The exceptional gold mineralisation in quartz pebble conglomerates of the Witwatersrand Basin is attributed to a combination of factors. These factors are linked to the co-evolution of the atmosphere, hydrosphere, lithosphere and biosphere, at a very specific time in Archaean geological history and the evolution of the Kaapvaal Craton. Following craton stabilisation and its subaerial emergence, intense chemical weathering and erosion of large volumes of granitoid-greenstone basement released detrital and dissolved gold. Shallow-marine reworking in a long-lived and slowly subsiding basin subjected to episodic compressional deformation and relative sea-level oscillations led to sedimentary concentration of detrital gold. The interaction between acidic, anoxic, and sulfurous surface runoff and more oxidizing marine waters in a near-coastal oxygen oasis supported microbially mediated diagenetic pyrite formation and incorporation of dissolved gold in the pyrite crystal lattice. Erosion and reworking of diagenetic pyrite gave rise to detrital pyrite that characterise most reefs. Abundance of detrital uraninite in conglomerates, derived from erosion of Mesoarchaean granites, and episodes of hydrocarbon migration through sedimentary strata during deep burial set the scene for further enhancement of gold grades in the reefs. Granular and seam pyro-bitumen formed by radiation-induced polymerisation of hydrocarbons around detrital uraninite. Gold dissolved in migrating hydrothermal fluids was then reduced and precipitated upon interaction with the reef pyro-bitumen during hydrothermal placer modification.
{"title":"Factors responsible for Witwatersrand gold mineralisation","authors":"A. Hofmann","doi":"10.25131/sajg.127.0023","DOIUrl":"https://doi.org/10.25131/sajg.127.0023","url":null,"abstract":"\u0000 The exceptional gold mineralisation in quartz pebble conglomerates of the Witwatersrand Basin is attributed to a combination of factors. These factors are linked to the co-evolution of the atmosphere, hydrosphere, lithosphere and biosphere, at a very specific time in Archaean geological history and the evolution of the Kaapvaal Craton. Following craton stabilisation and its subaerial emergence, intense chemical weathering and erosion of large volumes of granitoid-greenstone basement released detrital and dissolved gold. Shallow-marine reworking in a long-lived and slowly subsiding basin subjected to episodic compressional deformation and relative sea-level oscillations led to sedimentary concentration of detrital gold. The interaction between acidic, anoxic, and sulfurous surface runoff and more oxidizing marine waters in a near-coastal oxygen oasis supported microbially mediated diagenetic pyrite formation and incorporation of dissolved gold in the pyrite crystal lattice. Erosion and reworking of diagenetic pyrite gave rise to detrital pyrite that characterise most reefs. Abundance of detrital uraninite in conglomerates, derived from erosion of Mesoarchaean granites, and episodes of hydrocarbon migration through sedimentary strata during deep burial set the scene for further enhancement of gold grades in the reefs. Granular and seam pyro-bitumen formed by radiation-induced polymerisation of hydrocarbons around detrital uraninite. Gold dissolved in migrating hydrothermal fluids was then reduced and precipitated upon interaction with the reef pyro-bitumen during hydrothermal placer modification.","PeriodicalId":504199,"journal":{"name":"South African Journal of Geology","volume":" 10","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140994378","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D.E. Paprika, A. Agangi, A. Hofmann, P. Ringdahl, S. Hartmann, J. Déri-Takács
The ca. 2.96 Ga Dominion Group (DG) preserves the first subaerial volcano-sedimentary succession on the Kaapvaal Craton. Based on field and core observations, this study provides revised stratigraphic logs and geological maps from the area around Ottosdal that refine the understanding of the stratigraphic and tectonic evolution of these ancient rocks. Fluvial sandstone and conglomerate of the Rhenosterspruit Formation (RsF) were deposited on granite basement, followed by andesitic to basaltic volcanic rocks of the Rhenosterhoek Formation (RhF). These amygdaloidal andesitic to basaltic lava units show fragmentation around lava flows that may represent an indication of prevalent subaerial environment. However, local hyaloclastite and pillow lava units indicate periodic aqueous conditions. The Syferfontein Formation (SF) has the most extensive exposures in the Ottosdal area and represents the youngest volcanic unit of the DG. The porphyritic and spherulitic volcanic rocks tell a story of subaerial volcanism interspersed with periods of lacustrine deposition of sandstone and shale. The Witwatersrand Supergroup (WSG) overlies the DG along an angular unconformity. Folding affected the succession of the DG, WSG and the Ventersdorp Supergroup (Rietgat Formation). This event is reflected in small-scale folds and mullion structures in the central part of the study area and by larger scale north-northwest–south-southeast-striking anticlines and synclines. Folding was accompanied by northwest-southeast-striking thrust faulting, either during or shortly after the formation of the Ventersdorp Supergroup. In the study area, post-Ventersdorp deformation is restricted to east-northeast–west-southwest-striking faults.
{"title":"New details on the volcanic and tectonic evolution of the Mesoarchaean Dominion Group with special reference to the Syferfontein Formation in the Ottosdal area (South Africa)","authors":"D.E. Paprika, A. Agangi, A. Hofmann, P. Ringdahl, S. Hartmann, J. Déri-Takács","doi":"10.25131/sajg.127.0003","DOIUrl":"https://doi.org/10.25131/sajg.127.0003","url":null,"abstract":"\u0000 The ca. 2.96 Ga Dominion Group (DG) preserves the first subaerial volcano-sedimentary succession on the Kaapvaal Craton. Based on field and core observations, this study provides revised stratigraphic logs and geological maps from the area around Ottosdal that refine the understanding of the stratigraphic and tectonic evolution of these ancient rocks.\u0000 Fluvial sandstone and conglomerate of the Rhenosterspruit Formation (RsF) were deposited on granite basement, followed by andesitic to basaltic volcanic rocks of the Rhenosterhoek Formation (RhF). These amygdaloidal andesitic to basaltic lava units show fragmentation around lava flows that may represent an indication of prevalent subaerial environment. However, local hyaloclastite and pillow lava units indicate periodic aqueous conditions. The Syferfontein Formation (SF) has the most extensive exposures in the Ottosdal area and represents the youngest volcanic unit of the DG. The porphyritic and spherulitic volcanic rocks tell a story of subaerial volcanism interspersed with periods of lacustrine deposition of sandstone and shale. The Witwatersrand Supergroup (WSG) overlies the DG along an angular unconformity.\u0000 Folding affected the succession of the DG, WSG and the Ventersdorp Supergroup (Rietgat Formation). This event is reflected in small-scale folds and mullion structures in the central part of the study area and by larger scale north-northwest–south-southeast-striking anticlines and synclines. Folding was accompanied by northwest-southeast-striking thrust faulting, either during or shortly after the formation of the Ventersdorp Supergroup. In the study area, post-Ventersdorp deformation is restricted to east-northeast–west-southwest-striking faults.","PeriodicalId":504199,"journal":{"name":"South African Journal of Geology","volume":"2 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140710651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
T. Andersen, M. Elburg, M. Kristoffersen, M. de Kock
The Palaeoproterozoic sandstones and quartzites of the Pretoria Group (Transvaal Supergroup) in the Transvaal Basin of South Africa are important markers for regional correlations and dating of events of global importance (e.g., the Great Oxidation Event). The succession has few independent age markers, and much of the discussion about the time of deposition and the source of material of these rocks has been based on data from detrital zircon suites. The clastic sedimentary rocks of the Pretoria Group contain detrital zircon grains ranging from the Mesoarchaean to ages that are near-contemporaneous to, and even younger than the overlying and crosscutting igneous rocks of the Bushveld Complex. We show that the U-Pb age and Lu-Hf isotope distributions of the detrital zircon population in the Pretoria Group are the result of three different types of processes, acting successively: (1) Crystallisation in the igneous or metamorphic protosource rock (i.e., the rock where the zircon originally crystallised), (2) Metamorphic and hydrothermal resetting of the U-Pb chronometer induced by emplacement and crystallisation of the 2 055 Ma Bushveld Complex, and (3) Late, low-temperature processes (e.g., weathering). Critical age markers of maximum ages of deposition obtained after excluding effects of (2) and (3) are the 2 200 Ma Magaliesberg Formation (outside of the Bushveld aureole) and the 2 080 to 2 100 Ma Lakenvalei Formation. The Leeuwpoort Formation is a worst-case example, containing both young (<2 200 Ma) unmodified detrital zircon and hydrothermally altered zircon in the same age range. The two can only be distinguished from trace element analyses. Age distributions of Archaean and early Palaeoproterozoic zircon age fractions overlap with detrital zircon age suites in lower (i.e., pre-Timeball Hill Formation) parts of the Transvaal Supergroup, suggesting recycling within the basin or from the basin margin. Overlaps in 2 200 to 2 350 Ma zircon ages with those of volcanogenic zircon in the Timeball Hill Formation again suggest recycling. The origin of 2 080 to 2 150 Ma zircon is uncertain, but neither poorly constrained sources in the Kaapvaal Craton (e.g., Okwa Basement Complex) nor recycling of volcanogenic material from post-Magaliesberg formations can be ruled out.
{"title":"Retrieving meaningful information from detrital zircon in Palaeoproterozoic sedimentary rocks: Provenance, timing of deposition, metamorphism and alteration of zircon in sandstones of the Pretoria Group in the Transvaal Basin, South Africa","authors":"T. Andersen, M. Elburg, M. Kristoffersen, M. de Kock","doi":"10.25131/sajg.127.0012","DOIUrl":"https://doi.org/10.25131/sajg.127.0012","url":null,"abstract":"\u0000 The Palaeoproterozoic sandstones and quartzites of the Pretoria Group (Transvaal Supergroup) in the Transvaal Basin of South Africa are important markers for regional correlations and dating of events of global importance (e.g., the Great Oxidation Event). The succession has few independent age markers, and much of the discussion about the time of deposition and the source of material of these rocks has been based on data from detrital zircon suites.\u0000 The clastic sedimentary rocks of the Pretoria Group contain detrital zircon grains ranging from the Mesoarchaean to ages that are near-contemporaneous to, and even younger than the overlying and crosscutting igneous rocks of the Bushveld Complex. We show that the U-Pb age and Lu-Hf isotope distributions of the detrital zircon population in the Pretoria Group are the result of three different types of processes, acting successively: (1) Crystallisation in the igneous or metamorphic protosource rock (i.e., the rock where the zircon originally crystallised), (2) Metamorphic and hydrothermal resetting of the U-Pb chronometer induced by emplacement and crystallisation of the 2 055 Ma Bushveld Complex, and (3) Late, low-temperature processes (e.g., weathering).\u0000 Critical age markers of maximum ages of deposition obtained after excluding effects of (2) and (3) are the 2 200 Ma Magaliesberg Formation (outside of the Bushveld aureole) and the 2 080 to 2 100 Ma Lakenvalei Formation. The Leeuwpoort Formation is a worst-case example, containing both young (<2 200 Ma) unmodified detrital zircon and hydrothermally altered zircon in the same age range. The two can only be distinguished from trace element analyses.\u0000 Age distributions of Archaean and early Palaeoproterozoic zircon age fractions overlap with detrital zircon age suites in lower (i.e., pre-Timeball Hill Formation) parts of the Transvaal Supergroup, suggesting recycling within the basin or from the basin margin. Overlaps in 2 200 to 2 350 Ma zircon ages with those of volcanogenic zircon in the Timeball Hill Formation again suggest recycling. The origin of 2 080 to 2 150 Ma zircon is uncertain, but neither poorly constrained sources in the Kaapvaal Craton (e.g., Okwa Basement Complex) nor recycling of volcanogenic material from post-Magaliesberg formations can be ruled out.","PeriodicalId":504199,"journal":{"name":"South African Journal of Geology","volume":"29 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140711069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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