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Resonant electron transfer in ion/atom-metal surface interactions 离子/原子-金属表面相互作用中的共振电子转移
Pub Date : 1999-07-01 DOI: 10.1016/S0042-207X(98)00453-9
E. Taranko, R. Taranko
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引用次数: 1
Role of 3d electrons in formation of ionic-covalent bonds in II-VI based ternary compounds 三维电子在II-VI基三元化合物中离子共价键形成中的作用
Pub Date : 1997-04-01 DOI: 10.2172/603488
K. Lawniczak-Jablonska, R. Iwanowski, R. Perera, J. Underwood, E. Gullickson
In the II-VI compounds doped with transition metals (diluted magnetic semiconductors) a substitution of cation by the introduced magnetic ion leads to hybridization of its 3d states with the sp states of the host semiconductor. The degree of hybridization of the 3d states and its interaction with the host material band states has been a subject of numerous discussions. Inner shell absorption spectroscopy provides very useful means of electronic structure analysis in a wide variety of systems. Due to its selectivity for atomic species and the selection rules for electron transitions, the soft X-ray absorption technique offers quite unique opportunity to measure directly the site-selective local density of the unoccupied d states in the compounds studied. Results are reported for ZnS compounds with Mn, Fe, Co or Ni substitutions for Zn.
在掺杂过渡金属(稀释磁性半导体)的II-VI化合物中,引入的磁性离子取代阳离子导致其3d态与宿主半导体的sp态的杂化。三维态的杂化程度及其与主材料带态的相互作用一直是许多讨论的主题。内壳吸收光谱为各种系统的电子结构分析提供了非常有用的手段。由于其对原子种类的选择性和电子跃迁的选择规则,软x射线吸收技术提供了非常独特的机会来直接测量所研究化合物中未占据d态的选择性局域密度。报道了用Mn、Fe、Co或Ni取代Zn的ZnS化合物的结果。
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引用次数: 0
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Electron Technology
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