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Effect of Fin Type and Geometry on Thermal and Hydraulic Performance in Conditions of Combined-Cycle Nuclear Power Plant with High-Temperature Gas-Cooled Reactors 高温气冷堆联合循环核电站条件下鳍片类型和几何形状对热性能和水力性能的影响
Pub Date : 2024-08-09 DOI: 10.3390/thermo4030020
K.A.A. Ramadan, K.V. Slyusarskiy
One method of nuclear energy development involves using helium. Its properties make using extended surfaces obligatory. However, currently nuclear technology does not typically use finned tubes. This study explores ways of enhancing heat transfer efficiency in a high-temperature gas-cooled reactor system by using novel fin designs in the heat exchanger for residual heat removal. Four different types of fins were studied: annular, serrated, square, and helical. The effect of fin height, thickness, and number was evaluated. Serrated and helical fins demonstrated superior performance compared to conventional annular fin designs, which was expressed in enhanced efficiency. The thickness of fins was found to have the strongest influence on the efficiency, while the height and number of fins per meter had weaker effects. In addition, the study emphasized the significance of considering complex effects when optimizing fin design, like the effect of fin geometry on the velocity of helium. The findings highlight the potential of creative fin designs to greatly enhance the efficiency and dependability of gas-cooled reactor systems, opening up possibilities for advancements in nuclear power plant technology.
核能开发的一种方法是使用氦气。由于氦的特性,必须使用扩展表面。然而,目前的核技术通常不使用翅片管。本研究探讨了如何通过在热交换器中使用新型翅片设计来去除余热,从而提高高温气体冷却反应堆系统的传热效率。研究了四种不同类型的翅片:环形、锯齿形、方形和螺旋形。对翅片高度、厚度和数量的影响进行了评估。与传统的环形翅片设计相比,锯齿形和螺旋形翅片表现出更优越的性能,这体现在效率的提高上。研究发现,翅片厚度对效率的影响最大,而翅片高度和每米翅片数量的影响较小。此外,研究还强调了在优化翅片设计时考虑复杂效应的重要性,例如翅片几何形状对氦气速度的影响。研究结果凸显了创造性翅片设计的潜力,可大大提高气冷反应堆系统的效率和可靠性,为核电站技术的进步提供了可能性。
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引用次数: 0
Unified Classical Thermodynamics: Primacy of Dissymmetry over Free Energy 统一经典热力学:不对称高于自由能
Pub Date : 2024-07-19 DOI: 10.3390/thermo4030017
Lin-Shu Wang
In thermodynamic theory, free energy (i.e., available energy) is the concept facilitating the combined applications of the theory’s two fundamental laws, the first and the second laws of thermodynamics. The critical step was taken by Kelvin, then by Helmholtz and Gibbs—that in natural processes, free energy dissipates spontaneously. With the formulation of the second law of entropy growth, this may be referred to as the dissymmetry proposition manifested in the spontaneous increase of system/environment entropy towards equilibrium. Because of Kelvin’s pre-entropy law formulation of free energy, our concept of free energy is still defined, within a framework on the premise of primacy of energy, as “body’s internal energy or enthalpy, subtracted by energy that is not available.” This primacy of energy is called into question because the driving force to cause a system’s change is the purview of the second law. This paper makes a case for an engineering thermodynamics framework, instead, to be based on the premise of the primacy of dissymmetry over free energy. With Gibbsian thermodynamics undergirded with dissymmetry proposition and engineering thermodynamics with a dissymmetry premise, the two branches of thermodynamics are unified to become classical thermodynamics.
在热力学理论中,自由能(即可用能量)是一个概念,它促进了热力学第一定律和第二定律这两个基本定律的综合应用。开尔文、亥姆霍兹和吉布斯先后迈出了关键的一步--在自然过程中,自由能会自发耗散。根据熵增第二定律的表述,这可以被称为不对称命题,表现为系统/环境熵自发增加以达到平衡。由于开尔文在熵定律之前对自由能的表述,我们对自由能的概念仍然是在能量至上的前提下,将其定义为 "身体的内能或焓,减去不可用的能量"。由于导致系统变化的驱动力属于第二定律的范畴,因此能量的首要地位受到质疑。本文提出了一个工程热力学框架,该框架应建立在不对称比自由能更重要的前提之上。吉布斯热力学以不对称命题为基础,工程热力学以不对称为前提,两个热力学分支统一成为经典热力学。
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引用次数: 0
On the Second Law of Thermodynamics in Continuum Physics 论连续物理学中的热力学第二定律
Pub Date : 2024-06-11 DOI: 10.3390/thermo4020015
C. Giorgi, A. Morro
The paper revisits the formulation of the second law in continuum physics and investigates new methods of exploitation. Both the entropy flux and the entropy production are taken to be expressed by constitutive equations. In three-dimensional settings, vectors and tensors are in order and they occur through inner products in the inequality representing the second law; a representation formula, which is quite uncommon in the literature, produces the general solution whenever the sought equations are considered in rate-type forms. Next, the occurrence of the entropy production as a constitutive function is shown to produce a wider set of physically admissible models. Furthermore the constitutive property of the entropy production results in an additional, essential term in the evolution equation of rate-type materials, as is the case for Duhem-like hysteretic models. This feature of thermodynamically consistent hysteretic materials is exemplified for elastic–plastic materials. The representation formula is shown to allow more general non-local properties while the constitutive entropy production proves essential for the modeling of hysteresis.
本文重新审视了连续物理学中第二定律的表述,并研究了新的利用方法。熵通量和熵产生都用构成方程来表示。在三维环境中,矢量和张量是有序的,它们在表示第二定律的不等式中通过内积出现;只要以速率型形式考虑所寻求的方程,文献中非常少见的表示公式就能产生一般解。接下来,熵的产生作为一种构成函数,可以产生更多物理上可接受的模型。此外,熵产生的构成特性还在速率型材料的演化方程中产生了一个额外的基本项,就像杜恒滞后模型一样。热力学一致的滞变材料的这一特征在弹性塑料材料中得到了体现。研究表明,表示公式允许更多的非局部特性,而构成性熵产生则证明对滞后建模至关重要。
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引用次数: 0
An Optimized Artificial Neural Network Model of a Limaçon-to-Circular Gas Expander with an Inlet Valve 带有进气阀的利马逊-圆形气体膨胀机的优化人工神经网络模型
Pub Date : 2024-06-11 DOI: 10.3390/thermo4020014
Md Shazzad Hossain, Ibrahim A. Sultan, Truong H. Phung, Apurv Kumar
In this work, an artificial neural network (ANN)-based model is proposed to describe the input–output relationships in a Limaçon-To-Circular (L2C) gas expander with an inlet valve. The L2C gas expander is a type of energy converter that has great potential to be used in organic Rankine cycle (ORC)-based small-scale power plants. The proposed model predicts the different performance indices of a limaçon gas expander for different input pressures, rotor velocities, and valve cutoff angles. A network model is constructed and optimized for different model parameters to achieve the best prediction performance compared to the classic mathematical model of the system. An overall normalized mean square error of 0.0014, coefficient of determination (R2) of 0.98, and mean average error of 0.0114 are reported. This implies that the surrogate model can effectively mimic the actual model with high precision. The model performance is also compared to a linear interpolation (LI) method. It is found that the proposed ANN model predictions are about 96.53% accurate for a given error threshold, compared to about 91.46% accuracy of the LI method. Thus the proposed model can effectively predict different output parameters of a limaçon gas expander such as energy, filling factor, isentropic efficiency, and mass flow for different operating conditions. Of note, the model is only trained by a set of input and target values; thus, the performance of the model is not affected by the internal complex mathematical models of the overall valved-expander system. This neural network-based approach is highly suitable for optimization, as the alternative iterative analysis of the complex analytical model is time-consuming and requires higher computational resources. A similar modeling approach with some modifications could also be utilized to design controllers for these types of systems that are difficult to model mathematically.
本研究提出了一种基于人工神经网络(ANN)的模型,用于描述带有进气阀的利马孔到圆形(L2C)气体膨胀机的输入输出关系。L2C 气体膨胀机是一种能源转换器,在基于有机郎肯循环 (ORC) 的小型发电厂中具有巨大的应用潜力。所提出的模型可预测利马孔气体膨胀机在不同输入压力、转子速度和阀门截止角下的不同性能指标。与传统的系统数学模型相比,该模型构建了一个网络模型,并针对不同的模型参数进行了优化,以实现最佳的预测性能。报告显示,总体归一化均方误差为 0.0014,决定系数 (R2) 为 0.98,平均平均误差为 0.0114。这意味着代用模型可以高精度地有效模拟实际模型。模型性能还与线性插值 (LI) 方法进行了比较。结果发现,在给定的误差阈值下,所提出的 ANN 模型预测准确率约为 96.53%,而线性插值法的准确率约为 91.46%。因此,所提出的模型可以有效预测利马逊气体膨胀机在不同运行条件下的不同输出参数,如能量、充气系数、等熵效率和质量流量。值得注意的是,该模型仅通过一组输入值和目标值进行训练,因此其性能不会受到整个阀式膨胀机系统内部复杂数学模型的影响。这种基于神经网络的方法非常适合优化,因为替代复杂分析模型的迭代分析既耗时又需要较多的计算资源。类似的建模方法经过一些修改后,也可用于为这类难以建立数学模型的系统设计控制器。
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引用次数: 0
Comparative Numerical Analysis of Keyhole Shape and Penetration Depth in Laser Spot Welding of Aluminum with Power Wave Modulation 采用功率波调制对铝进行激光点焊时锁孔形状和穿透深度的数值对比分析
Pub Date : 2024-05-23 DOI: 10.3390/thermo4020013
Saeid SaediArdahaei, Xuan-Tan Pham
Keyhole mode laser welding is a valuable technique for welding thick materials in industrial applications. However, its susceptibility to fluctuations and instabilities poses challenges, leading to defects that compromise weld quality. Observing the keyhole during laser welding is challenging due to bright process radiation, and existing observation methods are complex and expensive. This paper alternatively presents a novel numerical modeling approach for laser spot welding of aluminum through a modified mixture theory, a modified level-set (LS) method, and a thermal enthalpy porosity technique. The effects of laser parameters on keyhole penetration depth are investigated, with a focus on laser power, spot radius, frequency, and pulse wave modulation in pulsed wave (PW) versus continuous wave (CW) laser welding. PW laser welding involves the careful modulation of power waves, specifically adjusting the pulse width, pulse number, and pulse shapes. Results indicate a greater than 80 percent increase in the keyhole penetration depth with higher laser power, pulse width, and pulse number, as well as decreased spot radius. Keyhole instabilities are also more pronounced with higher pulse width/numbers and frequencies. Notably, the rectangular pulse shape demonstrates substantially deeper penetration compared to CW welding and other pulse shapes. This study enhances understanding of weld pool dynamics and provides insights into optimizing laser welding parameters to mitigate defects and improve weld quality.
锁孔模式激光焊接是工业应用中焊接厚材料的重要技术。然而,它容易受到波动和不稳定性的影响,从而导致缺陷,影响焊接质量。由于激光焊接过程中会产生明亮的辐射,因此在焊接过程中观察锁孔具有挑战性,而且现有的观察方法复杂而昂贵。本文通过改进的混合物理论、改进的水平集(LS)方法和热焓气孔技术,提出了一种新的铝激光点焊数值建模方法。研究了激光参数对锁孔穿透深度的影响,重点是脉冲波(PW)与连续波(CW)激光焊接中的激光功率、光斑半径、频率和脉冲波调制。脉冲波激光焊接涉及对功率波的精心调制,特别是调整脉冲宽度、脉冲数和脉冲形状。结果表明,随着激光功率、脉冲宽度和脉冲数的增加,锁孔穿透深度增加了 80%以上,同时光斑半径也减小了。脉冲宽度/数量和频率越高,锁孔的不稳定性也越明显。值得注意的是,与 CW 焊接和其他脉冲形状相比,矩形脉冲形状的穿透深度更深。这项研究加深了对焊接熔池动力学的理解,并为优化激光焊接参数以减少缺陷和提高焊接质量提供了启示。
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引用次数: 0
The Effect of Temperature on the London Dispersive and Lewis Acid-Base Surface Energies of Polymethyl Methacrylate Adsorbed on Silica by Inverse Gas Chromatography 通过反气相色谱法研究温度对吸附在二氧化硅上的聚甲基丙烯酸甲酯的伦敦分散性和路易斯酸碱表面能的影响
Pub Date : 2024-05-17 DOI: 10.3390/thermo4020012
T. Hamieh
Inverse gas chromatography at infinite dilution was used to determine the surface thermodynamic properties of silica particles and PMMA adsorbed on silica, and more particularly, to quantify the London dispersive energy γsd, the Lewis acid γs+, and base γs− polar surface energies of PMMA/silica composites as a function of the temperature and the recovery fraction θ of PMMA. The polar acid-base surface energy γsAB and the total surface energy of the different composites were then deduced as a function of the temperature. In this paper, the Hamieh thermal model was used to quantify the surface thermodynamic energy of polymethyl methacrylate (PMMA) adsorbed on silica particles at different recovery fractions. A comparison of the new results was carried out with those obtained by applying other molecular models of the surface areas of organic molecules adsorbed on the different solid substrates. An important deviation of these molecular models from the thermal model was proved. The determination of γsd, γs+, γs−, and γsAB of PMMA in both the bulk and adsorbed phases showed an important non-linearity variation of these surface parameters as a function of the temperature. The presence of maxima in the curves of γsd(T) highlighted the second-order transition temperatures in PMMA showing beta-relaxation, glass transition, and liquid–liquid temperatures. These three transition temperatures depended on the adsorption rate of PMMA on silica. The proposed method gave a new relation between the recovery fraction of PMMA and its London dispersive energy, showing an important effect of the temperature on the surface energy parameters of the adsorption of PMMA on silica. A universal equation relating γsd(T,θ) of the systems PMMA/silica to the recovery fraction and the temperature was proposed.
采用无限稀释的反气相色谱法确定二氧化硅颗粒和吸附在二氧化硅上的 PMMA 的表面热力学性质,特别是量化 PMMA/二氧化硅复合材料的伦敦色散能 γsd、路易斯酸 γs+、碱 γs- 极性表面能与温度和 PMMA 的回收率 θ 的函数关系。然后推导出不同复合材料的极性酸碱表面能 γsAB 和总表面能与温度的函数关系。本文使用 Hamieh 热模型量化了不同回收率下吸附在二氧化硅颗粒上的聚甲基丙烯酸甲酯(PMMA)的表面热力学能量。将新结果与应用其他分子模型计算吸附在不同固体基底上的有机分子表面积所获得的结果进行了比较。结果表明,这些分子模型与热模型存在很大偏差。在测定 PMMA 体积相和吸附相的γsd、γs+、γs- 和 γsAB 时,发现这些表面参数随温度的变化呈重要的非线性变化。γsd(T)曲线中出现的最大值突显了 PMMA 的二阶转变温度,即β-松弛温度、玻璃化转变温度和液-液温度。这三个转变温度取决于 PMMA 在二氧化硅上的吸附速率。所提出的方法给出了 PMMA 的回收率与其伦敦色散能之间的新关系,表明温度对 PMMA 在二氧化硅上吸附的表面能参数有重要影响。提出了 PMMA/二氧化硅体系的 γsd(T,θ)与回收率和温度之间的通用方程。
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引用次数: 0
Molecular, Crystalline, and Microstructures of Lipids from Astrocaryum Species in Guyana and Their Thermal and Flow Behavior 圭亚那天南星物种脂质的分子、结晶和微结构及其热和流动行为
Pub Date : 2024-03-12 DOI: 10.3390/thermo4010009
Shaveshwar Deonarine, Navindra Soodoo, L. Bouzidi, R. Emery, Sanela Martic, Suresh S. Narine
The phase behavior of lipids extracted from Astrocaryum vulgare (AV) and Astrocaryum aculeatum (AA) pulp and kernels and their microstructural, thermal and flow properties were studied. The lipid profiles, crystal structures, microstructures, thermal stabilities and flow behaviors of these lipids provided important structure–function information that are useful to assess potential applications in the food, cosmetic and pharmaceutical industries. AV and AA fruits were sourced from the lowlands and rainforests, respectively, of Guyana. AV and AA pulp oils (AVP and AAP) were distinguished from each other in composition and unsaturation, with AVP oils being predominated by a di-unsaturated TAG (2-(palmitoyloxy)propane-1,3-diyl dioleate (POO)) and AAP oils predominated by propane-1,2,3-triyl trioleate (OOO); there were unsaturation levels of 65% and 80%, respectively. The main fatty acids in AVP oils were oleic, palmitic and stearic; for AAP, these were oleic, linoleic, palmitic and stearic. The kernel fats of AV and AA were similar in composition and had saturation levels of 80%, being mainly comprised of tri-saturated TAGs propane-1,2,3-triyl tridodecanoate (LLL) and 3-(tetradecanoyloxy)propane-1,2-diyl didodecanoate (LML). The onset of mass loss (T5%on) of AV and AA pulp oils were similar at 328 ± 6 °C, which were 31 °C ± 9 higher compared to that of the kernel fats, which demonstrated similar T5%on = 293 ± 7 °C. AA and AV pulp oils were liquid at room temperature, with melting points of −5 ± 1 °C and 3 ± 1 °C, respectively; both kernel fats were solid at room temperature, packing in β′ (90% of crystals) and β (10% of crystals) polymorphic forms and melting almost identically at 30 ± 1 °C. Pulp oils demonstrated sporadic nucleation at the onset of crystallization with slow growth into rod-shaped crystallites, leading to an approximately 50% degree of crystallization at undercooling of approximately 40K. Nucleation for kernel fats was instantaneous at undercooling of approximately 23K, demonstrating a spherulitic growth pattern incorporating crystalline lamella and a 90% degree of crystallization. Kernel fats and pulp oils demonstrated Newtonian flow behavior and similar dynamic viscosity in the melt, approximately 28.5 mPa·s at 40 °C. The lipid profiles of AVP and AAP oils were dominated by unsaturated TAGs, suggesting potential nutrition and health benefits, particularly compared to other tropical oils with higher saturation levels, such as palm oil. AAP oil in particular is as unsaturated as olive oil, contains high levels of beta carotene and provides a unique flavor profile. The AAK and AVK lipid profiles and phase transformation indicate potential for applications where a high solid fat content and medium-chain fatty acids are required. Their high lauric and myristic acid content makes them similar to industrially important tropical oils (coconut and palm kernel), suggesting their use in similar formulations. The melting point and plasticity o
研究了从Astrocaryum vulgare(AV)和Astrocaryum aculeatum(AA)果肉和果核中提取的脂质的相行为及其微结构、热和流动特性。这些脂质的特征、晶体结构、微观结构、热稳定性和流动行为提供了重要的结构-功能信息,有助于评估其在食品、化妆品和制药行业的潜在应用。AV 和 AA 果实分别来自圭亚那的低地和热带雨林。AV果肉油和AA果肉油(AVP和AAP)在成分和不饱和程度上有区别,AVP油以二不饱和TAG(2-(棕榈酰氧基)丙烷-1,3-二基二油酸酯(POO))为主,AAP油以丙烷-1,2,3-三基三油酸酯(OOO)为主;不饱和程度分别为65%和80%。AVP 油脂中的主要脂肪酸是油酸、棕榈酸和硬脂酸;AAP 油脂中的主要脂肪酸是油酸、亚油酸、棕榈酸和硬脂酸。AV 和 AA 的果仁脂肪成分相似,饱和度均为 80%,主要由三饱和 TAGs 丙烷-1,2,3-三基双癸酸酯(LLL)和 3-(十四碳酰氧基)丙烷-1,2-二基双癸酸酯(LML)组成。AV和AA纸浆油的质量损失起始温度(T5%on)相近,均为328 ± 6 °C,比核仁油脂的质量损失起始温度(T5%on = 293 ± 7 °C)高31 ± 9 °C。AA 和 AV 纸浆油在室温下呈液态,熔点分别为 -5 ± 1 °C 和 3 ± 1 °C;两种核仁油脂在室温下均呈固态,以 β′(90% 的晶体)和 β(10% 的晶体)多态形式堆积,熔点几乎相同,均为 30 ± 1 °C。纸浆油在结晶开始时显示出零星的成核现象,并缓慢生长成棒状结晶,在约 40K 的过冷度下结晶度约为 50%。核仁油脂的成核过程是在约 23K 的低温条件下瞬间发生的,呈现出包含结晶薄片的球状生长模式,结晶度为 90%。核仁油脂和纸浆油表现出牛顿流动性和相似的熔体动态粘度(40 °C 时约为 28.5 mPa-s)。AVP 和 AAP 油的脂质特征以不饱和 TAGs 为主,这表明它们具有潜在的营养和健康益处,尤其是与饱和度较高的其他热带油(如棕榈油)相比。尤其是 AAP 油,其不饱和程度与橄榄油相当,含有大量的 beta 胡萝卜素,并具有独特的风味。AAK 和 AVK 的脂质特征和相变表明,它们在需要高固体脂肪含量和中链脂肪酸的应用领域具有潜力。它们的月桂酸和肉豆蔻酸含量较高,与重要的工业用热带油(椰子油和棕榈仁油)相似,因此可用于类似配方。果仁油脂的熔点和可塑性与可可油和牛油果油相似,因此可用作化妆品、食品和糖果的替代品。不过,还需要更好地了解它们的营养状况和对健康的影响。
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引用次数: 0
A Review on Machine/Deep Learning Techniques Applied to Building Energy Simulation, Optimization and Management 应用于建筑能源模拟、优化和管理的机器/深度学习技术综述
Pub Date : 2024-03-06 DOI: 10.3390/thermo4010008
Francesca Villano, Gerardo Maria Mauro, Alessia Pedace
Given the climate change in recent decades and the ever-increasing energy consumption in the building sector, research is widely focused on the green revolution and ecological transition of buildings. In this regard, artificial intelligence can be a precious tool to simulate and optimize building energy performance, as shown by a plethora of recent studies. Accordingly, this paper provides a review of more than 70 articles from recent years, i.e., mostly from 2018 to 2023, about the applications of machine/deep learning (ML/DL) in forecasting the energy performance of buildings and their simulation/control/optimization. This review was conducted using the SCOPUS database with the keywords “buildings”, “energy”, “machine learning” and “deep learning” and by selecting recent papers addressing the following applications: energy design/retrofit optimization, prediction, control/management of heating/cooling systems and of renewable source systems, and/or fault detection. Notably, this paper discusses the main differences between ML and DL techniques, showing examples of their use in building energy simulation/control/optimization. The main aim is to group the most frequent ML/DL techniques used in the field of building energy performance, highlighting the potentiality and limitations of each one, both fundamental aspects for future studies. The ML approaches considered are decision trees/random forest, naive Bayes, support vector machines, the Kriging method and artificial neural networks. The DL techniques investigated are convolutional and recursive neural networks, long short-term memory and gated recurrent units. Firstly, various ML/DL techniques are explained and divided based on their methodology. Secondly, grouping by the aforementioned applications occurs. It emerges that ML is mostly used in energy efficiency issues while DL in the management of renewable source systems.
鉴于近几十年来的气候变化和建筑领域日益增长的能源消耗,人们广泛关注建筑的绿色革命和生态转型研究。在这方面,人工智能可以成为模拟和优化建筑节能性能的宝贵工具,最近的大量研究就证明了这一点。因此,本文综述了近年来(主要是 2018 年至 2023 年)有关机器/深度学习(ML/DL)在建筑能效预测及其模拟/控制/优化方面应用的 70 多篇文章。本综述使用 SCOPUS 数据库,以 "建筑物"、"能源"、"机器学习 "和 "深度学习 "为关键词,选择了涉及以下应用的最新论文:能源设计/改造优化、预测、供热/制冷系统和可再生能源系统的控制/管理和/或故障检测。值得注意的是,本文讨论了 ML 和 DL 技术的主要区别,并举例说明了它们在建筑能源模拟/控制/优化中的应用。本文的主要目的是对建筑能效领域最常用的 ML/DL 技术进行归类,强调每种技术的潜力和局限性,这两个方面都是未来研究的基础。所考虑的 ML 方法包括决策树/随机森林、天真贝叶斯、支持向量机、克里金法和人工神经网络。研究的 DL 技术包括卷积和递归神经网络、长短期记忆和门控递归单元。首先,解释了各种 ML/DL 技术,并根据其方法进行了划分。其次,根据上述应用进行分组。结果表明,ML 主要用于能源效率问题,而 DL 则用于可再生能源系统的管理。
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