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集料化学特性对C-S-H成核和生长的影响 集料化学特性对C-S-H成核和生长的影响
Q4 Materials Science Pub Date : 2021-01-01 DOI: 10.14062/J.ISSN.0454-5648.20200759
Xiaowei Ouyang, Shida Xu, Yuwei Ma, G. Ye
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引用次数: 0
Preparation and properties of phase change ceramisite loaded with inorganic salt hydrate 水合无机盐负载相变陶粒的制备及性能研究
Q4 Materials Science Pub Date : 2016-07-01 DOI: 10.14062/J.ISSN.0454-5648.2016.07.22
D. Kong, Luoshen Pan, S. Zhan, Zheng Xiaohua, Yang Fang'er, Surendra P. Shah
Phase change ceramisite (PCC) was prepared by vacuum adsorption method using inorganic CaCl2·6H2O (CCH) as phase change material. Effects of loading in ceramsite on super–cooling of CCH during liquid–solid phase change process and surface–sealing treatment of PCC on properties of the cement–based composite phase change material were investigated. The results showed that the amount of CCH adsorbed in ceramsite was significantly higher compared to that of capric acid (CA), and the supercooling degree of CCH during liquid–solid phase change can be greatly reduced after being loaded in ceramisite. By simple clading with cement and PEG, the salt hydrate cannot be effectively sealed within ceramisite. The dewdrops appeared on the surface after exposed in the air for 3 d for claded with cement, and expansive cream–like substance was found on the surface after exposed in the air for one month for claded with PEG, leading to a destruction of PCC. After further loaded with capric acid or oily paint, incorporation of both PCC in cement–based materials can effectively lower the temperature rise during hydration. However, the hardened composite showed leakage of CA for the former case whereas no leakage appeared for the ceramisite coated by using oily paint.
以无机CaCl2·6H2O (CCH)为相变材料,采用真空吸附法制备相变陶粒(PCC)。研究了陶粒加载对固液相变过程中CCH过冷的影响,以及PCC表面密封处理对水泥基复合相变材料性能的影响。结果表明,CCH在陶粒中的吸附量明显高于癸酸(CA),且在陶粒中加载CCH后,可大大降低CCH在液固相变过程中的过冷度。通过简单的水泥和聚乙二醇包层,水合盐不能有效地密封在陶粒内部。水泥包覆层在空气中暴露3 d后表面出现露珠,PEG包覆层在空气中暴露1个月后表面出现膨胀的膏状物质,导致PCC破坏。在水泥基材料中进一步加载癸酸或油性涂料后,掺入这两种PCC可以有效降低水化过程中的温升。然而,硬化后的复合材料中,前者出现了CA的渗漏,而涂有油漆的陶粒则没有出现渗漏。
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引用次数: 0
Performance of Engineered Cementitious Composites After Treated at Sub-high Temperatures 亚高温处理后工程胶凝复合材料的性能
Q4 Materials Science Pub Date : 2015-05-01 DOI: 10.14062/J.ISSN.0454-5648.2015.05.09
Jianhui Lin, Jiangtao Yu, V. Li
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引用次数: 2
Occurrence State of SiO_2 in Hercynite Synthesized by Reaction Sintering 反应烧结法合成海方石中SiO_2的赋存状态
Q4 Materials Science Pub Date : 2015-01-01 DOI: 10.7521/J.ISSN.0454-5648.2015.03.15
Chen Junhong, M. Yan, Jin-dong Su, Bin Li, Yong Li, Zhihui Li, Jia-lin Sun, L. Dongfang
Sample was prepared using Fe2O3, Al2O3 and Si O2 powders as raw materials according to mass ratio Fe O:Al2O3 of 40.8:59.2 and adding a percent of Si O2 in the synthetic system, and being sintered under high purity nitrogen atmosphere at 1 600 ℃for 4 h. The sample was analyzed and characterized by X-ray diffraction, scanning electron microscope, energy dispersive spectroscopy and transmission electron microscope. Based on Fe O-Al2O3-Si O2 ternary phase diagram, the existence of silicon dioxide was investigated. The results indicate that silicon dioxide didn't enter into hercynite crystals, but existed among hercynite crystals as amorphous phase. When a percent of Si O2 was added into the synthetic system, amorphous phase containing Si O2 was discontinuously distributed and the direct contact among hercynite crystals wasn't changed.
以Fe2O3、Al2O3和Si O2粉末为原料,按Fe O:Al2O3的质量比为40.8:59.2,在合成体系中加入1%的Si O2,在1 600℃的高纯氮气气氛下烧结4 h,对样品进行了x射线衍射、扫描电镜、能量色散光谱和透射电镜的分析和表征。基于Fe o - al2o3 - sio2三元相图,研究了二氧化硅的存在性。结果表明,二氧化硅并未进入海方石晶体,而是以非晶态存在于海方石晶体中。当合成体系中加入一定比例的Si O2时,含Si O2的非晶态相不连续分布,并没有改变硅尖晶石晶体之间的直接接触。
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引用次数: 0
Durability and service life prediction of reinforced concrete structures 钢筋混凝土结构耐久性与使用寿命预测
Q4 Materials Science Pub Date : 2015-01-01 DOI: 10.14062/J.ISSN.0454-5648.2015.10.11
L. Tang, P. Utgenannt, Dimitrios Boubitsas
This paper presents some durability and service life models for reinforced concrete structures with regard to chloride ingress, carbonation and frost attack. In the past years a number of models for durability design of concrete structures have been suggested by relevant organisations or international committees. It is necessary to validate these models against long-term field data for their applicability with respect to exposure climate in order to satisfactorily use the models in the durability design and redesign of concrete structures. In this study, various potential models for concrete resistance to chloride ingress, carbonation and frost attack were briefly reviewed. Three models including the simple ERFC, the DuraCrete and the ClinConc, for prediction of chloride ingress were evaluated using the infield data collected from both the field exposure site after over 20 years exposure and the real road bridges of about 30 years old. A physicochemical model for prediction of carbonation depth was evaluated using the infield data collected from the field exposure site after 11 years exposure and the limited data from the real structures with the age of 7-13 years. For the modelling of frost attack, some problems in measurement of critical saturation degree and actual degree of saturation are discussed. According to the comparison results, the simple ERFC overestimates whilst the DuraCrete model underestimate the chloride ingress in most cases. The ClinConc model on the other hand gives reasonable good prediction for both the short-term (one year) and the long-term (21 years) exposure. The Papadakis model for carbonation also gives fairly good prediction of carbonation depth when compared with the Norwegian infield data classified as exposure class XC3, but underestimates the carbonation depths when compared with the infield data from Norwegian structures in exposure class XC4. For the frost attack, it is premature to apply the models to the service life prediction so far.
本文提出了钢筋混凝土结构在氯化物侵入、碳化和霜冻作用下的耐久性和使用寿命模型。在过去的几年中,有关组织或国际委员会提出了许多混凝土结构耐久性设计模型。为了在混凝土结构耐久性设计和再设计中令人满意地使用这些模型,有必要通过长期现场数据验证这些模型在暴露气候方面的适用性。本文简要介绍了混凝土抗氯离子侵入、抗碳化和抗霜冻的各种潜在模型。利用20年以上的现场暴露现场数据和30年左右的真实路桥数据,对简单ERFC、DuraCrete和ClinConc三种预测氯化物进入的模型进行了评价。利用野外暴露11年后收集的内野数据和7 ~ 13年真实构造的有限数据,对预测碳酸化深度的物理化学模型进行了评价。针对冻损模型,讨论了临界饱和度和实际饱和度测量中的一些问题。根据比较结果,在大多数情况下,简单ERFC模型高估了氯化物的进入量,而DuraCrete模型低估了氯化物的进入量。另一方面,ClinConc模型对短期(1年)和长期(21年)暴露都给出了合理的良好预测。与挪威XC3暴露等级的内野数据相比,Papadakis碳酸化模型也能很好地预测碳酸化深度,但与挪威XC4暴露等级的内野数据相比,该模型低估了碳酸化深度。对于冻损,目前将模型应用于使用寿命预测还为时过早。
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引用次数: 18
Performance and durability of concrete under effect of multi-deterioration mechanisms 多种劣化机制作用下混凝土的性能与耐久性
Q4 Materials Science Pub Date : 2015-01-01 DOI: 10.14062/J.ISSN.0454-5648.2015.10.12
E. Holt, M. Ferreira, H. Kuosa, M. Leivo
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引用次数: 6
Pyroelectric Performances of Relaxor‐Based Ferroelectric Single Crystals and their Applications in Infrared Detectors 弛豫铁电单晶的热释电性能及其在红外探测器中的应用
Q4 Materials Science Pub Date : 2014-03-01 DOI: 10.1002/9781118771402.CH1
Long Li, Haosu Luo, Xiangyong Zhao, Xiaobing Li, Bo Ren, Qing Xu, Wenning Di
Relaxor-based ferroelectric single crystals(i.e.,lead magnesium niobate-lead titanate(PMNT),Mn-doped PMNT, ternary lead indium niobate-lead magnesium niobate-lead titanate(PMNT)and Mn-doped PIMNT)exhibit a high piezoelectric performance and superior pyroelectric properties.The pyroelectric coefficients of 15.3×10-4C/m2 K and 17.2×10-4C/m2 K were obtained for PMN-0.26PT and Mn-doped PMN-0.26PT,respectively.The dielectric loss of binary and ternary relaxor-based single crystals decreases from 0.3%to 0.05%due to Mn ions doping,enhancing the detectivity figure of merit(Fd)from 15.3×10-5Pa-1/2to 40.2× 10-5 Pa-1/2 for Mn-doped PMN-0.26PT.The Fdof Mn-PIMNT(23/47/30)is 19.5×10-5Pa-1/2.Furthermore,the Curie temperature is 253℃for PIMNT(41/17/42)and 179℃for Mn-doped PIMNT(23/47/30),respectively.By using the Mn-doped PMNT single crystals as sensitive element and multi-walled carbon nanotubes as absorbing layer,we can obtain the superior infrared detector.The specific detectivity of Mn-doped PMNT-based detector is 3.0×109 cm·Hz1/2/W at 4Hz and 2.21×109 cm·Hz1/2/W at 10Hz,respectively,which are four times greater than that of LiTaO3-based detector.
基于弛豫剂的铁电单晶(即铌酸铅镁-钛酸铅(PMNT)、锰掺杂PMNT、铌酸铅铟-铌酸铅镁-钛酸铅(PMNT)和锰掺杂PIMNT均表现出优异的压电性能和热释电性能。PMN-0.26PT和mn掺杂PMN-0.26PT的热释电系数分别为15.3×10-4C/m2 K和17.2×10-4C/m2 K。由于Mn离子的掺杂,二元和三元弛豫单晶的介电损耗从0.3%降低到0.05%,提高了Mn掺杂PMN-0.26PT的探测性能指数(Fd),从15.3×10-5Pa-1/2to 40.2× 10-5Pa-1/2。Mn-PIMNT的Fdof(23/47/30)是19.5×10-5Pa-1/2。此外,PIMNT(41/17/42)和mn掺杂PIMNT(23/47/30)的居里温度分别为253℃和179℃。采用掺杂锰的PMNT单晶作为敏感元件,多壁碳纳米管作为吸收层,可以得到性能优越的红外探测器。掺锰pmnt基探测器在4Hz时的比探测率为3.0×109 cm·Hz1/2/W,在10Hz时的比探测率为2.21×109 cm·Hz1/2/W,是litao3基探测器的4倍。
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引用次数: 2
Bi 和 Nd 共掺 CsI 晶体近红外宽带发光性能 Bi 和 Nd 共掺 CsI 晶体近红外宽带发光性能
Q4 Materials Science Pub Date : 2013-06-01 DOI: 10.7521/J.ISSN.0454-5648.2013.06.13
Xiao Fan, Su Liangbi, Jun Xu, X. Jiang
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引用次数: 0
Influence Mechanism of Calcium Sulfate Variety on Strength of Portland Cement-calcium Aluminate Cement Blends 硫酸钙品种对硅酸盐水泥-铝酸钙水泥共混物强度的影响机理
Q4 Materials Science Pub Date : 2013-01-01 DOI: 10.7521/J.ISSN.0454-5648.2013.11.06
Xu Linglin, W. Peiming, Zhang Guofang, G. Schutter
The influence mechanism of calcium sulfate varieties on the strength of Portland cement-calcium aluminate cement blends were investigated by means of calorimetry, X-ray diffraction, environmental scanning electron microscopy. Results show that the variety of calcium sulfate determines its solubility and dissolution rate, which directly lead to the differences in the formation content,time and size of ettringite(AFt), and affects the volume stability, which finally determines the strength of pastes. When the calcium sulfate dosage is 7.5%, the formation content of AFt firstly increases and then decreases. However, the time when AFt content reaches the maximum and the size of AFt have close relationships with the variety of calcium sulfate. When anhydrite is added, the transit time from AFt to monosulfate is the latest, and the size of AFt is much longer and thinner than those with other calcium sulfate, additionally the AFt content before 8 hours is prominently lower than others, which leads to lower strength. When the calcium sulfate dosage is 15%, secondary gypsum also forms besides AFt, is ten times bigger than AFt. This can lead to the expansion and even complete lost of strength for the systems with hemi-hydrite.
采用量热法、x射线衍射、环境扫描电镜等手段研究了硫酸钙品种对硅酸盐水泥-铝酸钙水泥共混物强度的影响机理。结果表明,硫酸钙的种类决定了其溶解度和溶解速率,直接导致钙矾石(AFt)的形成含量、时间和粒度的差异,并影响其体积稳定性,最终决定了膏体的强度。当硫酸钙用量为7.5%时,AFt的生成含量先增加后降低。而AFt含量达到最大值的时间和AFt的大小与硫酸钙的种类有密切的关系。添加硬石膏时,AFt向单硫酸盐过渡的时间最晚,且AFt的粒径比添加其他硫酸钙的AFt长得多、薄得多,且8 h前AFt的含量明显低于其他硫酸钙,从而导致强度降低。当硫酸钙用量为15%时,除AFt外还会形成二次石膏,其体积是AFt的10倍,这可能导致半水合体体系膨胀甚至完全失去强度。
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引用次数: 5
Spectroscopic characteristics of Nd 3+ -doped yttrium lanthanum oxide trans parent ceramics Nd - 3+掺杂氧化钇镧透明陶瓷的光谱特性
Q4 Materials Science Pub Date : 2006-11-09 DOI: 10.7498/aps.55.6414
Ding Jun, Yang Qiu-hong, Tang Zai-feng, Xu Jun, Su Liang-Bi
Nd 3+ -doped Y 2-2 x La 2 x O 3 ( x =0.08) transparent ceramics were fabricated by conventional fabrication process. Spectroscopic properties of the samples were investigated. The absorption band of Nd 3+ : Y 1.84 La 0.16 O 3 was broad covering the wavelength range 780—850 nm. When doped with 1.5at% Nd 3+ , the cross sections of the sample at 820 nm and laser diode pumped 808 nm were 1.81×10 -20 cm 2 and 1.54×10 -20 cm 2 , respectively. The strongest emission peak of the sample was centered at 1078 nm with long fluorescent lifetime, broad emission bandwidth and high quantum efficiency. Because of the additive La 2 O 3 , the spectroscopic quality parameter ( X Nd ) of matrix was decreased from 1.6 to 0.46, thus the fluorescence branch ratio of 4 F 3/2 — 4 I 11/2 transition was increased to 56.82%. These properties of Nd 3+ : Y 1.84 La 0.16 O 3 transparent ceramic are benefitial to achieve high efficient laser output and ultrashort modelocked pulse.
采用常规工艺制备了Nd 3+掺杂y2 -2 × l2 × o3 (x =0.08)透明陶瓷。对样品的光谱特性进行了研究。Nd 3+: y1.84 la0.16 o3的吸收带较宽,覆盖780 ~ 850 nm的波长范围。当掺1.5at% Nd 3+时,样品在820 nm和激光二极管泵浦808 nm处的截面分别为1.81×10 -20 cm 2和1.54×10 -20 cm 2。样品的最强发射峰集中在1078 nm处,荧光寿命长,发射带宽宽,量子效率高。由于添加了la2o3,使基体的光谱质量参数(X Nd)从1.6降低到0.46,使4f3 /2 - 4i11 /2跃迁的荧光支比提高到56.82%。Nd 3+: y1.84 la0.16 o3透明陶瓷的这些特性有利于实现高效的激光输出和超短锁模脉冲。
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引用次数: 0
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Kuei Suan Jen Hsueh Pao/ Journal of the Chinese Ceramic Society
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