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Visualization and analysis of electronic fine structure electron cloud 电子精细结构电子云的可视化与分析
Pub Date : 1900-01-01 DOI: 10.23977/mpcr.2023.030101
Jie Huang, Sihui Yan
: Electron spin and orbital interaction outside the nucleus is a classical and important problem in quantum mechanics. In this paper, a simplified model is constructed for the phenomenon of atomic energy level splitting in weak magnetic field in quantum mechanics, and the wave function of the fine structure of hydrogen-like atoms under perturbation is derived. According to the probability interpretation of quantum mechanics, we obtain the probability density function of the fine structure electron cloud of hydrogen-like atoms. The Monte Carlo selection method is used to sample, and the electron cloud images under different quantum numbers are drawn by Mathematica software. The experimental results are explained regularly, so that people can intuitively understand the distribution of electron cloud in three-dimensional space.
原子核外电子自旋和轨道相互作用是量子力学中的一个经典而重要的问题。本文建立了量子力学中弱磁场下原子能级分裂现象的简化模型,导出了类氢原子精细结构在微扰下的波函数。根据量子力学的概率解释,得到了类氢原子精细结构电子云的概率密度函数。采用蒙特卡罗选择法进行采样,利用Mathematica软件绘制不同量子数下的电子云图像。实验结果有规律的解释,使人们可以直观地了解电子云在三维空间中的分布。
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Modern Physical Chemistry Research
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