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On the Thermodynamic Consistency of a Two Micro-Structured Thixotropic Constitutive Model 两微结构触变本构模型的热力学一致性
Pub Date : 2018-10-10 DOI: 10.5772/INTECHOPEN.75987
H. P. A. D. Deus, M. Itskov
The time-dependent rheological behavior of the thixotropic fluids is presented in various industrial fields (cosmetics, food, oil, etc.). Usually, a couple of equations define constitutive model for thixotropic substances: a constitutive equation based on linear viscoelastic models and a rate equation (an equation related to the micro-structural evolution of the substance). Many constitutive models do not take into account the micro-structural dependence of the shear modulus and viscosity in the dynamic principles from which are developed. The modified Jeffreys model (con-sidering only one single micro-structure type) does not show this incoherence in its formulation. In this chapter, a constitutive model for thixotropic fluids, based on modified Jeffreys model, is presented with the addition of one more micro-structure type, besides of comments on some possible generalizations. The rheological coherence of this constitutive model and thermodynamic consistency are analyzed too. This model takes into account a simple isothermal laminar shear flows, and the micro-structures dynamics are relate to Brownian motion and de Gennes Reptation model via the Smoluchowski ™ s coagulation theory.
触变流体的随时间流变行为在各种工业领域(化妆品、食品、石油等)中得到了体现。触变性物质的本构模型通常由两个方程来定义:一个是基于线性粘弹性模型的本构方程,另一个是速率方程(与物质微观结构演化有关的方程)。许多本构模型并没有考虑剪切模量和黏度对微观结构的依赖性。修改后的Jeffreys模型(只考虑一种微观结构类型)在其公式中没有显示出这种不一致性。在本章中,提出了一种基于修正Jeffreys模型的触变流体本构模型,该模型增加了一种微观结构类型,并对一些可能的推广进行了评论。分析了本构模型的流变一致性和热力学一致性。该模型考虑了一个简单的等温层流剪切流,微观结构动力学通过Smoluchowski的凝固理论与布朗运动和de Gennes重复模型相关联。
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引用次数: 0
Introductory Chapter: Introduction to Thermomechanics Problems 导论章:热力学问题导论
Pub Date : 2018-10-10 DOI: 10.5772/INTECHOPEN.79945
J. Winczek
Thermomechanics is a scientific discipline which investigates the behavior of bodies (solid, liquid, and gas) under the action forces and heat input. Thermomechanical phenomena commonly occur in the human environment, from the action of solar radiation to the technological processes. The analysis of these phenomena often requires extensive interdisciplinary knowledge, e.g., thermodynamics, continuum mechanics (solid and fluid), soil mechanics, biomechanics, metallurgy, hydraulics, civil engineering, and materials science and even anatomy, chemistry, meteorology, or hydrology. The wide range of thermomechanics applications depends on the field of science and the areas of knowledge in which phenomena are considered. The description of these phenomena requires not only knowledge of the laws of physics but the use of advanced mathematical apparatus, tensor algebra, and methods for solving differential and integral equations. Thermomechanical phenomena are analyzed using analytical and numerical methods. The analytical solution offers a quicker assessment of the searched values and its dependence on the various parameters, but for more complex problems, they are difficult or even impossible to apply. Some problems can be solved only with numerical methods, of which the finite element method is commonly used, but also methods of boundary elements, finite differences and elementary balances. In addition to the mentioned above methods, one needs to know how to solve complex equation systems (in case of the author’s original software) or to possess the ability to handle professional engineer’s packages. Thermomechanics therefore describes a broad category of phenomena. It is a generalization of classical mechanical theory and thermodynamic theory. Currently, thermomechanical coupling is a fully formed issue. Basic dependences and differential equations have been formulated based on mechanical and thermodynamic laws. Numerous methods and algorithms for solving differential equations of thermomechanical coupling have been developed, including the finite element method. Looking at the development of thermomechanics, we cannot omit scientists who laid the foundation for this area of science. First and foremost, Isaak Newton, the author of the three principles of dynamics [1], an outstanding physicist and mathematician, parallels with G.W. Leibniz who developed the theory of differential and integral calculus. In turn, the development of thermomechanics (and not only) was contributed by Fourier, the creator of the Fourier transform and Fourier series theories, which he used in his fundamental work on the theory of heat conduction [2]. One should also mention eminent scientists, the creator of the law of thermal radiation, Kirchhoff [3] and Maxwell [4, 5]. Over the past half-century, a number of
热力学是一门研究物体(固体、液体和气体)在作用力和热量输入下的行为的科学学科。热机械现象通常发生在人类环境中,从太阳辐射的作用到工艺过程。对这些现象的分析通常需要广泛的跨学科知识,例如热力学、连续介质力学(固体和流体)、土壤力学、生物力学、冶金学、水力学、土木工程和材料科学,甚至解剖学、化学、气象学或水文学。热力学的广泛应用取决于所考虑的科学领域和知识领域。对这些现象的描述不仅需要物理定律的知识,还需要使用先进的数学仪器、张量代数以及求解微分和积分方程的方法。采用解析和数值方法对热力学现象进行了分析。分析解决方案提供了对搜索值及其对各种参数的依赖的更快评估,但对于更复杂的问题,它们很难甚至不可能应用。有些问题只能用数值方法来解决,其中常用的是有限元法,还有边界元法、有限差分法和初等平衡法。除了上述方法外,还需要知道如何解决复杂的方程组(如果是作者的原始软件),或者拥有处理专业工程师软件包的能力。因此,热力学描述了一大类现象。它是经典力学理论和热力学理论的推广。目前,热-机械耦合是一个完全成熟的问题。基本的依赖关系和微分方程是根据力学和热力学定律制定的。许多求解热力耦合微分方程的方法和算法已经发展起来,其中包括有限元法。回顾热力学的发展,我们不能忽略为这一科学领域奠定基础的科学家。首先,艾萨克·牛顿,动力学三原理的作者[1],一位杰出的物理学家和数学家,与发展微分和积分理论的G.W.莱布尼茨相提并论。反过来,热力学的发展(不仅如此)是由傅立叶贡献的,傅立叶变换和傅立叶级数理论的创造者,他在热传导理论的基础工作中使用了傅立叶理论[2]。我们还应该提到杰出的科学家,热辐射定律的创造者基尔霍夫[3]和麦克斯韦[4,5]。在过去的半个世纪里,一些
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引用次数: 0
Practical Methods for Online Calculation of Thermoelastic Stresses in Steam Turbine Components 汽轮机部件热弹性应力在线计算实用方法
Pub Date : 2018-10-10 DOI: 10.5772/INTECHOPEN.75876
M. Banaszkiewicz, J. Badur
This chapter presents two practical methods of thermoelastic stress calculation suitable for application in online monitoring systems of steam turbines. Both methods are based on the Green function and Duhamel integral and consider the effect of variable heat transfer coefficient and material physical properties on thermal stresses. This effect is taken into account either by using an equivalent steam temperature determined with a constant heat transfer coefficient or by applying an equivalent Green ’ s function determined with variable heat transfer coefficient and physical properties. The effectiveness of both methods was shown by comparing their predictions with the results of exact three-dimensional (3D) calculations of a steam turbine valve.
本文介绍了适用于汽轮机在线监测系统的两种实用的热弹性应力计算方法。这两种方法都基于Green函数和Duhamel积分,并考虑了变传热系数和材料物理性质对热应力的影响。这种影响可以通过使用恒定传热系数确定的等效蒸汽温度或应用由可变传热系数和物理性质确定的等效格林函数来考虑。通过将两种方法的预测结果与汽轮机阀门的精确三维计算结果进行比较,证明了两种方法的有效性。
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引用次数: 2
Thermomechanics of Solid Oxide Fuel Cell Electrode Microstructures Using Finite Element Methods: Progressive Interface Degradation under Thermal Cycling 基于有限元方法的固体氧化物燃料电池电极微观结构热力学:热循环下界面逐步退化
Pub Date : 2018-04-02 DOI: 10.5772/INTECHOPEN.76118
Sushrut Vaidya, J. Kim
The electrochemical performance of solid oxide fuel cell (SOFC) is significantly influenced by three-phase boundary (TPB) zones in the microstructure. TPB zones are locations where all three phases comprising the microstructure such as the two solid phases and the pore phase are present. Electrochemical reactions such as oxygen reduction occur near TPBs, and TPB density is believed to affect the polarization resistance of the cathode. In this regard, the effect of interface degradation under repeated thermal loading on the mechanical integrity and electrochemical performance of solid oxide fuel cell (SOFC) electrodes is studied through finite element simulations. Image-based 3-D models are used in this study, with additional interface zones at the boundaries between dissimilar solid phases. These interface zones are composed of 3-D cohesive elements of small thickness. The effect of interface degradation on mechanical integrity is studied by subjecting 50:50 LSM:YSZ wt.% cathode models to increasing levels of thermal load from room temperature (20°C) up to operating temperature (820°C). Energy quantities (e.g., strain energy and damage dissipation) for cathode models with and without cohesive interface zones are obtained through finite element analysis (FEA). These quantities are compared using energy balance concepts from fracture mechanics to gain insight into the effects of interface degradation on mechanical integrity.
固体氧化物燃料电池(SOFC)微观结构中的三相边界区(TPB)对其电化学性能有显著影响。TPB带是构成微观结构的所有三相(如两相固相和孔隙相)都存在的位置。氧还原等电化学反应发生在TPB附近,TPB密度被认为会影响阴极的极化电阻。为此,通过有限元模拟研究了重复热载荷下界面退化对固体氧化物燃料电池(SOFC)电极机械完整性和电化学性能的影响。在本研究中使用了基于图像的三维模型,在不同固相之间的边界处添加了额外的界面区。这些界面区由小厚度的三维内聚元素组成。通过将50:50 LSM:YSZ wt.%阴极模型置于从室温(20°C)到工作温度(820°C)不断增加的热负荷水平,研究了界面退化对机械完整性的影响。通过有限元分析(FEA)获得了具有和不具有黏性界面区的阴极模型的能量(如应变能和损伤耗散)。使用断裂力学中的能量平衡概念对这些量进行比较,以深入了解界面退化对机械完整性的影响。
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引用次数: 1
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Selected Problems of Contemporary Thermomechanics
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