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Study on Recovery, Accumulation and Reuse of Kinetic Energy When Going downhill to Support the Departure and Upward Movement of Small-Sized Timber Tractor complexes 小型木材拖拉机组合体下坡时动能的回收、积累和再利用以支持其出发和向上运动的研究
Mai Hoang Long
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引用次数: 0
Electronic absorption spectra of nickel (II) complexes used for sensitized solar cells: DFT/TDDFT Study 敏化太阳能电池用镍(II)配合物的电子吸收光谱:DFT/TDDFT研究
Sefia Brahim
A detailed theoretical study of electronic absorption spectra of Ni(II) complexes in a distorted square planar form. Such complexes have been the goal of several researches due to their special properties in many aspects; they are investigated in terms of their pertinence for use in DSSCs. We investigated the electronic structures and UV-Vis spectra of Ni(II) complexes with density functional theory (DFT) and time-dependent density functional theory (TDDFT) calculations with CAM-B3LYP and PBE0 hybrid functional. Moreover, the analysis of the frontier molecular orbitals (FMOs) which allowed a detailed assignment to interpret the electronic transitions of the calculated spectral properties. The influences of functional, substitution and solvent on electronic spectra have been assessed. According to the computed results, the geometry optimization was in good agreement with the experimental results from X-ray diffraction. The theoretical calculations reproduce the main observed spectroscopic proprieties and substituent effects of ecda and dtc ligands on the absorption spectra. As experimentally observed, computations results reveal that all complexes show a tree absorption bands in UV region and very low absorption one in visible region. We have assigned these bands to the electronic transitions answerable for their appearance; they are characterized by mixed character mainly dominated by MLCT and LLCT character.
扭曲方平面形式的Ni(II)配合物的电子吸收光谱的详细理论研究。由于其在许多方面的特殊性质,这类配合物已成为许多研究的目标;对它们在DSSCs中使用的相关性进行了研究。采用密度泛函理论(DFT)和时间依赖密度泛函理论(TDDFT)计算了Ni(II)配合物的电子结构和紫外可见光谱,并采用CAM-B3LYP和PBE0杂化泛函进行了研究。此外,前沿分子轨道(FMOs)的分析允许详细分配解释计算光谱性质的电子跃迁。考察了官能团、取代体和溶剂对电子光谱的影响。计算结果表明,几何优化与x射线衍射实验结果吻合较好。理论计算重现了观察到的主要光谱性质以及ecda和dtc配体对吸收光谱的取代效应。实验结果表明,所有配合物在紫外区呈树状吸收带,在可见光区呈极低吸收带。我们把这些能带归为对它们的出现负责的电子跃迁;它们具有以MLCT和LLCT为主的混合特征。
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引用次数: 0
Smart Phone Evapotranspiration-Based App for Optimal Irrigation Scheduling for Thai Crops 基于智能手机蒸散发的应用程序为泰国作物优化灌溉调度
D. Simonet
Thailand is known as a top producer of many essential agricultural commodities including canary seeds, cassava, mango, mangosteen, guava, and chili pepper. Due to global warming and population growth, droughts are increasing and water is becoming scarce, which have a direct impact on agriculture. Farmers are therefore facing difficulties in supplying their crops with sufficient water due to water scarcity and the increasing irrigation cost. This situation calls for optimal use of irrigation water in agriculture, which is sufficient to avoid crop water stress and at the same time help to sustain water and reduce irrigation expenses. Methodolgy/approach: With the number of smartphone users in the world exceeding 3.5 billion, this app uses geospatial data and the Water Balance Approach to estimate the optimal irrigation cycle in the current month in Thailand using Java. Result: This app would result in significant water savings and a less costly irrigation process for both large farms and private gardens in subsistence agriculture. Conclusion: The proposed smartphone app captures the unique characteristics of the weather and soil conditions of any location in Thailand to determine the optimal average daily amount of water required to prevent crop water stress in the current month.
泰国是许多重要农产品的顶级生产国,包括金丝雀种子、木薯、芒果、山竹、番石榴和辣椒。由于全球变暖和人口增长,干旱日益严重,水资源日益匮乏,这对农业产生了直接影响。因此,由于缺水和灌溉成本的增加,农民在为作物提供足够的水方面面临困难。这种情况要求在农业中最佳地利用灌溉水,这足以避免作物缺水,同时有助于维持用水和减少灌溉费用。方法/方法:随着全球智能手机用户数量超过35亿,该应用程序使用地理空间数据和水平衡方法来估计泰国当月使用Java的最佳灌溉周期。结果:这款应用程序将为自给农业中的大型农场和私人花园带来显著的节水和成本更低的灌溉过程。结论:提出的智能手机应用程序捕捉泰国任何地点的天气和土壤条件的独特特征,以确定当月防止作物水分胁迫所需的最佳平均每日水量。
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引用次数: 0
Location Models for Alternative Fuel Stations: A Brief Survey 替代燃料站选址模型:简要综述
M. Karatas
Due to their efficient and sustainable natures, hydrogen fuel cell vehicles are expected to replace traditional gasoline internal combustion engine vehicles in the future. The increasing number of hydrogen fueled vehicles rises the need for installing additional hydrogen fuel storage areas to serve as suppliers for the fuel retail stations in city centers. With this requirement, planners face the problem of locating and sizing hydrogen storage areas. These storage areas are semi-desirable in nature since they pose both social and transportation costs to the nearby communities. In this study, we tackle the location and sizing problem of hydrogen energy storage areas and propose a bi-objective integer linear model. Adopting a goal programming modelling framework, we minimize the total weighted unwanted deviations from each goal, i.e. minimizing transportation cost and social disutility. We demonstrate the performance of our modelling framework on a case study for the Anatolian side of Istanbul, Turkey. We also implement a posteriori approach and determine an efficient frontier to assist decision-makers and investors.
氢燃料电池汽车由于其高效和可持续的特性,有望在未来取代传统的汽油内燃机汽车。随着氢燃料汽车数量的增加,需要安装额外的氢燃料储存区域,作为城市中心燃料零售站的供应商。有了这一要求,规划人员就面临着定位和确定储氢区域大小的问题。这些储存区域在本质上是不太理想的,因为它们给附近的社区带来了社会和运输成本。在本研究中,我们解决了氢气储能区域的选址和规模问题,并提出了一个双目标整数线性模型。采用目标规划建模框架,最小化每个目标的总加权不期望偏差,即最小化运输成本和社会负效用。我们在土耳其伊斯坦布尔的安纳托利亚一侧的案例研究中展示了我们的建模框架的性能。我们还实施了一种后验方法,并确定了一个有效的边界,以帮助决策者和投资者。
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引用次数: 0
Impact strength and behavior of concrete containing different plastic wastes 含不同塑料废料混凝土的冲击强度和性能
Azad A. Mohammed
The growth of post consumed plastic wastes requires recycling to save the environment against pollution. One solution is the reuse of the waste as a substantially material for concrete production. Different properties of concrete containing different plastic wastes have been investigated by the past researchers. In this study, impact strength and behavior of normal strength concrete contained shredded PVC waste aggregate or PET waste fiber has been investigated experimentally. Results show that there is a first crack impact and ultimate impact loads enhancement of 97% and 23% as a result of using 20 mm length PET fiber added to concrete by 0.75%. The impact performance of 40 mm length PET fiber was found to be lower as compared with that of 20 mm length fiber to enhance impact. There is a reduction in both first crack impact and ultimate load impact of concrete as a result of replacing a part of fine aggregate with a PVC waste aggregate reaching 84% related to using 45% PVC aggregate as fine aggregate replacement. Results also show that there is a strong linear relationship between the first crack impact and ultimate load impact for concrete contained PET fiber or PVC aggregate.
消费后的塑料废物的增长需要回收,以保护环境免受污染。一种解决方案是将废物作为混凝土生产的主要材料进行再利用。前人研究了不同塑料废弃物对混凝土性能的影响。试验研究了含碎PVC废骨料和PET废纤维的普通强度混凝土的冲击强度和性能。结果表明:20mm长度PET纤维掺量为0.75%时,混凝土的初裂冲击和极限冲击载荷分别提高97%和23%;40mm长PET纤维的抗冲击性能比20mm长PET纤维的抗冲击性能要低。用PVC废骨料替代部分细骨料达到84%,与用45% PVC骨料替代细骨料有关,降低了混凝土的初裂冲击和极限荷载冲击。结果还表明,含PET纤维或PVC骨料混凝土的首次裂缝冲击与极限荷载冲击之间存在较强的线性关系。
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引用次数: 1
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Proceedings of The 2nd International Academic Conference on Research in Engineering and Technology
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