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Evaluation of Potassium Status Using Thermodynamic Relationships in some Soils of Ismailia Governorate, Egypt 利用热力学关系评估埃及伊斯梅利亚省某些土壤中的钾状况
Pub Date : 2024-02-01 DOI: 10.21608/jsws.2024.266709.1005
Mohamed Abdelbary, Ozoris Ali, Noha A. Mahgoub, E. M. Elsikhry
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引用次数: 0
Removal of Cd (II) and Pb (II) Ions from Aqueous Solutions Using Raw and Modified Activated Carbon 原料活性炭和改性活性炭去除水溶液中的Cd (II)和Pb (II)离子
Pub Date : 2022-12-01 DOI: 10.21608/jsws.2022.290564
Magdy Ibrahim and Mai Rashwan
: The main objective of this study is to investigate the feasibility of using raw and modified activated carbon with ammonia for the maximum removal of Pb 2+ and Cd 2+ ions from aqueous solutions and polluted water samples at optimized process parameters such as initial metal concentration, adsorbent dose, contact time and solution pH. The treatment of a commercial granular activated carbon by ammonia was performed to increase the power of the heavy metal ions removal from aqueous samples. In this work, the adsorption of these ions on raw and modified activated carbon was studied using the batch equilibrium technique, and the equilibrium adsorption data was described by Langmuir isotherm models. In the current work, Pb 2+ and Cd 2+ ions were adsorbed out of aqueous solutions using raw and modified activated carbon as an adsorbent. Investigations have been done into the effects of solution pH, contact time, initial metal ion concentrations, and adsorbent dosage on removal efficiency. The pH studies demonstrated that Pb 2+ and Cd 2+ ion removal efficiency is pH-dependent, increasing with increasing pH value, peaking at pH 6.5, and then remaining nearly constant. Due to an increase in the number of adsorption sites, an increase in adsorbent mass causes an increase in Pb 2+ and Cd 2+ adsorption. According to the data, activated carbon has removal efficiency (96.0 - 98.0%) for removing Pb 2+ and Cd 2+ ions from aqueous solutions in the initial metal concentration range of 10 to 50 mg/l. The experimental data suited the Langmuir and Freundlich adsorption isotherms well, and their constants were assessed. The effectiveness of Pb 2+ ions removal by adsorption (starting Pb 2+ concentration ranging from 1 - 10 mg/l) is shown by the treatment results of various polluted water samples to be between (81.5 - 86.7%), between (91 - 98%), utilizing raw Activated carbon (R-AC) and modified activated carbon with ammonia (A-AC), respectively. the results for cadmium ions reveal that the effectiveness of Cd 2+ ions removal by adsorption (starting Cd 2+ concentration ranging from 1 to 10 mg/l) is ranged from (74.3 to 83.7%), and from (97.6 to 98.4%) when the raw activated carbon (R-AC) and modified activated carbon with ammonia (A-AC) are used, respectively.
:本研究的主要目的是调查使用原始的可行性和改性活性炭对Pb的最大去除氨2 + 2和Cd +离子水溶液和受污染水样在优化的工艺参数如初始金属浓度、吸附剂剂量,接触时间和解决方案博士商业粒状活性炭的处理氨进行增加重金属离子去除的力量从水样本。采用间歇平衡技术研究了改性活性炭对这些离子的吸附,并用Langmuir等温线模型描述了平衡吸附数据。本研究以改性活性炭为吸附剂,对pb2 +和cd2 +离子进行了吸附。研究了溶液pH、接触时间、初始金属离子浓度和吸附剂用量对去除率的影响。pH研究表明,pb2 +和cd2 +离子的去除效率与pH值有关,随着pH值的增加而增加,在pH值为6.5时达到峰值,之后基本保持不变。由于吸附位点数量的增加,吸附剂质量的增加导致Pb 2+和Cd 2+的吸附量增加。实验结果表明,在初始金属浓度为10 ~ 50 mg/l的水溶液中,活性炭对pb2 +和cd2 +离子的去除率为96.0% ~ 98.0%。实验数据符合Langmuir和Freundlich吸附等温线,并计算了它们的常数。不同污染水样的处理结果表明,原料活性炭(R-AC)和氨修饰活性炭(A-AC)对pb2 +离子的吸附去除效果(初始pb2 +浓度为1 ~ 10 mg/l)分别在(81.5 ~ 86.7%)和(91 ~ 98%)之间。对镉离子的吸附结果表明,在初始浓度为1 ~ 10 mg/l的条件下,原料活性炭(R-AC)和氨修饰活性炭(A-AC)对镉离子的吸附去除率分别为74.3 ~ 83.7%和97.6 ~ 98.4%。
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引用次数: 0
Influence of Incorporating Shredded Corn Stover on some Physicochemical Properties of the Soil and Corn Crop Production 掺入玉米秸秆碎料对土壤理化性质及玉米作物生产的影响
Pub Date : 2022-12-01 DOI: 10.21608/jsws.2022.290562
Awad R.; G. M. ElMasry S. A. M. Abd El-Azeem
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引用次数: 0
Effects of Co-Inoculation of Rhizobium and Plant Growth-Promoting Rhizobacteria on Common Bean (Phaseolus vulgaris) Yield, Nodulation, Nutrient Uptake, and Microbial Activity under Field Conditions 田间条件下共接种根瘤菌和促生根瘤菌对菜豆产量、结瘤、养分吸收和微生物活性的影响
Pub Date : 2022-12-01 DOI: 10.21608/jsws.2022.290563
Samy Abd El-Malik Mohamed Abd El-Azeem
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引用次数: 0
Impact of Water Seepage of New Suez Canal on Soil Properties of El-Amal Area, Ismailia East, Egypt 新苏伊士运河渗水对埃及伊斯梅利亚东部El-Amal地区土壤性质的影响
Pub Date : 2021-12-01 DOI: 10.21608/jsws.2021.262001
A. Elwan
: Seawater seepage poses a major problem for agriculture in Egypt’s coastal areas. In 2020, a 285 Faddan area in El-Amal, Ismailia East was selected as a representative soil model for Egypt’s New Suez Canal region to investigate the impact of seawater seepage on soil properties and identify the responsible factors for land degradation, with an emphasis on suitable adaptations to land limitations and climate stressors. Seawater changes the behavior of soil and creates geotechnical problems that enhance soil alkalinity and salinity value. Five soil mapping units (SMUs) were identified with moderately to shallow soils dominating, in a detailed soil survey that was conducted in the field to conduct pedomorphological and physicochemical investigations. The water table had raised by 50–100 cm within the soil pedons. Approximately 45.4 Faddans were recognized as sabkhas due to the inundation of lowlands with seawater. Most study lands (217.2 Faddan) were unsuitable for cultivation due to the higher limitations of salinity, alkalinity, soil structure, and poor drainage under saturation conditions. The salinity of saturated soil reached 29.60 dS/m, posing a major challenge to agriculture. The results indicated that the pedomorphological and physicochemical properties of most study soils had degraded and become unsuitable for cultivation, which was linked to the seawater seepage. It is predicted that the rest lands (SMU1 and SMU2) and other adjacent lands to the study area are expected to change into desertified lands in the future due to continuous seawater seepage. The New Suez Canal’s seawater seepage caused the cultivated fruit trees and other vegetation in the study area to dry up and die. Climate change-induced seawater seepage and drought were the direct causes of soil salinization in the study lands. To achieve long-term sustainability and avoid maladaptive outcomes, an urgent need to adopt an integrated approach for large-scale investments in Egypt’s farming sector is urgently needed for effective policymaking toward achieving food security, with it being recognized that climate change has adverse effects and challenges to the soil resources in Egypt, and therefore, the sustainable planning of natural resources in coastal areas should be further studied and thoroughly managed. Adopting local adaptation actions and strategies for incremental, systemic, and transformational changes at the farm and on large scales in the agricultural sector is critical. The transformational adaptation actions are the suitable practices, followed by incremental and systemic adaptations to combat the agricultural limitations and climate change stressors in the current study lands.
海水渗漏对埃及沿海地区的农业造成了重大问题。2020年,伊斯梅尔东部El-Amal的285 Faddan地区被选为埃及新苏伊士运河地区的代表性土壤模型,以研究海水渗透对土壤性质的影响,并确定土地退化的负责因素,重点是对土地限制和气候压力的适当适应。海水改变了土壤的行为,产生了岩土工程问题,提高了土壤的碱度和盐度值。在野外进行了详细的土壤调查,进行了土壤形态和物理化学调查,确定了5个土壤作图单元(smu),以中浅土壤为主。地下水位上升了50 ~ 100厘米。由于低地被海水淹没,大约45.4个faddan被认为是sabkhas。大部分研究用地(217.2发丹)由于盐碱度、土壤结构限制较大,且在饱和条件下排水差,不适合种植。饱和土壤含盐量达到29.60 dS/m,对农业构成重大挑战。结果表明,大部分研究土壤的土壤形态和理化性质已经退化,不适合耕作,这与海水渗流有关。据预测,由于海水持续渗流,未来研究区剩余土地(SMU1和SMU2)及周边其他土地有望变为沙化土地。新苏伊士运河的海水渗漏导致研究区内栽培的果树和其他植被干涸死亡。气候变化引起的海水渗漏和干旱是研究区土壤盐渍化的直接原因。为了实现长期的可持续性,避免不适应的结果,迫切需要对埃及农业部门的大规模投资采取综合方法,以有效地制定政策,实现粮食安全,同时认识到气候变化对埃及土壤资源的不利影响和挑战,因此,应进一步研究和彻底管理沿海地区自然资源的可持续规划。采取地方适应行动和战略,在农场和农业部门进行渐进式、系统性和转型变革至关重要。转型适应行动是适当的实践,其次是渐进和系统的适应,以应对当前研究土地上的农业限制和气候变化压力。
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引用次数: 0
Formation and Taxa of some Wadi Dahab Tributaries Soils, South Sinai, Egypt 埃及南西奈一些瓦迪达哈卜支流土壤的形成和分类群
Pub Date : 2018-08-07 DOI: 10.21608/jsws.2018.58715
A. Elwan
Geological parent material is a soil forming factor which controls the particle size distribution (PSD), geochemical characterization, and mineralogical properties. In Wadi Dahab Basin at southeastern Sinai of Egypt, four main tributaries (Al-Ghaib, Zoghra, Abu-Khashab and Um-Ism) and their subtributaries, having different geological parent materials, were selected and mapped. Sixteen pedons containing 51 sediment samples across the slope gradient (1335-9 m) of Wadi Dahab Basin representing all its tributaries and subtributaries were exhaustively analysed for the purposes of: (1) detecting the lithologic discontinuities (LDs) through soil morphology and uniformity indices; (2) recognizing the weathering intensity using the geochemical data; (3) identifying the sediments provenance via heavy mineral distribution; and (4) classifying the soils up to family level. LDs in most pedons revealed sequences of deposition and erosion processes and the heterogeneity of the parent material. The vertical distribution of coarse fragments within a pedon is proposed as a morphologic indicator (as with other clay-free basis indices) to detect LDs in soils. The Fe2O3 and Al2O3 were relatively enriched at downslope positions while SiO2, MgO, K2O, and Na2O were strongly lost during sediment weathering and soil formation, with the exception of CaO that was highly affected by CaCO3 content. The heavy minerals characteristics suggest their mixed sources from sandstone, limestone, granites, and metamorphic rocks. The heavy minerals concentration and geochemical oxides in most studied pedons followed the LD set, indicating further approaches for detecting LDs. Pedons from upslope positions were immature sediments and classified as Entisols while pedons from the downslopes of Wadi Al-Ghaib, Wadi Zoghra, and Wadi Dahab's delta were submature sediments and classified as Aridisols. Furthermore, six families were identified across the study area. Indices based on PSD, geochemical, and mineralogical data were evaluated and further implications of the results were discussed in the text.
地质母质是控制土壤粒度分布、地球化学特征和矿物学性质的土壤形成因子。在埃及西奈半岛东南部的Wadi Dahab盆地,选取了具有不同地质母质的Al-Ghaib、Zoghra、Abu-Khashab和Um-Ism四条主要支流及其支流,并进行了作图。对瓦底达哈卜盆地所有支流和次支流的16个坡脚(含51个沉积物样本)进行了详尽的分析,目的是:(1)通过土壤形态和均匀性指数检测岩性不连续面(LDs);(2)利用地球化学资料识别风化强度;(3)通过重矿物分布识别沉积物物源;(4)按科级对土壤进行分类。大部分土墩的LDs显示了沉积和侵蚀过程的序列以及母质的非均质性。土墩内粗碎片的垂直分布被提出作为一种形态指标(与其他无粘土基指标一样)来检测土壤中的ld。Fe2O3和Al2O3在下坡位置相对富集,SiO2、MgO、K2O和Na2O在沉积物风化和成土过程中损失严重,但CaO受CaCO3含量影响较大。重矿物特征表明其主要来源为砂岩、石灰岩、花岗岩和变质岩。大多数研究区的重矿物浓度和地球化学氧化物均遵循LD集,为LD的进一步探测指明了方向。上坡位置的土墩为未成熟沉积,属完整溶质(Entisols); Wadi Al-Ghaib、Wadi Zoghra和Wadi Dahab三角洲下坡位置的土墩为次成熟沉积,属干旱溶质(aridisol)。此外,在整个研究区域确定了六个家庭。本文对基于PSD、地球化学和矿物学数据的指数进行了评价,并讨论了结果的进一步意义。
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引用次数: 1
Anthropogenic Impacts on Soils of Wadi Al-Molak, Suez Canal West, Egypt 埃及苏伊士运河西部Wadi Al-Molak地区土壤的人为影响
Pub Date : 2018-08-07 DOI: 10.21608/jsws.2018.58714
A. Elwan
The past three decades saw rapid and massive agriculture in Wadi Al-Molak at west of Suez Canal, Egypt. Land cover and pedon changes were studied in 850 km of the Wadi Al-Molak catena using time series and paired-site approach, respectively. The aim was to better understand the anthropogenic impacts responsible for the change of land cover and soil characteristics vertically within pedons and horizontally across landscapes under different ages of cultivation. Five landscapes were recognized: mountains and piedmont slope at upland; alluvial plain at midland; bajada plain and Nile old deltaic plain at lowland. The available Landsat images were analyzed from December 1986 to December 2016 of the Wadi to track the agrarian expansions in epochs (till 1986, 1987-1996, 1997-2006, and 20072016). Forty-three pedons were randomly distributed throughout the five landscapes representing both of cultivated soils under all periods and native soils. Detailed soil morphological as well as selected physical and chemical characteristics were studied. Soil morphology and taxonomy from five landscapes were used to interpret the anthropogenic impacts. Landscapes and soils were altered by conversion to agriculture for direct human use. Among out key findings are that (1) the agricultural areas increased from 225 km in 1986 to 475 km in 2016 while the annual expansion rate decelerated from 11.8 kmyr in 1996 to 2.2 kmyr in 2016; (2) the majority of agrarian expansions during 1987-2016 mainly occurred on alluvial plain landscape; (3) availability of irrigation water, soil potentialities, and national policies were the major driving forces; (4) solum horizons and redoximorphic/ped surface features occurred in cultivated soils and absent in native soils; (5) soil moisture regime was changed to anthraquic under sustained paddy cultivation, suggesting a modification in USDA Soil Taxonomy; (6) soil solum thickness increased with increasing time of cultivation; (7) formation of salic and natric horizons with high soil bulk density in lowland indicated soil degradation process as a result of mismanagement; (8) pedons under cultivation contained greater concentrations of organic carbon, total nitrogen, and clay than pedons under natural vegetation; and (9) the cultivated soils were classified as Aridisols or Vertisols while the native soils were classified as Entisols. The results demonstrated that agricultural expansion had changed the land cover, soil morphological, physical, and chemical properties, even the soil types. These results are very valuable for better understanding soil genesis and evolution with agricultural utilization.
在过去的30年里,埃及苏伊士运河以西的瓦迪莫拉克(Wadi Al-Molak)迅速发展了大规模的农业。采用时间序列法和配对样地法对Wadi Al-Molak流域850 km的土地覆盖和土壤变化进行了研究。目的是为了更好地了解不同耕作年限下,土壤覆被和土壤特征变化的人为影响。识别出五种景观:山地和高地山前坡;中部的冲积平原;巴哈达平原和尼罗河古三角洲平原在低地。利用1986年12月至2016年12月的Wadi陆地卫星图像,对不同时期(至1986年、1987-1996年、1997-2006年和2007 - 2016年)的土地扩张进行了分析。43个土墩随机分布在5个景观中,分别代表了不同时期的耕地土壤和原生土壤。研究了土壤的详细形态特征和部分理化特征。利用5个景观的土壤形态和分类来解释人为影响。景观和土壤因转为农业供人类直接利用而改变。主要发现有:(1)农业面积从1986年的225公里增加到2016年的475公里,而年扩张速度从1996年的11.8平方公里下降到2016年的2.2平方公里;(2) 1987—2016年,大部分土地扩张主要发生在冲积平原景观;(3)灌溉水可利用性、土壤潜力和国家政策是主要驱动因素;(4)栽培土壤中存在土壤层位和土壤表面特征,原生土壤中不存在;(5)在水稻持续栽培条件下,土壤水分状态转变为炭疽状态,表明美国农业部土壤分类有一定的修改;(6)土壤厚度随栽培时间的延长而增加;(7)低海拔地区土壤容重较高的盐碱层和天然层的形成表明由于管理不善导致土壤退化;(8)人工栽培土壤的有机碳、全氮和粘粒含量均高于自然植被;(9)将栽培土壤划分为干旱区和垂直区,将原生土壤划分为完整区。结果表明,农业扩张改变了土地覆被、土壤形态、理化性质甚至土壤类型。这些结果对于更好地了解土壤的发生与演变具有重要的指导意义。
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引用次数: 2
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Journal of Soil and Water Sciences
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