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Multilayer laminated Cu coil/CaO–Li2O–B2O3–SiO2 glass-ceramic preparation via a novel insulation packaging strategy for flat wire motor applications 通过新型绝缘封装策略制备多层叠层铜线圈/CaO-Li2O-B2O3-SiO2 玻璃陶瓷,用于扁线电机应用
Pub Date : 2024-03-16 DOI: 10.1016/j.nanoms.2024.02.002
Haitao Zhu, Yanyu Song, Guangyou Pan, Naibin Chen, Xiaoguo Song, Long Xia, Duo Liu, Shengpeng Hu
A new insulation packaging strategy for the stator windings of flat wire motors based on LTCC technology was studied for the first time. The study aimed to replace traditional plastic packaging methods and avoid aging issues by fabricating a novel multilayer laminated Cu coil/CaO–LiO–BO–SiO glass-ceramic structure. The analysis of the interface microstructure of the laminated structure revealed that the CaO–LiO–BO–SiO glass-ceramic matrix consisted of a crystalline phase of CaSiO and an amorphous phase of SiO. The interface between the Cu coil and CaO–LiO–BO–SiO glass-ceramic exhibited good bonding with no formation of secondary phases. Additionally, the strong bonding between the Cu coil and CaO–LiO–BO–SiO glass-ceramic was attributed to the diffusion of Cu atoms at the interface. The novel multilayer laminated structure based on LTCC technology proposed in this study can help achieve high-reliability insulation packaging for the stator windings of future high-power density and miniaturized flat wire motors.
首次研究了基于 LTCC 技术的扁线电机定子绕组新型绝缘封装策略。该研究旨在通过制造一种新型多层层叠铜线圈/CaO-LiO-BO-SiO 玻璃陶瓷结构,取代传统的塑料封装方法并避免老化问题。对层压结构界面微观结构的分析表明,CaO-LiO-BO-SiO 玻璃陶瓷基体由 CaSiO 结晶相和 SiO 非晶相组成。铜线圈和 CaO-LiO-BO-SiO 玻璃陶瓷之间的界面结合良好,没有形成次生相。此外,Cu 线圈与 CaO-LiO-BO-SiO 玻璃陶瓷之间的牢固粘结还归因于界面上 Cu 原子的扩散。本研究提出的基于 LTCC 技术的新型多层层压结构有助于实现未来高功率密度和微型扁线电机定子绕组的高可靠性绝缘封装。
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引用次数: 0
Impact of functional groups in spacer cations on the properties of PEA-based 2D monolayer halide perovskites 间隔阳离子中的官能团对基于 PEA 的二维单层卤化物包晶特性的影响
Pub Date : 2024-03-16 DOI: 10.1016/j.nanoms.2024.02.005
Chenchen Li, Xian Chen, Tan Jin, Tianmin Wu, Jun Chen, Wei Zhuang
Incorporating low-dimensionalization technologies effectively tackle the challenge of inadequate long-term stability in hybrid halide perovskites, however their wide bandgap and strong quantum well confinement remain substantial obstacle for various optoelectronic applications. Addressing these issues without compromising long-term stability has emerged as a pivotal focus in materials science, in particular exploring the effects of the functional groups within spacer cations. Our simulations reveal that the robust π-π stacking interactions involving PEA and the strong hydrogen bonding interactions between PEA and MX contribute to narrowing the electronic bandgap in 2D monolayer PEAMX (e. g. 2D monolayer PEASnI: 1.34 ​eV) for reasonable visible-light absorption while simultaneously ensuring their favorable long-term stability. Moreover, the delocalized orbitals and relatively high dielectric constants in PEA, attributed to the conjugated benzene ring, has been observed to weaken the potential barrier, exciton binding effect and quantum well confinement in 2D monolayer PEAMX, thus facilitating photogenerated electron-hole separations and out-of-plane carrier transport. The impact of spacer cations on the optoelectronic and transport properties of 2D monolayer perovskites highlights the critical role of meticulously chosen and well-designed spacer cations, especially functional groups, in shaping their photophysical properties and ensuring long-term stability even under extremely operating conditions.
采用低维化技术可以有效地解决混合卤化物包晶石长期稳定性不足的难题,但其宽带隙和强量子阱约束仍然是各种光电应用的巨大障碍。在不影响长期稳定性的前提下解决这些问题已成为材料科学领域的一个重要焦点,特别是探索间隔阳离子内官能团的影响。我们的模拟揭示了 PEA 强大的 π-π 堆叠相互作用以及 PEA 和 MX 之间强大的氢键相互作用有助于缩小二维单层 PEAMX 的电子带隙(例如二维单层 PEASnI:1.34 eV),从而实现合理的可见光吸收,同时确保其良好的长期稳定性。此外,由于共轭苯环的存在,PEA 中的分散轨道和相对较高的介电常数被观察到可以削弱二维单层 PEAMX 中的势垒、激子结合效应和量子阱约束,从而促进光生电子-空穴分离和平面外载流子传输。间隔阳离子对二维单层包晶的光电和传输特性的影响凸显了精心选择和设计的间隔阳离子(尤其是官能团)在塑造其光物理性质和确保其在极端工作条件下的长期稳定性方面的关键作用。
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引用次数: 0
Nanoarchitectonics of point-of-care diagnostics for sweat biomarkers analysis 用于汗液生物标记分析的床旁诊断纳米架构
Pub Date : 2024-03-16 DOI: 10.1016/j.nanoms.2024.01.010
Xuan Lin, Arya Vasanth, Aditya Ashok, Hoang-Phuong Phan, Kevin M. Koo, Mohammed A. Amin, Yusuf Valentino Kaneti, Carlos Salomon, Md Shahriar A. Hossain, Yusuke Yamauchi, Mostafa Kamal Masud
Sweat contains numerous vital biomarkers such as metabolites, electrolytes, proteins, nucleic acids and antigens that reflect hydration status, exhaustion, nutrition, and physiological changes. Conventional healthcare diagnosis relies on disease diagnostics in sophisticated centralized laboratories with invasive sample collection (e.g., chemical analyses, plasma separation centrifugation, tissue biopsy, etc.). Cutting-edge point-of-care diagnostics for sweat biomarker analysis allow for non-invasive monitoring of physiologically related biomarkers in sweat and real-time health status tracking. Moreover, using advanced nanoarchitectures, including nanostructured platforms and nanoparticles, can enhance the specificity, sensitivity, wearability and widen the sensing modality of sweat biosensors. Herein, we comprehensively review the secretory mechanisms, clinical uses of sweat biomarkers, and the design, principle, and latest technologies of sweat biosensors. With an emphasis on cutting-edge technologies for sweat biomarker analysis, this review chronicles the issues associated with the current sweat biomarkers analysis of sweat biomarkers and provides insights into strategies for enhancing the translation of such biosensors into routine clinical practice.
汗液中含有大量重要的生物标记物,如代谢物、电解质、蛋白质、核酸和抗原,可反映水合状态、疲惫程度、营养状况和生理变化。传统的医疗诊断依赖于在精密的中央实验室进行疾病诊断,并采集侵入性样本(如化学分析、血浆分离离心、组织活检等)。用于汗液生物标志物分析的尖端床旁诊断技术可对汗液中与生理相关的生物标志物进行无创监测,并实时跟踪健康状况。此外,利用先进的纳米结构,包括纳米结构平台和纳米颗粒,可以提高汗液生物传感器的特异性、灵敏度、耐磨性并拓宽传感模式。在此,我们全面综述了汗液生物标记物的分泌机制、临床用途以及汗液生物传感器的设计、原理和最新技术。这篇综述以汗液生物标志物分析的前沿技术为重点,记录了当前汗液生物标志物分析中的相关问题,并对加强此类生物传感器转化为常规临床实践的策略提出了见解。
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引用次数: 0
Ag anchored mesoporous carbon hollow sphere in Cellulose nanofibers/MXene composite films for high-performance electromagnetic interference shielding 用于高性能电磁干扰屏蔽的纤维素纳米纤维/MXene 复合薄膜中的银锚介孔碳空心球
Pub Date : 2024-03-16 DOI: 10.1016/j.nanoms.2024.02.001
Wenting Tao, Wenqin Shao, Meng Ma, Si Chen, Yanqin Shi, Huiwen He, Yulu Zhu, Xu Wang
The increasingly serious electromagnetic (EM) radiation and related pollution effects have gradually attracted people's attention in the information age. Hence, it's crucial to develop adaptive shielding materials with minimum EM waves (EMW) reflection. In this paper, Ag nanoparticles loaded mesoporous carbon hollow spheres (MCHS@Ag) were synthesized by chemical reduction method, and cellulose nanofibers (CNF)/MXene/MCHS@Ag homogeneous composites were prepared. The total EM interference shielding efficiency (SE) of CNF/MXene/MCHS@Ag composite film was 32.83 ​dB (at 12.4 ​GHz), and the absorption effectiveness (SE) was improved to 26.6 ​dB, which was 63.1% and 195.5% higher than that of CNF/MXene/MCHS composite film. The low dielectric property of MCHS effectively optimized the impedance matching between the composites and air. The hollow porous structure prolonged the transmission path of EMW and increased the absorption loss of the composites. At the same time, Ag nanoparticles located the MCHS were helpful to construct the internal conductive path overcoming the damage of the conductive property caused by the low dielectric of MCHS. This research adopts a straightforward method to construct a lightweight, pliable, and mesoporous composites for EMI shielding, which serves a crucial role in the current era of severe EM pollution.
在信息时代,日益严重的电磁辐射及相关污染效应已逐渐引起人们的关注。因此,开发电磁波(EMW)反射最小的自适应屏蔽材料至关重要。本文采用化学还原法合成了负载Ag纳米颗粒的介孔碳空心球(MCHS@Ag),并制备了纤维素纳米纤维(CNF)/MXene/MCHS@Ag均相复合材料。CNF/MXene/MCHS@Ag复合膜的电磁干扰总屏蔽效率(SE)为32.83 dB(12.4 GHz时),吸收效率(SE)提高到26.6 dB,分别比CNF/MXene/MCHS复合膜提高了63.1%和195.5%。MCHS 的低介电性能有效优化了复合材料与空气之间的阻抗匹配。中空多孔结构延长了电磁波的传输路径,增加了复合材料的吸收损耗。同时,位于 MCHS 中的 Ag 纳米粒子有助于构建内部导电路径,克服了 MCHS 低介电特性对导电性能的破坏。该研究采用一种简单的方法构建了一种轻质、柔韧的介孔复合材料,用于电磁干扰屏蔽,在当前电磁污染严重的时代发挥了重要作用。
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引用次数: 0
2D SnSe2 micro-flower decorated with 0D In2O3 nanoparticles for low-temperature low-concentration TEA detection 用 0D In2O3 纳米粒子装饰的二维 SnSe2 微花,用于低温低浓度三乙醇胺检测
Pub Date : 2024-03-07 DOI: 10.1016/j.nanoms.2024.02.010
Li Wang, Jianpeng Li, Cheng Xu, Ziqin Yang, Xiangyun Tan, Zhihu Dong, Li Xu, Dongwei Zhang, Chunqing He
Triethylamine, a crucial industrial raw material, poses significant threats to both the ecosystem and human health. However, detecting lower concentrations of TEA remains an arduous task. In this study, we report the facile hydrothermal and ultrasonic treatment synthesis of 2D SnSe micro-flower modified with 0D InO nanoparticles to form SnSe/InO heterojunctions for the first time. The SnSe/InO sensor has a response value of 4.86 for 10 ​ppm TEA gas at 120 ​°C, with response and recovery times of 18 ​s and 79 ​s respectively, and detection limits as low as 100 ​ppb. In addition, the SnSe/InO sensor is essentially unaffected by humidity in the 30% RH to 60% RH range, and the SnSe/InO sensor response value decreases slightly in the 70% RH to 97% RH range, demonstrating excellent humidity tolerance. More importantly, the sensor maintained excellent cyclic-stability performance during a four-month cyclic stability test. The improved gas-sensitive performance can be attributed to the large number of n-n heterojunctions in the SnSe/InO material, which enhances the interfacial charge transfer, as well as the active-sites on the material surface. This work serves as a valuable complement to the TEA gas sensor and holds significant potential for detecting low concentrations of TEA at low temperatures in environmental sensing applications.
三乙胺是一种重要的工业原料,对生态系统和人类健康都构成重大威胁。然而,检测较低浓度的三乙胺仍然是一项艰巨的任务。在这项研究中,我们首次报道了用 0D InO 纳米粒子修饰二维 SnSe 微花,形成 SnSe/InO 异质结的简便水热和超声处理合成方法。SnSe/InO 传感器在 120 °C 下对 10 ppm 三乙醇胺气体的响应值为 4.86,响应时间和恢复时间分别为 18 秒和 79 秒,检测限低至 100 ppb。此外,在 30% 相对湿度至 60% 相对湿度范围内,SnSe/InO 传感器基本上不受湿度的影响,而在 70% 相对湿度至 97% 相对湿度范围内,SnSe/InO 传感器的响应值会略有下降,这表明该传感器具有出色的耐湿性。更重要的是,该传感器在为期四个月的循环稳定性测试中保持了出色的循环稳定性能。气敏性能的提高可归因于 SnSe/InO 材料中大量的 n-n 异质结增强了界面电荷转移,以及材料表面的活性位点。这项工作是对三乙醇胺气体传感器的重要补充,在环境传感应用中低温检测低浓度三乙醇胺方面具有巨大潜力。
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引用次数: 0
Recent advances in self-lubricating metal matrix nanocomposites reinforced by carbonous materials: A review 碳材料增强的自润滑金属基纳米复合材料的最新进展:综述
Pub Date : 2024-03-01 DOI: 10.1016/j.nanoms.2024.02.007
Wenting Ye, Yeran Shi, Qing Zhou, Mingda Xie, Haifeng Wang, Benyebka Bou-Saïd, Weimin Liu
Metal matrix self-lubricating materials lie at the core of cutting-edge aerospace, mechanical, and electrical industries, which demand technological performances that cannot be met by traditional liquid lubricants. Rapid innovation in nanocarbon materials in recent years enabled rapid development of advanced nanocomposites for applications in structural engineering and functional devices. Carbonous materials (e.g., graphite, graphene and carbon nanotubes), exhibit a wide range of unique electrical, mechanical, and thermal properties, which are also considered ideal lubricating reinforcements for metal matrix nanocomposites (MMCs) with superior mechanical and tribological properties. In this review, we first showcase the distinctive features of the constituents commonly employed in self-lubricating MMCs, encompassing the high-strength metallic matrix and nano-carbonous reinforcement. Then, we present a comprehensive overview of the recent advancements in preparation techniques for these advanced MMCs, followed by an in-depth discussion on their corresponding tribological properties and wear mechanisms. We close this review by outlining key problems to be solved and the future trend of the development in self-lubricating MMCs.
金属基自润滑材料是尖端航空航天、机械和电气工业的核心,其技术性能要求是传统液体润滑剂无法满足的。近年来,纳米碳材料的快速创新使得应用于结构工程和功能设备的先进纳米复合材料得以迅速发展。碳材料(如石墨、石墨烯和碳纳米管)具有多种独特的电学、机械和热学特性,被认为是金属基纳米复合材料(MMC)的理想润滑增强材料,具有优异的机械和摩擦学特性。在这篇综述中,我们首先展示了自润滑 MMC 中常用成分的显著特点,包括高强度金属基体和纳米碳增强材料。然后,我们全面概述了这些先进 MMC 制备技术的最新进展,并深入探讨了其相应的摩擦学特性和磨损机理。最后,我们概述了自润滑 MMC 需要解决的关键问题和未来的发展趋势。
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引用次数: 0
Construction of 3D aerogels consisting of cellulose and BNNSs bridged by AgNPs for enhancing thermal and tribological properties of polyurethane composites 用 AgNPs 桥接纤维素和 BNNSs 构建三维气凝胶,提高聚氨酯复合材料的热性能和摩擦学性能
Pub Date : 2024-02-26 DOI: 10.1016/j.nanoms.2024.02.004
Yu He, Yuanya Zhang, Yongjun Zhou, Junya Yuan, Xuehu Men
Waterborne polyurethane (WPU) is attracting widespread attention in the friction field, but pure WPU cannot meet the wear resistance requirements due to poor thermal and self-lubricating properties. Herein, a novel cellulose/BNNSs-AgNPs aerogel (CBAg) composed of zero-dimensional silver nanoparticles (AgNPs), one-dimensional cellulose and two-dimensional boron nitride nanosheets (BNNSs) was successfully fabricated. Specifically, AgNPs were loaded onto the surface of BNNSs, which could serve as bridges to connect adjacent BNNSs. Cellulose was used to construct a 3D skeleton structure for stabilizing better dispersion of inorganic fillers. Finally, the thermal and tribological properties of CBAg-WPU were improved compared to pure WPU, with a 69% increase in thermal conductivity and an 89% reduction in wear rate. This was attributed to the load-bearing capacity of cellulose and outstanding thermal and lubricant capability of BNNSs-AgNPs. In addition, BNNSs and AgNPs inside the aerogel were transferred to the sliding interface and participated in the formation of high-quality friction transfer film, further endowing CBAg-WPU composites prominent tribological performance. Therefore, the novel design of 3D hybrid aerogels provided a promising avenue to improve the tribological performance of WPU composites.
水性聚氨酯(WPU)在摩擦领域受到广泛关注,但由于热性能和自润滑性能较差,纯 WPU 无法满足耐磨性要求。本文成功制备了一种新型纤维素/BNNSs-AgNPs 气凝胶(CBAg),该气凝胶由零维银纳米粒子(AgNPs)、一维纤维素和二维氮化硼纳米片(BNNSs)组成。具体来说,AgNPs 被负载到 BNNSs 表面,可作为连接相邻 BNNSs 的桥梁。纤维素被用来构建三维骨架结构,以更好地稳定无机填料的分散。最后,与纯 WPU 相比,CBAg-WPU 的热性能和摩擦学性能得到了改善,热导率提高了 69%,磨损率降低了 89%。这归功于纤维素的承载能力和 BNNSs-AgNPs 出色的导热和润滑能力。此外,气凝胶中的 BNNSs 和 AgNPs 被转移到滑动界面,参与形成了高质量的摩擦传递膜,进一步赋予了 CBAg-WPU 复合材料突出的摩擦学性能。因此,三维混合气凝胶的新颖设计为改善WPU复合材料的摩擦学性能提供了一条很有前景的途径。
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引用次数: 0
Beyond contribution of ionic liquids in nanostructuring polyaniline morphology; its effect on the properties of the polymerization medium 离子液体在纳米聚苯胺形态结构中的作用及其对聚合介质性质的影响
Pub Date : 2024-02-20 DOI: 10.1016/j.nanoms.2023.12.001
Fatima Al-Zohbi, Fouad Ghamouss, Bruno Schmaltz, Mohamed Abarbri, Khalil Cherry, Mohamad fadel Tabcheh, François Tran-Van
{"title":"Beyond contribution of ionic liquids in nanostructuring polyaniline morphology; its effect on the properties of the polymerization medium","authors":"Fatima Al-Zohbi, Fouad Ghamouss, Bruno Schmaltz, Mohamed Abarbri, Khalil Cherry, Mohamad fadel Tabcheh, François Tran-Van","doi":"10.1016/j.nanoms.2023.12.001","DOIUrl":"https://doi.org/10.1016/j.nanoms.2023.12.001","url":null,"abstract":"","PeriodicalId":501090,"journal":{"name":"Nano Materials Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139927587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-performance self-driven broadband photoelectrochemical photodetector based on reduced graphene oxide/Bi2Te3 heterojunction 基于还原氧化石墨烯/Bi2Te3 异质结的高性能自驱动宽带光电化学光电探测器
Pub Date : 2024-02-20 DOI: 10.1016/j.nanoms.2023.12.008
Chenchen Zhao, Yangyang Liu, Dongbo Wang, Wen He, Bingke Zhang, Jingwen Pan, Zhi Zeng, Donghao Liu, Sihang Liu, Shujie Jiao, Xuan Fang, Dan Fang, Liancheng Zhao, Jinzhong Wang
{"title":"High-performance self-driven broadband photoelectrochemical photodetector based on reduced graphene oxide/Bi2Te3 heterojunction","authors":"Chenchen Zhao, Yangyang Liu, Dongbo Wang, Wen He, Bingke Zhang, Jingwen Pan, Zhi Zeng, Donghao Liu, Sihang Liu, Shujie Jiao, Xuan Fang, Dan Fang, Liancheng Zhao, Jinzhong Wang","doi":"10.1016/j.nanoms.2023.12.008","DOIUrl":"https://doi.org/10.1016/j.nanoms.2023.12.008","url":null,"abstract":"","PeriodicalId":501090,"journal":{"name":"Nano Materials Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139927601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The microstructural evolution and relaxation strengthening for nano-grained Ni upon low-temperature annealing 纳米晶粒镍低温退火后的微观结构演变和弛豫强化
Pub Date : 2024-02-19 DOI: 10.1016/j.nanoms.2023.12.007
Ze Chai, Bo Peng, Xukai Ren, Kaiyuan Hong, Xiaoqi Chen
{"title":"The microstructural evolution and relaxation strengthening for nano-grained Ni upon low-temperature annealing","authors":"Ze Chai, Bo Peng, Xukai Ren, Kaiyuan Hong, Xiaoqi Chen","doi":"10.1016/j.nanoms.2023.12.007","DOIUrl":"https://doi.org/10.1016/j.nanoms.2023.12.007","url":null,"abstract":"","PeriodicalId":501090,"journal":{"name":"Nano Materials Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139927599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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