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Electrically Switchable Transmissive and Reflective Liquid Crystal Polarization Gratings Based on Cholesteric Liquid Crystals 基于胆甾型液晶的可电动切换透射和反射液晶偏振光栅
Pub Date : 2024-08-10 DOI: 10.1002/admt.202400726
Yi-Te Chuang, Yu-Chieh Li, Ting‐Mao Feng, Chun-Ta Wang
Liquid crystal polarization gratings liquid crystal Pancharatnam‐Berry phase optical element (LCPGs) are a superior alternative to traditional diffraction gratings due to their high diffraction efficiency, strong polarization sensitivity, and versatile tunability. This paper introduces an electrically switchable liquid crystal polarization grating based on cholesteric liquid crystals (CLCs). The LCPG is designed to operate in reflective (R‐mode) and transmissive (T‐mode) states. It utilizes the standing helical (SH) configuration of CLCs for reflective functionality and transitions to a lying helical (LH) configuration for transmissive operations. This dual‐mode capability is achieved through a unique application of electric fields, which reorient the liquid crystal helix axis according to the desired optical function. The performance of the LCPG in both R‐mode and T‐mode is evaluated by applying different frequencies and voltages to dynamically switch between the helical states. The manufacturing process is simple, and the device performs robustly. This suggests that the technology could be useful for developing optical systems that require dynamic control over light modulation.
液晶偏振光栅液晶Pancharatnam-Berry相光学元件(LCPGs)具有高衍射效率、强偏振灵敏度和多功能可调性,是传统衍射光栅的优越替代品。本文介绍了一种基于胆甾型液晶(CLCs)的电动可切换液晶偏振光栅。LCPG 可在反射(R 模式)和透射(T 模式)状态下工作。它利用 CLC 的站立螺旋(SH)配置实现反射功能,并过渡到躺卧螺旋(LH)配置实现透射功能。这种双模功能是通过独特的电场应用实现的,电场可根据所需的光学功能调整液晶螺旋轴的方向。通过应用不同的频率和电压在螺旋状态之间进行动态切换,对 LCPG 在 R 模式和 T 模式下的性能进行了评估。制造工艺简单,器件性能稳定。这表明该技术可用于开发需要对光调制进行动态控制的光学系统。
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引用次数: 0
Low‐Temperature Poly‐Si Thin‐Film Transistor with High‐k ZrAlOx Gate Insulator with SiO2 Blocking Layer 带有二氧化硅阻挡层的高 k ZrAlOx 栅极绝缘体的低温多晶硅薄膜晶体管
Pub Date : 2024-08-10 DOI: 10.1002/admt.202400820
Yuna Kim, Byunglib Jung, Md Mobaidul Islam, Byeonggwan Kim, Jin Jang
Low‐power electronic devices are of increasing interest with high‐k gate insulators (GI). Herein, the performance and stability of low‐temperature poly‐Si (LTPS) thin‐film transistors (TFTs) are investigated with two different GIs: spray pyrolyzed zirconiumaluminum oxide (ZAO) directly deposited on poly‐Si, and SiO2/ZAO stack GI. The LTPS TFT with SiO2/ZAO stack GI exhibits hysteresis free characteristics with a threshold voltage of −0.2 V, field‐effect mobility of 114.4 cm2 V−1 s−1, subthreshold swing of 0.10 V dec−1, and high on/off current ratio of 7.3 × 108, at a gate voltage sweeping ±6 V. The TFT exhibits very stable operation under negative bias temperature stress. The X‐ray photoelectron spectroscopy and high‐resolution transmission electron microscopy analyses demonstrate that the diffusion of Zr and Al into poly‐Si deteriorates device performance with ZAO only GI. A thin SiO2 on LTPS blocks the diffusion of Zr and Al, resulting the high‐performance and stable p‐type LTPS TFT with a high‐k SiO2/ZAO stack GI. Finally, a 7‐stage ring oscillator using LTPS TFTs with SiO2/ZAO stack GI is demonstrated, exhibiting an oscillation frequency of 7.49 MHz and a propagation delay of 9.54 ns at a supply voltage of 6 V, indicating its suitability for low‐power consumption TFT electronics and displays.
采用高 K 栅极绝缘体 (GI) 的低功耗电子器件越来越受到关注。本文研究了使用两种不同栅极绝缘体的低温多晶硅(LTPS)薄膜晶体管(TFT)的性能和稳定性:直接沉积在多晶硅上的喷雾热解氧化锆(ZAO)和二氧化硅/ZAO叠层栅极绝缘体。采用 SiO2/ZAO 叠层 GI 的 LTPS TFT 具有无滞后特性,阈值电压为 -0.2 V,场效应迁移率为 114.4 cm2 V-1 s-1,阈下摆幅为 0.10 V dec-1,在栅极电压为 ±6 V 时具有 7.3 × 108 的高导通/关断电流比。X 射线光电子能谱和高分辨率透射电子显微镜分析表明,由于 Zr 和 Al 扩散到多晶硅中,导致器件性能下降,只有 GI 采用了 ZAO。LTPS 上的薄二氧化硅阻挡了锆和铝的扩散,从而产生了具有高 k SiO2/ZAO 叠层 GI 的高性能、稳定的 p 型 LTPS TFT。最后,展示了使用具有 SiO2/ZAO 叠层 GI 的 LTPS TFT 的 7 级环形振荡器,在 6 V 电源电压下,振荡频率为 7.49 MHz,传播延迟为 9.54 ns,表明它适用于低功耗 TFT 电子产品和显示器。
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引用次数: 0
Impact of Crosslinking Degree on Chitosan and Oxidized Guar Gum‐Based Injectable Hydrogels for Biomedical Applications 交联度对用于生物医学应用的壳聚糖和氧化瓜尔胶注射水凝胶的影响
Pub Date : 2024-08-10 DOI: 10.1002/admt.202400285
R. N. F. Moreira Filho, Matheus Xavier de Oliveira, Ana Lorena Brito Soares, Lidyane Souto Maciel Marques, Pascale Chevallier, Diego Mantovani, J. P. Andrade Feitosa, Rodrigo Silveira Vieira
Evaluating the biodegradability and biocompatibility of hydrogels is essential for identifying materials suitable for biomedical applications. This study describes the fabrication of hydrogels utilizing physiological‐soluble chitosan (N‐succinyl chitosan, NSC) crosslinked with dialdehyde guar gum (Oxidized Galactomannan, OxGM) via the Schiff‐base reaction. Hydrogels with varying volumetric ratios of NSC/OxGM, resulting in distinct NH2/CHO functional group ratios and crosslinking degrees, underwent comprehensive characterization using Fourier‐transform infrared spectroscopy (FTIR), X‐ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), swelling, and scanning electron microscopy (SEM). Gelation time (tgel) is assessed by rheological analysis (tgel = G′ > G″), where tgel increased with higher crosslinking density, reaching a maximum value of ≈80 s. Biodegradation analysis in phosphate‐buffered saline (PBS) with lysozyme (13 mg L−1) revealed that the crosslinking degree significantly influenced degradation, with lower crosslinking associated with an elevated degradation profile. Moreover, cell viability assays with fibroblastic cells demonstrated minimal cytotoxicity, but an increase in free aldehyde groups correlated with decreased cell viability. For the 75C25C hydrogel, the compressive test yielded a Young's modulus value of 67.2 kPa (±8.5). These results imply that the hydrogels developed exhibit favorable biodegradability and biocompatibility, making them promising candidates for diverse biomedical applications.
评估水凝胶的生物降解性和生物相容性对于确定适合生物医学应用的材料至关重要。本研究介绍了利用生理可溶性壳聚糖(N-琥珀酰壳聚糖,NSC)与二醛瓜尔胶(氧化半乳甘露聚糖,OxGM)通过席夫碱反应交联制成的水凝胶。使用傅立叶变换红外光谱(FTIR)、X 射线光电子能谱(XPS)、热重分析(TGA)、溶胀和扫描电子显微镜(SEM)对不同体积比的 NSC/OxGM 水凝胶进行了综合表征,从而得出不同的 NH2/CHO 官能团比例和交联度。在含溶菌酶(13 毫克/升)的磷酸盐缓冲盐水(PBS)中进行的生物降解分析表明,交联度对降解有显著影响,交联度越低,降解曲线越高。此外,用成纤维细胞进行的细胞存活率测定显示,细胞毒性极小,但游离醛基的增加与细胞存活率的降低有关。对于 75C25C 水凝胶,压缩测试得出的杨氏模量值为 67.2 kPa(±8.5)。这些结果表明,所开发的水凝胶具有良好的生物降解性和生物相容性,有望用于各种生物医学应用。
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引用次数: 0
Chemical Vapor Deposition Growth of Vertical Graphene/WSe2 Heterostructures with Interlayer Twists 化学气相沉积生长具有层间扭曲的垂直石墨烯/WSe2 异质结构
Pub Date : 2024-08-09 DOI: 10.1002/admt.202400901
Xiahong Zhou, Mengya Liu, Xudong Xue, Shan Liu, G. Yu
The interlayer twist is a new degree of freedom for forming moiré superlattices in 2D vertical heterostructures, which is expected to play an important role in the emerging field of twistronics. The constructions of heterostructures by transfer and re‐stacking way have low efficiency and are prone to causing interface pollution. In this study, vertical molybdenum diselenide (WSe2)/graphene heterostructures with twisted angles are realized by using two‐step chemical vapor deposition (CVD) growth strategy. The WSe2/graphene heterostructures exhibit Raman and photoluminescence (PL) responses of both WSe2 and graphene. The PL quenching of WSe2 in the heterostructures manifests that direct CVD growth is conducive to the formation of a cleaner interlayer interface between WSe2 and graphene layers, resulting in better interlayer coupling. The adhesion and surface potential differences indicate the formation of hetero‐bilayer stacks. By analyzing the apparent growth orientations and crystal diffractions, vertical WSe2/graphene heterostructures exhibit a wide range of interlayer twisted angles (3.6–46.5°). The difference between the growth behavior with twisted angles and the typical epitaxial growth mode may originate from the heterogeneous nucleation, leading to interlayer twists of the hetero‐bilayers. These findings provide a facile protocol for the preparations of twisted hetero‐bilayers and a material system for fundamental research of twistronics.
层间扭曲是在二维垂直异质结构中形成摩尔纹超晶格的新自由度,有望在新兴的双电子学领域发挥重要作用。通过转移和再堆叠方式构建异质结构的效率较低,而且容易造成界面污染。本研究采用两步化学气相沉积(CVD)生长策略,实现了具有扭曲角度的垂直二硒化钼(WSe2)/石墨烯异质结构。WSe2/ 石墨烯异质结构同时显示出 WSe2 和石墨烯的拉曼和光致发光 (PL) 反应。异质结构中 WSe2 的光致发光淬灭表明,直接 CVD 生长有利于在 WSe2 和石墨烯层之间形成更清洁的层间界面,从而实现更好的层间耦合。附着力和表面电位差表明形成了异质双层堆叠。通过分析表观生长方向和晶体衍射,垂直 WSe2/ 石墨烯异质结构呈现出广泛的层间扭曲角(3.6-46.5°)。具有扭曲角度的生长行为与典型的外延生长模式之间的差异可能源于异质成核,从而导致异质层的层间扭曲。这些发现为制备扭曲异质层提供了一个简便的方案,也为扭曲电子学的基础研究提供了一个材料系统。
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引用次数: 0
Solid–Liquid Elastic Pendulum Triboelectric Nanogenerator Design for Application to Omnidirectional Blue Energy Harvesting 应用于全向蓝光能量收集的固液弹性摆三电纳米发电机设计
Pub Date : 2024-08-08 DOI: 10.1002/admt.202400531
Xinyao Zhang, Yuxiang Su, Xin Dong, Jinlin Wu, Xiaonan Su, Guanyu Dai, Anguo Liu, Wuwei Feng, Keyang Zhao, Bangjun Lei, Zhenhua Li
The ocean is regarded as a significant resource for renewable energy development. The use of triboelectric nanogenerators (TENGs) provides an effective approach to capturing energy from low‐frequency, random, and disorganized water waves. In this paper, the solid–liquid elastic pendulum (SLEP)‐TENG is designed for omnidirectional blue energy harvesting applications. Differentiating from traditional designs, the proposed TENG has a simple, reliable, and durable flexible pendulum structure with a spherical shell and a solid counterweight at the bottom that can absorb the impact of ocean waves efficiently. The structure also has a hollow hexagonal space that allows it to generate a larger contact area when it is subjected to wave impacts from different directions. Under low‐speed lateral motion conditions (at frequencies below 0.83 Hz), its open‐circuit voltage VOC, short circuit current ISC, and power density Pm can reach up to 486.8 V, 16.9 µA, and 10.26 W m−3, respectively, which is sufficient to power more than 450 commercial light‐emitting diodes. By storing electrical power in small capacitors, the TENG can support small power‐consuming devices, e.g., thermometers and calculators. Therefore, the SLEP‐TENG has great potential for use in combination with Internet of Things devices to enable self‐powered sensing system construction in complex ocean areas.
海洋被视为可再生能源开发的重要资源。三电纳米发电机(TENGs)的使用为从低频、随机和无序的水波中获取能量提供了一种有效的方法。本文设计的固液弹性摆(SLEP)-TENG 可用于全向蓝色能量收集应用。与传统设计不同的是,所提出的 TENG 具有简单、可靠和耐用的弹性摆结构,其球形外壳和底部的固体配重可有效吸收海浪的冲击。该结构还具有中空的六边形空间,使其在受到来自不同方向的海浪冲击时能够产生更大的接触面积。在低速横向运动条件下(频率低于 0.83 Hz),其开路电压 VOC、短路电流 ISC 和功率密度 Pm 分别可达 486.8 V、16.9 µA 和 10.26 W m-3,足以为 450 多个商用发光二极管供电。通过在小型电容器中储存电能,TENG 可以支持小型耗电设备,如温度计和计算器。因此,SLEP-TENG 与物联网设备结合使用,在复杂海域构建自供电传感系统方面具有巨大潜力。
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引用次数: 0
Colloidal Semiconductor Quantum Well Supraparticles as Low‐Threshold and Photostable Microlasers 作为低阈值和光稳定微激光器的胶体半导体量子阱超微粒
Pub Date : 2024-08-08 DOI: 10.1002/admt.202401152
P. Alves, Gemma Quinn, M. Strain, E. G. Durmusoglu, M. Sharma, H. Demir, Paul R. Edwards, Robert W. Martin, M. D. Dawson, N. Laurand
This study introduces and compares the lasing performance of micron‐sized and sphere‐shaped supraparticle (SP) lasers fabricated through bottom‐up assembly of II‐VI semiconductor colloidal quantum wells (CQWs) with their counterparts made of quantum dots (CQDs). CQWs consist of a 4‐monolayers thick CdSe core and an 8‐monolayers thick CdxZn1‐xS shell with a nominal size of 14 × 15 × 4.2 nm, and CQDs of CdSxSe1‐x/ZnS with 6 nm diameter. SPs are optically characterized with a 0.76 ns pulse laser (spot size: 2.88 × 10−7 cm2) at 532 nm, and emit in the 620–670 nm spectral range. Results show that CQW SPs have lasing thresholds twice as low (0.1–0.3 nJ) as CQD SPs (0.3–0.6 nJ), and stress tests using a constant 0.6 nJ optical pump energy demonstrate that CQW SPs withstand lasing emission for longer than CQD SPs. Lasing emission in CQW and CQD SPs under continuous operation yields half‐lives of τCQW SP ≈150 min and τCQD SP ≈22 min, respectively. The half‐life of CQW SPs is further extended to τQW ≈385 min when optically pumped at 0.5 nJ. Such results compare favorably to those in the literature and highlight the performance of CdSe‐based CQW SPs for laser applications.
本研究介绍并比较了通过自下而上组装 II-VI 半导体胶体量子阱(CQWs)和量子点(CQDs)制造的微米级和球形超粒子(SP)激光器的激光性能。CQW 由 4 单层厚的 CdSe 内核和 8 单层厚的 CdxZn1-xS 外壳组成,标称尺寸为 14 × 15 × 4.2 nm,CQD 由直径为 6 nm 的 CdSxSe1-x/ZnS 组成。用 0.76 ns 脉冲激光(光斑大小:2.88 × 10-7 cm2)在 532 nm 波长对 SPs 进行光学表征,并在 620-670 nm 光谱范围内发光。结果表明,CQW SP 的激光阈值(0.1-0.3 nJ)比 CQD SP 的激光阈值(0.3-0.6 nJ)低两倍,使用恒定的 0.6 nJ 光泵浦能量进行的应力测试表明,CQW SP 比 CQD SP 能够承受更长时间的激光发射。在连续工作条件下,CQW 和 CQD SP 的激光发射半衰期分别为 τCQW SP ≈150 分钟和 τCQD SP ≈22 分钟。在 0.5 nJ 的光泵浦条件下,CQW SP 的半衰期进一步延长至 τQW ≈385 分钟。这些结果与文献中的结果相比毫不逊色,凸显了碲化镉基 CQW SPs 在激光应用中的性能。
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引用次数: 0
Single‐Step Inkjet Printing PDMS Microlens Arrays for Tunable‐Focus Artificial Compound Eyes 用于可调焦人工复眼的单步喷墨打印 PDMS 微透镜阵列
Pub Date : 2024-08-08 DOI: 10.1002/admt.202400016
Shiyu Zhou, Hao Guo, Bo Qian, Lingying Li, Xuejun Shi
Flexible, tunable‐focus artificial compound eyes (ACEs) have been extensively studied due to their large field of view (FOV), variable focal length, and large depth of field. The fabrication of flexible polydimethylsiloxane (PDMS) microlens arrays (MLAs) is a key issue for this system. Due to the difficulty of directly precision‐machining PDMS, PDMS MLAs typically need molds, which involve complex, costly, and hard‐to‐control methods like laser fabrication and lithography. In this paper, a moldless, single‐step inkjet printing method for PDMS MLAs is proposed. By optimizing the rheological properties of the PDMS ink and adjusting printing waveforms, voltages, and frequencies, this study achieves, for the first time, large‐scale inkjet printing fabrication of PDMS MLAs. The surface morphologies of the microlenses are uniformly consistent, resembling spherical caps. Subsequently, the optimized printed PDMS MLA film is bonded to a microfluidic chip to fabricate a hydraulically driven, variable‐focus ACE with the FOV tunable between 0° and 140° and the focal length tunable from 6 mm to infinity. The ACE is demonstrated to image the objects at various distances by altering the volume of the injected liquid and possessing good optical imaging quality.
柔性可调焦人工复眼(ACE)具有大视野(FOV)、可变焦距和大景深的特点,因此已被广泛研究。柔性聚二甲基硅氧烷(PDMS)微透镜阵列(MLA)的制造是该系统的关键问题。由于难以直接精密加工 PDMS,PDMS 微透镜阵列通常需要模具,这涉及复杂、昂贵且难以控制的方法,如激光制造和光刻。本文提出了一种无模具、单步喷墨打印 PDMS MLA 的方法。通过优化 PDMS 墨水的流变特性以及调整打印波形、电压和频率,本研究首次实现了 PDMS MLA 的大规模喷墨打印制造。微透镜的表面形态均匀一致,类似球形帽。随后,将优化打印的 PDMS MLA 薄膜粘合到微流控芯片上,制造出液压驱动的可变焦距 ACE,其视场角可在 0° 和 140° 之间调节,焦距可在 6 mm 到无限远之间调节。实验证明,通过改变注入液体的体积,ACE 可对不同距离的物体成像,并具有良好的光学成像质量。
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引用次数: 0
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Advanced Materials Technologies
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