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Computer-Aided Design of Catalysts最新文献

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Modeling of Polymerization Processes 聚合过程建模
Pub Date : 2020-08-18 DOI: 10.1201/9781003067115-10
K. Choi
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引用次数: 0
Catalytic Membrane Reactors 催化膜反应器
Pub Date : 2020-08-18 DOI: 10.1201/9781003067115-12
T. Tsotsis, R. Minet, A. M. Champagnie, Paul K. T. Liu
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引用次数: 0
Optimal Distribution of Catalyst in Pellets 催化剂在球团中的最佳分布
Pub Date : 1993-08-01 DOI: 10.1080/01614949308013912
A. Gavriilidis, A. Varma, M. Morbidelli
Abstract A large fraction of the chemical and refinery processes are catalytic in nature. While the worldwide sales of catalysts are only about $4 billion annually, the economic impact of catalysis comes from the fact that approximately $200 worth of products are manufactured for every $1 worth of catalyst consumed [1]. The active materials used as catalysts are often expensive metals, and in order to be utilized effectively, they are deposited on high surface area supports. This approach in many cases introduces intrapellet activity gradients during the preparation process, which were traditionally thought to be detrimental to catalyst performance. However, the effects of deliberate nonuniform distribution of the catalytic material within the support on the performance of a catalyst pellet started receiving attention in the late 1960's (see Refs. 2–6). These, as well as later studies, both experimental and theoretical, demonstrated that nonuniformly distributed catalysts can offer superior conversion, se...
很大一部分化学和炼油过程本质上是催化的。虽然全球催化剂的年销售额仅为40亿美元左右,但催化的经济影响来自于这样一个事实:每消耗1美元的催化剂,就会生产出大约200美元的产品[1]。用作催化剂的活性材料通常是昂贵的金属,为了有效利用,它们被沉积在高表面积的载体上。在许多情况下,这种方法在制备过程中引入了颗粒内活性梯度,传统上认为这不利于催化剂的性能。然而,在20世纪60年代后期,载体内催化剂材料故意不均匀分布对催化剂颗粒性能的影响开始受到关注(见参考文献2-6)。这些,以及后来的实验和理论研究,都证明了非均匀分布的催化剂可以提供更好的转化。
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引用次数: 44
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Computer-Aided Design of Catalysts
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