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Preface of the 2nd International Electronic Conference on Processes (ECP 2023) 第二届国际过程电子会议(ECP 2023)序言
Giancarlo Cravotto, D. Dziki, K. Gernaey
The 2nd International Electronic Conference on Processes: Process Engineering— Current State and Future Trends (ECP 2023) was hosted online from 17 to 31 May 2023. This conference presented the latest studies in process/systems-related research in chemistry, biology, material, energy, environment, food and engineering fields. The goal was to show the current state, challenges, opportunities and future trends in process systems engineering
第二届国际过程电子会议:第二届国际过程电子会议:过程工程--现状与未来趋势(ECP 2023)于 2023 年 5 月 17 日至 31 日在网上举行。本次会议展示了化学、生物、材料、能源、环境、食品和工程领域与过程/系统相关的最新研究成果。其目的是展示过程系统工程的现状、挑战、机遇和未来趋势。
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引用次数: 0
Accounting for Greenhouse Gas Emissions at Farm Level
V. Naujokienė, Kristina Lekavičienė, R. Bleizgys, Dainius Savickas
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引用次数: 0
Modeling and Economic Optimization of a Hollow Fiber Membrane Module for CO2 Separation Using Collocation Methods and Genetic Algorithms 基于配置方法和遗传算法的CO2分离中空纤维膜模块建模与经济优化
Quoc-Tuan Vuong, Tuan-Anh Nguyen
: Hollow fiber membranes are frequently used to remove CO 2 gas during the gas sweetening process due to their advantages such as cost-efficiency, simplicity of operation and maintenance, and compact size. Permeate flux behavior, which is governed by various factors such as membrane features and operating conditions, has a significant impact on the performance of membrane separation. The majority of existing research studies focused on enhancing the permeability and selectivity of membranes. The configuration and operation of membrane modules have received scant attention in investigation. The geometrical layout and operational parameters of a membrane module were taken into account as a multivariable optimization problem in this study. The total annual cost serves as the objective function. A construction expenditure based on the size of the membrane plant plus an operational expense related to energy usage make up the total cost. The module dimensions (fiber diameter, fiber length, and packing density) and operating conditions (inlet pressure) were taken into consideration as the design factors in the optimization problem. The membrane area and energy consumption, which are directly related to the overall cost, were calculated using a model to simulate the membrane plant. To simulate multicomponent gas transport through hollow fiber modules, a membrane model with a high prediction accuracy was adapted from a previous work and solved numerically using an orthogonal collocation method. The optimization process was carried out using a genetic algorithm. This study also investigated how different parameters affect the overall cost. The accuracy of the self-developed computation program was checked with the results obtained from ChemBrane. The relative difference in the results obtained from our program and ChemBrane is less than 1%, suggesting the applicability of our model and program. The proposed optimization process is able to find the conditions of the module that meet the requirement of CO 2 concentration of effluent while minimizing the cost. The results suggest that the use of polyamides has a lower cost than the use of cellulose acetate membranes.
:中空纤维膜常用的去除CO 2天然气在天然气脱硫过程中由于其成本效率等优点,操作和维护简单,紧凑的尺寸。渗透通量行为对膜分离性能有重要影响,它受膜特性和操作条件等多种因素的制约。大多数现有的研究集中在提高膜的渗透性和选择性。膜模块的配置和操作已收到很少注意在调查。本文将膜组件的几何布局和操作参数作为一个多变量优化问题来考虑。以年总成本为目标函数。基于膜厂规模的建设支出加上与能源使用相关的运营费用构成了总成本。在优化问题中,考虑了模块尺寸(纤维直径、纤维长度和填料密度)和运行条件(进口压力)作为设计因素。利用模型对膜装置进行模拟,计算与总成本直接相关的膜面积和能耗。为了模拟中空纤维组件中多组分气体的输运,借鉴前人的研究成果,建立了具有较高预测精度的膜模型,并采用正交配置法进行了数值求解。优化过程采用遗传算法进行。这项研究还调查了不同的参数如何影响总成本。自行开发的计算程序的准确性与ChemBrane的计算结果进行了验证。计算结果与ChemBrane的相对差异小于1%,表明了模型和程序的适用性。所提出的优化流程能够在成本最小的情况下找到满足出水co2浓度要求的模块条件。结果表明,使用聚酰胺膜比使用醋酸纤维素膜成本更低。
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引用次数: 0
Two-Phase Stefan Problem for the Modeling of Urea Prilling Tower 尿素造粒塔建模中的两相Stefan问题
Kim Thanh Vy Ha, Tuan-Anh Nguyen, Quoc-Lan Nguyen, V. Dang, Van-Han Dang, Hoang-Luan Van, Le-Na T. Pham
. The prilling technique is frequently used to make granular urea and ammonium nitrate. The generated droplets fall and become solid due to the heat removal by the cooling air, which flows in a counter-current direction. Generally, three sequential thermal intervals for the solidification of urea droplets are considered: cooling of liquid drops, solidification at freezing temperature of the liquid phase, and cooling of complete solid particles. In this study, the solidification of the urea droplets has been considered as a two-phase Stefan problem with convective flux boundary condition rather than dividing the whole process into three sequential steps. The heat transfer problem was solved numerically using the enthalpy method. The particles were assumed to attain the terminal velocity immediately. The convective heat transfer was determined from the terminal velocity. The temperature distribution of the droplets, and the minimum height for complete solidification at different particle diameters were investigated.
. 造粒技术常用于生产颗粒尿素和硝酸铵。产生的液滴下落并变成固体,因为冷却空气以逆流的方向流动,带走了热量。一般考虑尿素液滴凝固的三个顺序热间隔:液滴冷却、液相冻结温度下凝固、完整固体颗粒冷却。在本研究中,尿素液滴的凝固被视为具有对流通量边界条件的两相Stefan问题,而不是将整个过程划分为三个连续步骤。用焓法对传热问题进行了数值求解。假设粒子立即达到终端速度。对流换热由终端速度确定。研究了液滴在不同粒径下的温度分布和完全凝固的最小高度。
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引用次数: 0
Supercritical Fluid CO2 Extraction Technology to Produce an Innovative Healthy Product from Almond Wastes 从杏仁废料中提取创新健康产品的超临界流体CO2萃取技术
F. Chamorro, J. Echave, M. Prieto, J. Simal-Gándara, P. Otero
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引用次数: 0
Benefits and Drawbacks of Incorporating Grape Seeds into Bakery Products: Is It Worth It? 在烘焙产品中加入葡萄籽的利弊:值得吗?
J. Echave, Aurora Silva, A. Pereira, P. García-Oliveira, M. Fraga-Corral, P. Otero, L. Cassani, H. Cao, J. Simal-Gándara, M. Prieto, Jia-Qi Xiao
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引用次数: 0
The Performance of Venturi Microbubble Generator Type with a 60° Twisted Baffles 带有60°扭流挡板的文丘里微泡发生器的性能
Garc í a Mart í n, Fatma Roshanti, S. Deddy, Purnomo Sidhi, S. Kamal
: Due to their unique physical properties, microbubbles have received a lot of attention in waste treatment, aquaculture, and food processing. The demand for high-efficient and low power consumption microbubble generators has become a challenge today. Swirling flow has been widely proven to improve bubble formation. Numerous researchers have developed designs to produce swirl flow and strengthen the turbulence fluid flow. In this study, we present a swirl venturi microbubble generator with a 60 ◦ twisted baffle fin on the inlet section. The performance of the microbubble generator swirl venturi type was tested experimentally using parameters such as the distribution of bubble size, hydraulic power (L w ), and bubble-generating efficiency ( η b ). A microbubble generator was installed in the transparent test pool with 672 L of water. A high-speed video camera was employed to visualize the flow behavior. The water and gas flow rates varied between 40 and 60 lpm and 0.1 and 0.5 lpm, respectively. The data were analyzed by MATLAB R2022b with the technique image processing method. The results showed that majority bubbles 100–300 µ m were generated. An increased water flow rate (Q L ) will increase the hydraulic power by 22–27 W, while an enlargement of the gas flow rate (Q G ) would only enlarge it by 1 W. As the water flow rate increases, bubble-generating efficiency decreases. The lowest bubble-generating efficiency of 0.008% occurs at a Q L 60 lpm and Q G of 0.1 lpm. In conclusion, we can conclude that the microbubble generator swirl venturi type is an efficient device for generating microbubbles.
由于其独特的物理性质,微气泡在废物处理、水产养殖和食品加工等领域受到了广泛的关注。对高效、低功耗的微泡发电机的需求已成为当今的挑战。旋流已被广泛证明可以改善气泡的形成。许多研究人员已经开发出产生旋流和增强湍流流体流动的设计。在这项研究中,我们提出了一个涡流文丘里微泡发生器与60◦扭曲挡板鳍在进口部分。利用气泡大小分布、水力功率(L w)和气泡产生效率(η b)等参数对旋流文丘里型微泡发生器的性能进行了实验测试。在672 L水的透明试验池中安装微泡发生器。采用高速摄像机对流动特性进行了可视化观察。水和气的流速分别在40 ~ 60lpm和0.1 ~ 0.5 lpm之间变化。利用MATLAB R2022b对数据进行分析,采用技术图像处理方法。结果表明,气泡以100-300µm居多。水流量(Q L)的增加可使水力功率增加22 ~ 27 W,而气体流量(Q G)的增加只会使水力功率增加1 W。随着水流量的增加,气泡产生效率降低。在60lpm和0.1 lpm时,气泡产生效率最低,为0.008%。综上所述,旋流文丘里型微泡发生器是一种产生微泡的有效装置。
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引用次数: 0
Grindability, Energy Requirements and Gravity Separation of Quartz from Blast Furnace Ironmaking Slag by Shaking Table and Falcon Concentrator 振动台与猎鹰选矿机对高炉炼铁渣中石英的可磨性、能量需求及重选
Itumeleng Kohitlhetse, H. Rutto, Kentse Motsetse, M. Manono
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引用次数: 0
Supercritical Fluid Extraction as a Potential Extraction Technique for the Food Industry 超临界流体萃取技术在食品工业中的应用前景广阔
A. Perez-Vazquez, P. Barciela, M. Carpena, P. Donn, S. Seyyedi-Mansour, H. Cao, M. Fraga-Corral, P. Otero, J. Simal-Gándara, Mguel A. Prieto, L. Cassani
: Supercritical fluid extraction (SFE) is a non-conventional extraction technique that can be used in the food industry because it can recover both polar and non-polar compounds. This technique is carried out above the critical point of the extraction solvent, allowing for the control and manipulation of different properties such as diffusivity, viscosity, and density. This is possible due to the fluid’s changes in pressure and temperature that cause variations in selectivity and power. This eco-friendly extraction technique has several advantages, including high selectivity due to changes in pressure and temperature, as well as changes in the solvent’s polarity by adding co-solvents. SFE has already been used in the food industry due to the benefits of this technique and its suitability for both polar and non-polar compound extraction. The goal of this work is to compile the most recent data on SFE applications in the food industry, thereby providing insight into SFE feasibility in a large-scale process.
超临界流体萃取(SFE)是一种非传统的萃取技术,可用于食品工业,因为它可以回收极性和非极性化合物。该技术在萃取溶剂的临界点以上进行,允许控制和操纵不同的性质,如扩散率、粘度和密度。这是可能的,因为流体的压力和温度的变化会导致选择性和功率的变化。这种环保的萃取技术有几个优点,包括由于压力和温度的变化而产生的高选择性,以及通过添加助溶剂来改变溶剂的极性。由于该技术的优点及其对极性和非极性化合物提取的适用性,SFE已在食品工业中得到应用。这项工作的目标是汇编食品工业中SFE应用的最新数据,从而深入了解SFE在大规模工艺中的可行性。
{"title":"Supercritical Fluid Extraction as a Potential Extraction Technique for the Food Industry","authors":"A. Perez-Vazquez, P. Barciela, M. Carpena, P. Donn, S. Seyyedi-Mansour, H. Cao, M. Fraga-Corral, P. Otero, J. Simal-Gándara, Mguel A. Prieto, L. Cassani","doi":"10.3390/ecp2023-14674","DOIUrl":"https://doi.org/10.3390/ecp2023-14674","url":null,"abstract":": Supercritical fluid extraction (SFE) is a non-conventional extraction technique that can be used in the food industry because it can recover both polar and non-polar compounds. This technique is carried out above the critical point of the extraction solvent, allowing for the control and manipulation of different properties such as diffusivity, viscosity, and density. This is possible due to the fluid’s changes in pressure and temperature that cause variations in selectivity and power. This eco-friendly extraction technique has several advantages, including high selectivity due to changes in pressure and temperature, as well as changes in the solvent’s polarity by adding co-solvents. SFE has already been used in the food industry due to the benefits of this technique and its suitability for both polar and non-polar compound extraction. The goal of this work is to compile the most recent data on SFE applications in the food industry, thereby providing insight into SFE feasibility in a large-scale process.","PeriodicalId":237780,"journal":{"name":"The 2nd International Electronic Conference on Processes: Process Engineering—Current State and Future Trends","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126149024","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photocatalytic Degradation and Defluorination of Per- and Poly-Fluoroalkyl Substances (PFASs) Using Biosynthesized TiO2 Nanoparticles under UV–Visible Light 紫外-可见光下生物合成TiO2纳米粒子光催化降解全氟和多氟烷基物质(PFASs)的研究
Mustapha Saheed, Tijani Jimoh Oladejo, E. Rabi, Etsuyankpa Muhammed Binin, Amigun Azeezah Taiwo, Shuaib Damola Taye, Sumaila Abdulmumuni, Olaoye Adekunle Jelili, Abubakar Hassana Ladio, Abdulkareem Saka Abdulkareem, Ndamitso Muhammed Muhammed
: Per-and poly-fluoroalkyl substances (PFASs) are recalcitrant chemicals with stable carbon– fluorine (C–F) bonds. These complex substances are difficult to degrade; therefore, they persist in the environment, causing potential health effects on humans. This study focused on the photocatalytic degradation and defluorination of perfluorooctane sulfonate (PFOS) in aqueous water using TiO 2 nanoparticles under UV–visible light. The biosynthesized TiO 2 catalysts at pH 8, 10, and 12 were characterized using XRD, HRTEM, and HRSEM. The XRD patterns of the respective TiO 2 nanoparticles at different synthesized pHs exhibited similar anatase phases, and it was observed that the crystallite sizes decreased with increasing pH. The HRSEM and HRTEM confirmed the spherical shapes of the produced nanoparticles with particle size distributions of 12.17 nm, 10.65 nm, and 8.81 nm for the synthesized TiO 2 nanoparticles at pH 8, 10, and 12, respectively. The photodegradation and defluorination of PFOS were performed at various initial solution pH values of 2, 4, 6, 8, 10, and 12 under UV irradiation for 150 min. The study showed 95.62 and 56.13% degradation and defluorination efficiency at pH 2. The degradation and defluorination efficiencies significantly decreased as the pH of the solution increased; hence, the degradation increases at lower solution pHs. Without UV–visible light, the photocatalysis achieved a lower degradation and defluorination efficiency. The photocatalysis showed that the pH of the solution and UV irradiation greatly influence the degradation and defluorination. Therefore, TiO 2 nanoparticles were effective for the degradation and defluorination of PFOS under UV–visible light, which could also have an influence on the treatment of other PFASs in wastewater.
全氟和多氟烷基物质(PFASs)是具有稳定碳-氟(C-F)键的顽固化学品。这些复杂的物质很难降解;因此,它们在环境中持续存在,对人类的健康造成潜在影响。研究了在紫外-可见光下利用二氧化钛纳米颗粒光催化降解水中全氟辛烷磺酸(PFOS)。采用XRD、HRTEM和HRSEM对pH为8、10和12的生物合成tio2催化剂进行了表征。不同pH值下合成的tio2纳米颗粒的XRD谱图显示出相似的锐钛矿相,晶粒尺寸随pH值的增加而减小。HRSEM和HRTEM证实,在pH值为8、10和12时合成的tio2纳米颗粒为球形,粒径分布分别为12.17 nm、10.65 nm和8.81 nm。在初始溶液pH为2、4、6、8、10和12的条件下,紫外照射150 min,对PFOS进行光降解和除氟,pH为2时的降解和除氟效率分别为95.62%和56.13%。随着溶液pH值的增加,降解和除氟效率显著降低;因此,在较低的溶液ph下,降解加剧。在没有紫外-可见光的情况下,光催化的降解和除氟效率较低。光催化实验表明,溶液的pH值和紫外线照射对降解和除氟有较大影响。因此,tio2纳米颗粒在紫外可见光下对全氟辛烷磺酸的降解和除氟是有效的,这也可能对废水中其他全氟辛烷磺酸的处理产生影响。
{"title":"Photocatalytic Degradation and Defluorination of Per- and Poly-Fluoroalkyl Substances (PFASs) Using Biosynthesized TiO2 Nanoparticles under UV–Visible Light","authors":"Mustapha Saheed, Tijani Jimoh Oladejo, E. Rabi, Etsuyankpa Muhammed Binin, Amigun Azeezah Taiwo, Shuaib Damola Taye, Sumaila Abdulmumuni, Olaoye Adekunle Jelili, Abubakar Hassana Ladio, Abdulkareem Saka Abdulkareem, Ndamitso Muhammed Muhammed","doi":"10.3390/ecp2023-14630","DOIUrl":"https://doi.org/10.3390/ecp2023-14630","url":null,"abstract":": Per-and poly-fluoroalkyl substances (PFASs) are recalcitrant chemicals with stable carbon– fluorine (C–F) bonds. These complex substances are difficult to degrade; therefore, they persist in the environment, causing potential health effects on humans. This study focused on the photocatalytic degradation and defluorination of perfluorooctane sulfonate (PFOS) in aqueous water using TiO 2 nanoparticles under UV–visible light. The biosynthesized TiO 2 catalysts at pH 8, 10, and 12 were characterized using XRD, HRTEM, and HRSEM. The XRD patterns of the respective TiO 2 nanoparticles at different synthesized pHs exhibited similar anatase phases, and it was observed that the crystallite sizes decreased with increasing pH. The HRSEM and HRTEM confirmed the spherical shapes of the produced nanoparticles with particle size distributions of 12.17 nm, 10.65 nm, and 8.81 nm for the synthesized TiO 2 nanoparticles at pH 8, 10, and 12, respectively. The photodegradation and defluorination of PFOS were performed at various initial solution pH values of 2, 4, 6, 8, 10, and 12 under UV irradiation for 150 min. The study showed 95.62 and 56.13% degradation and defluorination efficiency at pH 2. The degradation and defluorination efficiencies significantly decreased as the pH of the solution increased; hence, the degradation increases at lower solution pHs. Without UV–visible light, the photocatalysis achieved a lower degradation and defluorination efficiency. The photocatalysis showed that the pH of the solution and UV irradiation greatly influence the degradation and defluorination. Therefore, TiO 2 nanoparticles were effective for the degradation and defluorination of PFOS under UV–visible light, which could also have an influence on the treatment of other PFASs in wastewater.","PeriodicalId":237780,"journal":{"name":"The 2nd International Electronic Conference on Processes: Process Engineering—Current State and Future Trends","volume":"30 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128491342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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The 2nd International Electronic Conference on Processes: Process Engineering—Current State and Future Trends
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