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Advances on Molecular Systems for Photocatalytic CO2 Reduction Based on Cobalt Complexes as Catalysts 基于钴配合物的光催化CO2还原分子体系研究进展
Q4 Engineering Pub Date : 2017-09-15 DOI: 10.7517/J.ISSN.1674-0475.2017.04.025
Gui Mengxi, Yu Yang, Zhu Chengyi, Liu Hongfang, Wang Feng
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引用次数: 0
Controlling and Application of the Triplet Excited State of Organic Chromphores 有机发色体三重激发态的控制与应用
Q4 Engineering Pub Date : 2017-05-15 DOI: 10.7517/J.ISSN.1674-0475.2017.03.211
Wang Zhijia, Chen Kepeng, L. Ya, Zhao Jianzhang, Zafar Mahmood, Jianwei Wei, H. Keli
{"title":"Controlling and Application of the Triplet Excited State of Organic Chromphores","authors":"Wang Zhijia, Chen Kepeng, L. Ya, Zhao Jianzhang, Zafar Mahmood, Jianwei Wei, H. Keli","doi":"10.7517/J.ISSN.1674-0475.2017.03.211","DOIUrl":"https://doi.org/10.7517/J.ISSN.1674-0475.2017.03.211","url":null,"abstract":"","PeriodicalId":39957,"journal":{"name":"Yingxiang Kexue yu Guanghuaxue/Imaging Science and Photochemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77242230","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of Bifunctional One-component Photoinitiator and Its Initiatiating Activity 双功能单组分光引发剂的合成及其引发活性
Q4 Engineering Pub Date : 2016-11-15 DOI: 10.7517/J.ISSN.1674-0475.2016.06.505
Jian Kai, Liu Dongbing, Zhou Jindi, Yang Jinliang, Nie Jun
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引用次数: 0
光还原制备石墨烯-硫化钼RGO—MoSx产氢催化剂 光还原制备石墨烯-硫化钼RGO—MoSx产氢催化剂
Q4 Engineering Pub Date : 2015-11-16 DOI: 10.7517/J.ISSN.1674-0475.2015.06.461
王静, 张慧慧, 高雨季, 叶晨, 冯科, 陈彬, 张丽萍, 佟振合, 吴骊珠
本文以石墨烯氧化物(GO)和硫代钼酸铵((NH4)2MoS4)为前体,曙红(EY)和三乙醇胺(TEOA)为光敏单元和电子牺牲体,通过一种环境友好的光还原方法原位制备了石墨烯一硫化钼(RGO-MoSx)产氢催化剂。RGO-MoSx表现出高效的催化产氢活性,石墨烯的引入使其催化产氢效率提高至原来的2.10倍。通过傅里叶红外光谱(FTIR)、拉曼光谱(Raman)、透射电子显微镜(TEM)和X射线光电子能谱(XPS)表征,证实了RGO-MoSx的组成、结构及形貌特征。
本文以石墨烯氧化物(GO)和硫代钼酸铵((NH4)2MoS4)为前体,曙红(EY)和三乙醇胺(TEOA)为光敏单元和电子牺牲体,通过一种环境友好的光还原方法原位制备了石墨烯一硫化钼(RGO-MoSx)产氢催化剂。RGO-MoSx表现出高效的催化产氢活性,石墨烯的引入使其催化产氢效率提高至原来的2.10倍。通过傅里叶红外光谱(FTIR)、拉曼光谱(Raman)、透射电子显微镜(TEM)和X射线光电子能谱(XPS)表征,证实了RGO-MoSx的组成、结构及形貌特征。
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引用次数: 0
Non-hydrothermal Method for Preparation of Nickel Sulfide Loaded Carbon Nanotubes for Catalytic Hydrogen Evolution 非水热法制备硫化镍负载碳纳米管催化析氢
Q4 Engineering Pub Date : 2015-03-15 DOI: 10.7517/J.ISSN.1674-0475.2015.02.117
Y. Shan, Ouyang Bo, Li Zhi-jun, Meng Qingyuan, F. Ke, Chen Bin, Tong Zhen-he, Wu Li-Zhu
{"title":"Non-hydrothermal Method for Preparation of Nickel Sulfide Loaded Carbon Nanotubes for Catalytic Hydrogen Evolution","authors":"Y. Shan, Ouyang Bo, Li Zhi-jun, Meng Qingyuan, F. Ke, Chen Bin, Tong Zhen-he, Wu Li-Zhu","doi":"10.7517/J.ISSN.1674-0475.2015.02.117","DOIUrl":"https://doi.org/10.7517/J.ISSN.1674-0475.2015.02.117","url":null,"abstract":"","PeriodicalId":39957,"journal":{"name":"Yingxiang Kexue yu Guanghuaxue/Imaging Science and Photochemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2015-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89158203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fluorescence “Turn-on” Sensor for Cyanide Based on Phenazine Derivative 基于非那嗪衍生物的氰化物荧光“开启”传感器
Q4 Engineering Pub Date : 2014-01-15 DOI: 10.7517/J.ISSN.1674-0475.2014.01.113
Y. Lin, Zhang Xiao, QU Weisong, H. Jianli
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引用次数: 0
Surface Properties of UV-Heat Cured Films of Organosilicon Modified Epoxy Monoacrylates 有机硅改性环氧丙烯酸酯紫外光热固化膜的表面性能
Q4 Engineering Pub Date : 2013-03-15 DOI: 10.7517/J.ISSN.1674-0475.2013.02.005
Liu Hong-bo, Lin Feng, Xiao Wang-dong, X. Ling, Zhang Wu-ying
A series of UV-heat hybrid curable compositions were prepared by using organosilicon modified epoxy monoacrylates(OMEMA) as resins.The change of absorption peaks of double bond and epoxy group were identified by FTIR spectra during UV-heat curing process.The influence of different kinds and content of active diluents on the gel content,water absorption and water contact angle of UV-heat cured films were investigated.Mass content of Si in surface of UV-heat cured films was tested by the energy dispersive spectrometer(EDS).The gel contents of UV cured films were lower than 86.5%,and the gel contents of UV-heat cured films were about 97%.Compared to the epoxy monoacrylates(EMA) compositions with same active diluents,the water contact angle of UV-heat cured films of OMEMA system was increased from 62.53 to 99.27.The data of EDS testing proved that the Si content of air side of UV-heat cured films was higher than glass side.
以有机硅改性环氧单丙烯酸酯(OMEMA)为树脂制备了一系列紫外光热复合固化组合物。利用红外光谱分析了紫外光热固化过程中双键和环氧基团吸收峰的变化。研究了不同活性稀释剂种类和含量对紫外光热固化膜的凝胶含量、吸水性和水接触角的影响。用能谱仪(EDS)测定了紫外光热固化膜表面硅的质量含量。UV固化膜的凝胶含量低于86.5%,UV热固化膜的凝胶含量约为97%。与相同活性稀释剂的环氧单丙烯酸酯(EMA)组合物相比,OMEMA体系紫外光固化膜的水接触角由62.53提高到99.27。EDS测试数据证明,紫外热固化膜的空气侧Si含量高于玻璃侧Si含量。
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引用次数: 0
Progresses on Sensitization of Cationic Photoinitiators 阳离子光引发剂敏化研究进展
Q4 Engineering Pub Date : 2013-01-15 DOI: 10.7517/J.ISSN.1674-0475.2013.01.009
Z. Hong, Liang Jianxiong, L. Anhua
The curing rate and quantum efficiency of cationic photoinitiators are relatively low because the UV absorption of the photoinitiators ranges from 250 nm to 300 nm normally and does not match with the wavelength of light from UV light sources.To make the absorption red-shift,many efforts have been devoted onto the photosensitization of the photoinitiators.The achievements on the sensitization of the cationic photoinitiators have been summarized here.The sensitization is mainly based on the mechanisms as energy transfer,oxidation of free radical,electron transfer via exciplexes and addition fragmentation reaction.The methods adopted for the sensitization include adding photosensitizer,expanding molecular conjugation and attaching chromophore.The development of the photoinitiators and photosensitizers has been outlined and the applications of novel cationic photoinitiators and photosensitizers have been forecasted.
阳离子光引发剂的固化速率和量子效率相对较低,因为其对紫外光的吸收通常在250 ~ 300 nm之间,与紫外光的波长不匹配。为了使吸收红移,人们对光引发剂的光敏化进行了大量的研究。本文综述了阳离子光引发剂敏化的研究进展。敏化机理主要是能量传递、自由基氧化、杂络合物电子传递和加成破碎反应。敏化的方法包括添加光敏剂、扩大分子偶联和附着发色团。概述了光引发剂和光敏剂的研究进展,并对新型阳离子光引发剂和光敏剂的应用前景进行了展望。
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引用次数: 0
Progress in Preparation of Functional Films by Spin-Coating 旋涂法制备功能薄膜的研究进展
Q4 Engineering Pub Date : 2012-03-15 DOI: 10.7517/J.ISSN.1674-0475.2012.02.91
Wang Dong, Liu Hong-ying, He Jun-hui, Liu Lin-lin
Spin-coating,as one of thin film preparation methods,has advantages of precise thickness control,high cost performance,energy saving,low pollution,etc.Thin films fabricated by spin-coating are widely applied in the areas of microelectronics,nanophotonics,biology,medicine,etc.In this paper,fundamental processes and estimation methodologies of key parameters for spin-coating are briefly introduced.Then a range of advanced applications and recent progresses of spin-coating technology within several disciplines are reviewed,including optics,microelectronics,etc.Finally,the developing trend of spin-coating technology is also discussed.
旋涂作为薄膜制备方法之一,具有厚度控制精确、性价比高、节能、低污染等优点。自旋镀膜技术在微电子、纳米光子学、生物、医学等领域有着广泛的应用。本文简要介绍了旋涂工艺的基本流程和关键参数的估计方法。综述了自旋镀膜技术在光学、微电子等领域的最新应用和进展。最后,对旋涂技术的发展趋势进行了展望。
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引用次数: 2
Discussion about the Hazards and Preventive Measures of Cine Film Acetic Acid Syndrome 浅谈电影胶片醋酸综合征的危害及预防措施
Q4 Engineering Pub Date : 2011-11-23 DOI: 10.7517/J.ISSN.1674-0475.2011.06.464
Zhou Ya-Jun, Li Yu-hu
The cine film,as a kind of important historical and cultural heritage,is an important part of the archives protection works.The cellulose triacetate base cinefilm is the largest group in library collections,the acetic acid syndromes is produced from the hydrolysis of the cellulose triacetate ester base film under the storage condition of high temperature and humidity and other adverse environment.Acetic acid syndrome has become the major diseases which threaten the archives preservation of cellulose triacetate cine film,which is considered the cancer of cine film.This paper summarizes the hazards and analyses the reasons of acetic acid syndrome,and preventive measures are introduced.
电影胶片作为一种重要的历史文化遗产,是档案保护工作的重要组成部分。三醋酸纤维素基薄膜是图书馆馆藏中最大的一类,醋酸综合征是三醋酸纤维素基薄膜在高温高湿等不利环境下贮存条件下水解而产生的。醋酸综合征已成为威胁三醋酸纤维素电影胶片档案保存的主要疾病,被认为是电影胶片的癌症。本文总结了醋酸综合征的危害,分析了其产生的原因,并介绍了预防措施。
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引用次数: 1
期刊
Yingxiang Kexue yu Guanghuaxue/Imaging Science and Photochemistry
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