesia which was selected as the reference or control site. Sample preparations and analyses were done according to recommended methods. Fluoride levels were 6.34±2.45 mg/Kg and 9.58±6.03 mg/Kg in caprine and mutton, respectively. Heavy metals ranged between 0.06±0.02-0.06±0.03 mg/Kg for Pb, 0.06±0.03-0.09±0.06 mg/Kg for Cd, 3.31±1.90-3.66±2.41 mg/Kg for Zn, 0.51±0.32-0.82±0.55 mg/Kg for Fe and 0.44±0.28-0.54±0.33 mg/Kg for Cr. Fluoride levels in vegetation ranged between 4.77±2.52 and 6.27±3.40 mg/Kg, while heavy metal levels ranged between 0.01±0.01- 0.04±0.02 mg/Kg for Pb, 0.02±0.02-0.05±0.03 mg/Kg for Cd, 0.26±0.21-0.48±0.30 mg/Kg for Zn, 0.21±0.15-0.50±0.34 mg/Kg for Fe and 0.19±0.14-0.23±0.18 mg/Kg for Cr. Zn, Fe and Cr levels in meat and fluoride surpassed the WHO/FAO maximum limits while Pb and Cd in all the samples were within allowable limits. Conclusively, meat recorded higher analytes concentrations compared to vegetation. The fact that the levels of key chemical analytes in the assessed samples were availed and the contamination status indicated, presented the primary significance of this research.   Keywords: heavy metals; caprine, mutton; food chain; Fluorspar mining Plant
这项研究的目的是评估凯里奥山谷氟石矿厂周围的山羊、羊肉和植被中氟化物和某些重金属的含量。以前的研究报告了肯尼亚凯里奥山谷的水和土壤受到含有有害重金属和氟化物的酸性工厂排放的污染。然而,没有氟化物和氟石矿周围食物链中选定重金属的数据。这形成了这项研究背后的动机,利用污染水平的数据。试验设计为完全随机设计,在3个重复中随机采集3个地点(Tumeiyo、Choff和Kimwarer)的羊肉、山羊和植物(叶子、草、玉米)样品,并选择Tumeiyo、Choff和Kimwarer作为对照或参照地。按照推荐的方法进行样品制备和分析。山羊和羊肉的氟含量分别为6.34±2.45 mg/Kg和9.58±6.03 mg/Kg。重金属范围在0.06±0.02 Pb -0.06±0.03毫克/公斤,0.06±0.03 - -0.09±0.06毫克/公斤Cd, 3.31±1.90 - -3.66±2.41毫克/公斤锌、0.51±0.32 - -0.82±0.55毫克/公斤铁和0.44±0.28 - -0.54±0.33毫克/公斤Cr。氟含量植被之间的远程4.77±2.52,6.27±3.40毫克/公斤,而重金属含量范围在0.01±0.01 Pb - 0.04±0.02毫克/公斤,0.02±0.02 - -0.05±0.03毫克/公斤的Cd, 0.26±0.21 - -0.48±0.30毫克/公斤为锌、0.21±0.15 - -0.50±0.34毫克/公斤铁和0.19±0.14 - -0.23±0.18毫克/公斤Cr。锌、肉类中的铁、铬含量和氟化物含量均超过世卫组织/粮农组织的最高限量,而所有样品中的铅、镉含量均在允许范围内。最后,与植物相比,肉类的分析物浓度更高。评估样品中关键化学分析物的水平得到了利用,并表明了污染状况,这一事实表明了本研究的主要意义。关键词:重金属;山羊的羊;食物链;萤石矿厂
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引用次数: 6
A Comprehensive Study of Leachate Characteristics from Three Soluos Dumpsites in Igando Area of Lagos State, Nigeria 尼日利亚拉各斯州Igando地区三个Soluos垃圾场渗滤液特征综合研究
Pub Date : 2019-01-06 DOI: 10.15580/GJEMPS.2019.1.110118520
L. Salami, A. Susu
Leachate from dumpsites is a threat to soil, vegetation, surface and groundwater within the vicinity of the dumpsites. This work was carried out to comprehensively study the leachates from three Soluos dumpsites with a view of establishing correlation matrix for the leachate parameters in each of the dumpsites. The locations of the dumpsites were identified using Global Positioning System (GPS). Four different leachate samples were taken in each of the dumpsites and all the samples were analysed for thirty four leachate parameters according to the America Public Health Association (APHA). The results of the analysis were used to develop correlation matrices using the in-built Pearson product moment correlation coefficient solver tool in Microsoft Excel version 7. The results of the analysis reveal that some parameters such as biochemical oxygen demand, chemical oxygen demand, copper and chromium exceeded the permissible limits of the regulatory bodies. The correlation matrices showed a strong relationship among the leachate parameters and it was therefore recommended that the current practise of waste mix in the dumpsites should be stopped and the dumpsites leachates should be treated.   Keywords: Soluos dumpsites, solid waste, leachates, contaminants, correlation matrices.
垃圾场的渗滤液对垃圾场附近的土壤、植被、地表水和地下水构成威胁。本文对三个Soluos垃圾场的渗滤液进行了综合研究,并建立了各垃圾场渗滤液参数的相关矩阵。倾卸地点的位置是利用全球定位系统(GPS)确定的。在每个垃圾场采集了四种不同的渗滤液样本,并根据美国公共卫生协会(APHA)对所有样本进行了34种渗滤液参数分析。利用Microsoft Excel version 7中内置的Pearson积矩相关系数求解工具,利用分析结果建立相关矩阵。分析结果表明,生化需氧量、化学需氧量、铜、铬等指标均超过了监管机构的允许范围。相关矩阵显示渗滤液参数之间有很强的关系,因此建议停止目前在垃圾场混合废物的做法,并对垃圾场的渗滤液进行处理。关键词:垃圾场,固体废物,渗滤液,污染物,相关矩阵。
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引用次数: 8
Assessment of Benthic Macro-invertebrate Communities in Relation to Water Quality in Teltele Stream, Ambo West Showa, Ethiopia 埃塞俄比亚Ambo West Showa Teltele溪流中底栖大型无脊椎动物群落与水质关系的评估
Pub Date : 2018-08-01 DOI: 10.15580/gjemps.2018.3.070318092
G. Tessema, Agumassie Tesfahun
DOI: 10.15580/GJEMPS.2018.3.070318092 The assessment of benthic macro-invertebrates were studied in Teltele stream based on total of 6 orders and 11 families collected through December-May, 2015. Microsoft Excel and PAST software were employed to investigate the abundance and diversity of macro-invertebrates. Ephemeroptera was dominated 137(40.53%) followed by Coleoptera 112(33.14%) in the Teletele stream. However, other groups had less distribution. Based on the study sites, Ephemeroptera, Coleoptera and Diptera were the most widely distributed organisms accounted for 69(60%) at site 1, 28(17.1%) at site 2 and 40(67.8%) at site 3 for Ephemeroptera. Coleoptera comprised 22(19.1%) at site 1 and 90(54.87%) at site 2 and Diptera consisted 34(20.7%) at site 2 and 15(25.4%) at site 3. The distributions and compositions of the benthic macro-invertebrates were unequal at the sampling sites and statistically not significant (one way ANOVA, P>0.05). The Shannon diversity indexes were different among the sampling sites and the distribution of benthic organisms strongly associated with water quality parameters. The overall Shannon diversity index was (1.37) it revealed that the abundance and diversity of macro-invertebrate communities were low and therefore showed that poor water quality. At the study sites, several human induced associated impact problems like the existence of exotic Eucalyptus trees, Agricultural lands, waste material disposal and Ambo University’s oxidation pond were identified that resulted less distribution of macro-invertebrates in Teltele stream. The stream is vital for socioeconomic purposes such as drinking (cattle watering), sanitation, recreation, irrigation and others of the communities around the catchment and therefore, watershed management throughout the catchment is vital for proper utilization of the Teltele stream. Submitted: 03/07/2018 Accepted: 24/07/2018 Published: 01/08/2018
基于2015年12月至5月收集的6目11科,对Teltele溪流中底栖大型无脊椎动物的评估进行了研究。采用Microsoft Excel和PAST软件对大型无脊椎动物的丰度和多样性进行了调查。远翅目以蜉蝣目137目(40.53%)居多,鞘翅目112目(33.14%)次之。然而,其他组的分布较少。从各研究点来看,蜉蝣目、鞘翅目和双翅目生物分布最广,分别在1点、2点和3点分布69种(60%)、28种(17.1%)和40种(67.8%)。1号点鞘翅目22只(19.1%),2号点90只(54.87%);2号点双翅目34只(20.7%),3号点15只(25.4%)。各采样点底栖大型无脊椎动物的分布和组成不均匀,差异无统计学意义(单因素方差分析,P < 0.05)。不同采样点的Shannon多样性指数不同,底栖生物的分布与水质参数密切相关。总体Shannon多样性指数为(1.37),表明大型无脊椎动物群落的丰度和多样性较低,水质较差。在研究地点,发现了一些人为引起的相关影响问题,如外来桉树的存在、农业用地、废物处理和Ambo大学的氧化池,导致大型无脊椎动物在Teltele溪流中的分布减少。这条河流对于流域周围社区的饮用(牲畜饮水)、卫生、娱乐、灌溉等社会经济目的至关重要,因此,整个流域的流域管理对于Teltele河流的适当利用至关重要。提交时间:03/07/2018接收时间:24/07/2018发布时间:01/08/2018
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引用次数: 1
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