Pub Date : 2018-10-03DOI: 10.5772/INTECHOPEN.79749
M. Azeez
The use of trees for paper production has contributed to the problem of deforestation with radical negative impact on the environment thereby causing an imbalance in the ecosystem. An increase in the demand and consumption of paper has also induced depletion of woods resources for paper production, thus resulting in limited availability of the raw materials. This work examined the use of non-woody biomasses as alternative raw materials, which are accessible and convertible into pulp and paper of the same quality as those obtained from wood.
{"title":"Pulping of Non-Woody Biomass","authors":"M. Azeez","doi":"10.5772/INTECHOPEN.79749","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.79749","url":null,"abstract":"The use of trees for paper production has contributed to the problem of deforestation with radical negative impact on the environment thereby causing an imbalance in the ecosystem. An increase in the demand and consumption of paper has also induced depletion of woods resources for paper production, thus resulting in limited availability of the raw materials. This work examined the use of non-woody biomasses as alternative raw materials, which are accessible and convertible into pulp and paper of the same quality as those obtained from wood.","PeriodicalId":438556,"journal":{"name":"Pulp and Paper Processing","volume":"3 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134130964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-10-03DOI: 10.5772/INTECHOPEN.79015
Alejandro Rodríguez, E. Espinosa, Juan Domínguez-Robles, R. Sánchez, I. Bascón, A. Rosal
Organosolv pulping is a two-stage process involving hydrolysis (decomposition of wood by use of a catalyst) and removal of lignin with an organic solvent (usually a mixture of alcohol and water). The main disadvantage of using an alcohol is its low boiling point, which requires operating at a high pressure and hence using special equipment that is expensive to purchase and operate. One solution to this problem is using alternative organic solvents that afford operation at pressure levels similar to those of classic pulp ing processes (e.g., the Kraft process). This chapter provides a comprehensive literature review on the organosolv-based production of cellulose pulp by using alternative solvents such as glycols, phenols, esters, organic acids, acetone and amines.
{"title":"Different Solvents for Organosolv Pulping","authors":"Alejandro Rodríguez, E. Espinosa, Juan Domínguez-Robles, R. Sánchez, I. Bascón, A. Rosal","doi":"10.5772/INTECHOPEN.79015","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.79015","url":null,"abstract":"Organosolv pulping is a two-stage process involving hydrolysis (decomposition of wood by use of a catalyst) and removal of lignin with an organic solvent (usually a mixture of alcohol and water). The main disadvantage of using an alcohol is its low boiling point, which requires operating at a high pressure and hence using special equipment that is expensive to purchase and operate. One solution to this problem is using alternative organic solvents that afford operation at pressure levels similar to those of classic pulp ing processes (e.g., the Kraft process). This chapter provides a comprehensive literature review on the organosolv-based production of cellulose pulp by using alternative solvents such as glycols, phenols, esters, organic acids, acetone and amines.","PeriodicalId":438556,"journal":{"name":"Pulp and Paper Processing","volume":"41 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124518734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-10-03DOI: 10.5772/INTECHOPEN.76508
Ahmed Koubaa, Z. Koran
This study investigates alternatives that can improve the internal bond strength (IBS) of paper by pulp refining and paper press-drying (PD). The improvement mechanisms of IBS and their impact on the strength development of high-yield pulps are discussed. All experiments were conducted using a factorial design where the factors were four pulp types (one spruce thermomechanical (TMP) and three chemi-thermomechanical (CTMP) from spruce, birch, and aspen), three refining levels, three PD temperatures and three pressures. The effects of these treatments on the physical and mechanical properties of paper were studied using an analysis of variance. Refining changed the fibre surface, thereby promoting mechanical adhesion. PD temperature softened the fibres and changed their surface chemistry, while PD pressure improved the contact area between fibres. These changes led to an important improvement in IBS which explained, to a large extent, the variations in paper properties. Compared to air-dried paper, PD paper showed much higher properties for most tested pulps at all refining levels. These results were due to the increase in bonded areas. PD at 175°C substantially improved the wet tensile strength of paper due to the flow of lignin on the fibre surface, which protects the hydrogen bonds from moisture.
{"title":"Effect of Press-Drying Parameters on Paper Properties","authors":"Ahmed Koubaa, Z. Koran","doi":"10.5772/INTECHOPEN.76508","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.76508","url":null,"abstract":"This study investigates alternatives that can improve the internal bond strength (IBS) of paper by pulp refining and paper press-drying (PD). The improvement mechanisms of IBS and their impact on the strength development of high-yield pulps are discussed. All experiments were conducted using a factorial design where the factors were four pulp types (one spruce thermomechanical (TMP) and three chemi-thermomechanical (CTMP) from spruce, birch, and aspen), three refining levels, three PD temperatures and three pressures. The effects of these treatments on the physical and mechanical properties of paper were studied using an analysis of variance. Refining changed the fibre surface, thereby promoting mechanical adhesion. PD temperature softened the fibres and changed their surface chemistry, while PD pressure improved the contact area between fibres. These changes led to an important improvement in IBS which explained, to a large extent, the variations in paper properties. Compared to air-dried paper, PD paper showed much higher properties for most tested pulps at all refining levels. These results were due to the increase in bonded areas. PD at 175°C substantially improved the wet tensile strength of paper due to the flow of lignin on the fibre surface, which protects the hydrogen bonds from moisture.","PeriodicalId":438556,"journal":{"name":"Pulp and Paper Processing","volume":"36 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131546490","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-10-03DOI: 10.5772/INTECHOPEN.79014
Guangjun Gou, Wei Wei, Man Jiang, S. Zhang, T. Lu, Xiaoli Xie, F. Meng, Zuowan Zhou
Separation of cellulose from agricultural straw is one of the key bottlenecks hindering the application of such kind of biomass resources. In this chapter, we provide three environmental-friendly ways for separation of cellulose from agricultural straw pretreated with steam explosion, which include delignification with recyclable water-polar aprotic organic solvent, selective bio-degradation of the lignin component, and extraction of cellulose with imidazolium-based ionic liquids from the steam-exploded rice straw. The isolated rice straw celluloses have been adopted as an enhancement for all-cellulose composites (ACCs) and cellulose/cement composites. Ultra-high tensile strength (650.2 MPa) can be achieved for the ACCs containing the activated straw cellulose fiber (A-SCF). The cellulose/cement composites show a significant promotion in the flexural strength and fracture toughness. The new nonderivative solvent for cellulose, tetrabutylammonium hydroxide (TBAH) aqueous solution with urea as additives has been proved to be manipulable for dissolving cellulose.
{"title":"Environmentally Friendly Method for the Separation of Cellulose from Steam-Exploded Rice Straw and Its High-Value Applications","authors":"Guangjun Gou, Wei Wei, Man Jiang, S. Zhang, T. Lu, Xiaoli Xie, F. Meng, Zuowan Zhou","doi":"10.5772/INTECHOPEN.79014","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.79014","url":null,"abstract":"Separation of cellulose from agricultural straw is one of the key bottlenecks hindering the application of such kind of biomass resources. In this chapter, we provide three environmental-friendly ways for separation of cellulose from agricultural straw pretreated with steam explosion, which include delignification with recyclable water-polar aprotic organic solvent, selective bio-degradation of the lignin component, and extraction of cellulose with imidazolium-based ionic liquids from the steam-exploded rice straw. The isolated rice straw celluloses have been adopted as an enhancement for all-cellulose composites (ACCs) and cellulose/cement composites. Ultra-high tensile strength (650.2 MPa) can be achieved for the ACCs containing the activated straw cellulose fiber (A-SCF). The cellulose/cement composites show a significant promotion in the flexural strength and fracture toughness. The new nonderivative solvent for cellulose, tetrabutylammonium hydroxide (TBAH) aqueous solution with urea as additives has been proved to be manipulable for dissolving cellulose.","PeriodicalId":438556,"journal":{"name":"Pulp and Paper Processing","volume":"56 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128141396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-10-03DOI: 10.5772/INTECHOPEN.80044
L. Wanat, E. Mikołajczak, J. Chudobiecki
Analyzing the relationship between production of wood-based products and the pro- duction of paper and its derivatives ever more often attention is paid to complementar-ity of the processes of production, recovery and recycling of key raw materials and finally to their value and profitability of production. In this context, two main trends in converting wood by-products are noticed: paper production and energy generation. Development of market of sawmill by-products constitutes a challenge for wood industry, which requires determination of the most efficient means of utilizing those by- products. One of the crucial criteria of making business decisions is the value of wood by-products. A method of valuation of those sawmill by-products when converted into briquettes, pellet, or energy was presented. This method allows for multilateral analysis of profitability of various means of utilizing wooden by-products, on the example of Poland. Based on comparative analysis, recommendations for wood-based industry were formulated.
{"title":"The Value and Profitability of Converting Sawmill Wood By- Products to Paper Production and Energy Generation: The Case of Poland","authors":"L. Wanat, E. Mikołajczak, J. Chudobiecki","doi":"10.5772/INTECHOPEN.80044","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.80044","url":null,"abstract":"Analyzing the relationship between production of wood-based products and the pro- duction of paper and its derivatives ever more often attention is paid to complementar-ity of the processes of production, recovery and recycling of key raw materials and finally to their value and profitability of production. In this context, two main trends in converting wood by-products are noticed: paper production and energy generation. Development of market of sawmill by-products constitutes a challenge for wood industry, which requires determination of the most efficient means of utilizing those by- products. One of the crucial criteria of making business decisions is the value of wood by-products. A method of valuation of those sawmill by-products when converted into briquettes, pellet, or energy was presented. This method allows for multilateral analysis of profitability of various means of utilizing wooden by-products, on the example of Poland. Based on comparative analysis, recommendations for wood-based industry were formulated.","PeriodicalId":438556,"journal":{"name":"Pulp and Paper Processing","volume":"55 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127737053","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-10-03DOI: 10.5772/INTECHOPEN.79017
Zhong Liu, Huimei Wang, Lanfeng Hui
In general, the main raw materials of pulp and papermaking industry can be classified into three categories: wood, non-wood, and non-plant (mainly wastepaper), of which non-wood fiber material is an important fiber source in the areas where forest resources are scarce. Nowadays, in the total pulp consumption of the world, the proportions of wood pulp, wastepaper pulp, and non-wood pulp are 63, 34, and 3%, respectively. The effective use of non-wood fiber resources, especially grasses, cereal straws, corn stalks, bamboo, and bagasse, would play a major role in optimizing papermaking raw materials. On the other hand, there are non-wood fibers such as flax, hemp, jute, kenaf, cotton, sisal, and abaca with properties as good as or much better than softwood materials.
{"title":"Pulping and Papermaking of Non-Wood Fibers","authors":"Zhong Liu, Huimei Wang, Lanfeng Hui","doi":"10.5772/INTECHOPEN.79017","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.79017","url":null,"abstract":"In general, the main raw materials of pulp and papermaking industry can be classified into three categories: wood, non-wood, and non-plant (mainly wastepaper), of which non-wood fiber material is an important fiber source in the areas where forest resources are scarce. Nowadays, in the total pulp consumption of the world, the proportions of wood pulp, wastepaper pulp, and non-wood pulp are 63, 34, and 3%, respectively. The effective use of non-wood fiber resources, especially grasses, cereal straws, corn stalks, bamboo, and bagasse, would play a major role in optimizing papermaking raw materials. On the other hand, there are non-wood fibers such as flax, hemp, jute, kenaf, cotton, sisal, and abaca with properties as good as or much better than softwood materials.","PeriodicalId":438556,"journal":{"name":"Pulp and Paper Processing","volume":"83 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123245988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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