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International Journal of Bio-Inorganic Hybrid Nanomaterials最新文献

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Hybrid Nanomaterials: Biomedical, Environmental and Energy Applications 混合纳米材料:生物医学、环境和能源应用
Pub Date : 2022-01-01 DOI: 10.1007/978-981-19-4538-0
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引用次数: 0
A SYSTEMATIC GROWTH OF GOLD NANOSEEDS ON SILICA FOR SILICA@GOLD CORE-SHELL NANOPARTICLES AND INVESTIGATION OF OPTICAL PROPERTIES silica@gold核壳纳米粒子在二氧化硅上的系统生长及其光学性质研究
Pub Date : 2014-12-01 DOI: 10.7508/IJND.2014.06.003
M. K. Otoufi, N. Shahtahmasebebi, A. Kompany, E. Goharshadi
Metal nanoshells consists of a dielectric core surrounded by a thin noble metal shell, possess unique optical properties, which render nanoshells attractive for use in different technologies. This paper reports a facile method for growth of small gold nanoparticles on the functionalized surface of larger silica nanoparticles. Mono-dispersed silica particles and gold nanoparticles were prepared by the chemical reduction method. The size of the shell nanoseeds could be altered by repeating the stage of reducing HAuCl4 on Au/APTES/silica particles, and the time for which they react. The nanocore-shell particles prepared were studied using transmission electron microscopy (TEM), UV–vis spectroscopy, Fourier transform infrared spectroscopy (FTIR) and PL spectrophotometer. The TEM images indicated that by growing gold nanoseeds over the silica cores a red shift in the maximum absorbance of UV-Visible spectroscopy is observed. Furthermore, a remarkable intensification happens in the PL spectra of silica@Au NPs in comparison with that of bare silica NPs. But, the existence of gold nanoseeds on the silica particles surfaces does not change the PL spectra peaks of these nanoparticles.
金属纳米壳由一层薄薄的贵金属外壳包裹着一个电介质核组成,具有独特的光学性质,这使得纳米壳在不同的技术中具有吸引力。本文报道了一种在较大的二氧化硅纳米颗粒的功能化表面上生长小的金纳米颗粒的简便方法。采用化学还原法制备了单分散二氧化硅颗粒和金纳米颗粒。通过在Au/APTES/二氧化硅颗粒上重复还原HAuCl4的阶段,以及它们反应的时间,可以改变壳纳米种子的大小。采用透射电镜(TEM)、紫外-可见光谱(UV-vis)、傅里叶变换红外光谱(FTIR)和PL分光光度计对制备的纳米核壳颗粒进行了研究。透射电镜图像表明,在二氧化硅核上生长金纳米种子,在紫外可见光谱中观察到最大吸光度的红移。此外,与裸二氧化硅NPs相比,silica@Au NPs的PL光谱有显著的增强。但是,在二氧化硅颗粒表面存在金纳米种子并没有改变这些纳米颗粒的PL光谱峰。
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引用次数: 11
期刊
International Journal of Bio-Inorganic Hybrid Nanomaterials
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