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Occurrence and risk assessment of organochlorine pesticides in River Rwizi sediment in Western Uganda. 乌干达西部Rwizi河沉积物中有机氯农药的发生及风险评价
Pub Date : 2025-01-01 Epub Date: 2025-11-22 DOI: 10.1007/s44274-025-00465-7
Grace Birungi, Denis Byamugisha, Steven Morrison, James Bolender

Fifteen organochlorine pesticides (OCPs) were determined in sediments from 14 sites in upper, middle and lower reaches of River Rwizi. Duplicate samples were collected at each site, during three sampling regimes covering the wet and dry seasons. Sediments were extracted using acetone: hexane (1:1 mixture) and clean-up was achieved using C18 cartridge. OCPs were determined using gas chromatography-mass spectrometry (GC-MS). Principal component analysis (PCA) was used to assess spatial relationships. To assess ecological health risk, the risk quotient (RQ) based on exposure and toxicity was calculated. Hazard index (HI), based on the sum of ratios of the OCP doses to permitted levels was calculated assess risk to human health. Recoveries of 54.4-93%, linearity (R2) > 0.9988, limits of detection (LoD) of 0.34-0.66 ng/kg and limits of quantification (LoQ) of 1.02-2.01 ng/kg were obtained during method validation. The total OCPs concentration was 84.34-159.5 µg/kg dry weight. Presence of OCPs in the sediment may be attributed to environmental persistence, however the presence of endosulfans implies continuing input since they have a relatively short half-life. Ecological risk quotient (RQ) values were 0.01-9780.37 while hazard index (HI) values were all less than 1. The HI for dermal exposure in children was 0.2695 and in adults it was 0.1497, exceeding the negligible risk threshold of H < 0.1. While the risk to human health was low, the high risk posed to ecology by heptachlor (RQ = 9780.37) and endosulfan II (RQ = 835.98) requires immediate mitigation.

Supplementary information: The online version contains supplementary material available at 10.1007/s44274-025-00465-7.

对日维济河上、中、下游14个地点沉积物中15种有机氯农药进行了检测。在每个地点收集了重复的样本,在三个采样制度覆盖湿季和旱季。用丙酮:己烷(1:1混合物)提取沉积物,用C18滤筒进行清理。采用气相色谱-质谱联用(GC-MS)测定OCPs。采用主成分分析(PCA)评价空间关系。为了评估生态健康风险,计算了基于暴露和毒性的风险商(RQ)。危害指数(HI)是根据OCP剂量与允许水平之比的总和来计算的,用以评估对人类健康的风险。方法回收率为54.4 ~ 93%,线性(R2)为0.9988,检出限为0.34 ~ 0.66 ng/kg,定量限为1.02 ~ 2.01 ng/kg。总OCPs浓度为84.34 ~ 159.5µg/kg干重。沉积物中ocp的存在可归因于环境持久性,但硫丹的存在意味着持续输入,因为它们的半衰期相对较短。生态风险商(RQ)值为0.01 ~ 9780.37,危害指数(HI)值均小于1。儿童皮肤暴露的HI为0.2695,成人为0.1497,超过可忽略的风险阈值H。补充信息:在线版本包含补充资料,可在10.1007/s44274-025-00465-7。
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引用次数: 0
Occurrence of toxic metals in river Rwizi surface water and efficacy of wastewater stabilization ponds (WSPs) in Mbarara City, Uganda. 乌干达姆巴拉拉市Rwizi河地表水中有毒金属的出现及废水稳定池(WSPs)的效果。
Pub Date : 2025-01-01 Epub Date: 2025-11-16 DOI: 10.1007/s44274-025-00446-w
Grace Birungi, Denis Byamugisha, Robinah Asiimwe, Irene Aheisibwe, Deusdedit Tusubira, Paul E Alele, Muhamad Ntale, James Bolender

Toxic metal concentrations and physical chemical properties of River Rwizi surface water were determined. Aluminium, antimony, arsenic, barium, beryllium, cadmium, chromium, cobalt, copper, iron, potassium, lead, manganese, molybdenum, nickel, selenium, silver, thallium, thorium, uranium, vanadium, and zinc, were quantified using Inductively coupled plasma optical emission spectroscopy (ICP-OES). Physical chemical parameters were measured in-situ using a HANA meter. Heavy metal pollution index (HMPI), Contamination Degree (CD) and Hazard index (HI) were determined by comparing measured concentrations and reference values. Efficacy of wastewater treatment was evaluated from metal concentrations at the inlet and outlet of the Wastewater Stabilization Ponds (WSP). Selenium (up to 10.35 µg/L), iron (up to 601.74 µg/L) and aluminium (up to 435.44 µg/L), were higher than the World Health Organization (WHO) recommendations of 10 µg/L, 300 µg/L and 100 µg/L respectively. The physical-chemical parameters met the drinking water standard, except for turbidity (up to 89.1 NTU) which was higher than the WHO recommendation of < 5 NTU. HMPI was 19.5-140.7 and CD was - 12.0-18.5 showing moderate to very high pollution. The HI was 0.084-0.804 for children and 0.036-0.379 for adults. For chronic exposure, HI was 0.008-0.069 for children and 0.016-0.163 for adults. The risk to human health exceeded the negligible threshold of HI ≤ 0.1 for adults. The efficiency of removal of metals by WSPs was low (5.87-57.73%), therefore, better wastewater management methods are desirable for protection of human health.

Supplementary information: The online version contains supplementary material available at 10.1007/s44274-025-00446-w.

测定了日茨河地表水中有毒金属的浓度和理化性质。铝、锑、砷、钡、铍、镉、铬、钴、铜、铁、钾、铅、锰、钼、镍、硒、银、铊、钍、铀、钒和锌使用电感耦合等离子体光学发射光谱(ICP-OES)进行定量。物理化学参数采用HANA仪进行原位测量。通过实测浓度与参考值的比较,确定重金属污染指数(HMPI)、污染度(CD)和危害指数(HI)。通过废水稳定池(WSP)进出口金属浓度对废水处理效果进行了评价。硒(高达10.35µg/L)、铁(高达601.74µg/L)和铝(高达435.44µg/L)分别高于世界卫生组织(WHO)建议的10µg/L、300µg/L和100µg/L。除浊度(高达89.1 NTU)高于WHO推荐的- 12.0-18.5(中度至极高污染)外,其他理化参数均符合饮用水标准。儿童的HI为0.084 ~ 0.804,成人为0.036 ~ 0.379。对于慢性暴露,儿童的HI为0.008-0.069,成人为0.016-0.163。对人体健康的风险超过了成人HI≤0.1的可忽略阈值。废液对金属的去除率较低(5.87 ~ 57.73%),因此,为了保护人类健康,需要更好的废水管理方法。补充信息:在线版本包含补充资料,提供地址为10.1007/s44274-025-00446-w。
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引用次数: 0
Scoping review of the societal impacts of compound climate events. 对复合气候事件的社会影响进行范围审查。
Pub Date : 2025-01-01 Epub Date: 2025-01-16 DOI: 10.1007/s44274-025-00185-y
Caroline A Fehlman, Sophia C Ryan, Kristen G Lysne, Quinn M Rundgren, Taylin J Spurlock, Rustyn O Orbison, Jennifer D Runkle, Margaret M Sugg

Climatic extremes have historically been seen as univariate; however, recent international reports have highlighted the potential for an increase in compound climate events (e.g., hot and dry events, recurrent flooding). Despite the projected increase in the frequency of compound climate events and the adoption of compound event terminology, few studies identify climate extremes as compound climate events and little evidence exists on the societal impacts of these compound climate events. This scoping review summarizes key findings and knowledge gaps in the current state of empirical studies that focus on the societal impacts of compound climate events. We identified 28 eligible studies published in four databases reporting on the societal impacts of compound climate events in four sectors: agriculture, public health, the built environment, and land use. Overall, we found the need for more research explicitly linking compound climate events to societal impacts, particularly across multiple compound climate events, rather than single case study events. We also noted several key findings, including changes in agricultural productivity, loss of habitat, increased fire risk, poor mental health outcomes, decreased health care access, and destruction of homes and infrastructure from these events. Additional research is needed both globally and locally to understand the implications of compound climate events across different geographic regions and populations to ensure responsive adaptation policies in a compound climate event framework.

Supplementary information: The online version contains supplementary material available at 10.1007/s44274-025-00185-y.

历史上,极端气候被认为是单变量的;然而,最近的国际报告强调了复合气候事件(如干热事件、经常性洪水)增加的可能性。尽管复合气候事件的频率预计会增加,复合气候事件术语的采用也会增加,但很少有研究将极端气候事件确定为复合气候事件,而且关于这些复合气候事件的社会影响的证据也很少。本综述总结了当前关注复合气候事件的社会影响的实证研究的主要发现和知识差距。我们确定了发表在四个数据库中的28项符合条件的研究,这些研究报告了复合气候事件在四个领域的社会影响:农业、公共卫生、建筑环境和土地利用。总的来说,我们发现需要更多的研究明确地将复合气候事件与社会影响联系起来,特别是跨多个复合气候事件,而不是单一的案例研究事件。我们还注意到一些重要的发现,包括农业生产力的变化、栖息地的丧失、火灾风险的增加、心理健康状况的恶化、获得医疗服务的机会的减少以及这些事件造成的房屋和基础设施的破坏。全球和地方都需要进一步的研究,以了解复合气候事件对不同地理区域和人口的影响,以确保在复合气候事件框架下采取响应性的适应政策。补充信息:在线版本包含补充资料,提供地址为10.1007/s44274-025-00185-y。
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引用次数: 0
Agronomic and socio-economic drivers of fertilizer use and crop productivity in smallholder wheat production systems in Ethiopia. 埃塞俄比亚小农小麦生产系统中肥料使用和作物生产力的农艺和社会经济驱动因素。
Pub Date : 2024-01-01 Epub Date: 2024-11-13 DOI: 10.1007/s44274-024-00162-x
Ebrahim Mohammed, Mesfin Tewodros, Tamene Lulseged, Liben Feyera, Abera Wuletawu, Tilaye Amsalu

Wheat (Triticum aestivum L.) is crucial for global food security and a staple crop in Ethiopia, yet farmer yields remain low, averaging 2.7 t ha⁻1 compared to over 5 t ha⁻1 at research stations. This study investigates the impact of socio-economic factors, local agronomic practices, and site-specific fertilizer management on wheat production in Goba, Lemu, Siyadebr, and Basona districts of Ethiopia. A survey of 228 households analyzed the influence of these factors on wheat productivity and fertilizer use, employing descriptive statistics, t-tests, and regression models. Results indicated that crop residue retention, improved wheat varieties, and organic fertilizers significantly increased yields, while row fertilizer application at planting had a negative effect. Fertilizer application rates varied significantly among farmers and were influenced by practices like top-dressing, monocropping, and participation in agricultural training. District-level differences in yield and fertilizer response highlighted the need for site-specific management. Multiple regression analysis revealed that key predictors of fertilizer use included cultivated land area, household income, education, small ruminant ownership, and extension contact, with larger land ownership, higher income, organic fertilizer use, and extension access being the most significant. Average yield increases due to site-specific fertilizer applications varied across districts. Overall, significant yield gains were achieved through site-specific fertilizer application across the four districts, with an average yield of 5.3 Mg ha⁻1, compared to approximately 4 Mg ha⁻1 using the local farmers' fertilizer application rates. This study underscores the importance of considering local agroecological conditions in fertilizer management to boost wheat productivity and support food security and economic development in Ethiopia.

小麦(Triticum aestivum L.)对全球粮食安全至关重要,也是埃塞俄比亚的主粮作物,但农民的产量仍然很低,平均为 2.7 吨/公顷,而研究站的产量超过 5 吨/公顷。本研究调查了埃塞俄比亚 Goba、Lemu、Siyadebr 和 Basona 地区的社会经济因素、当地农艺实践和特定地点肥料管理对小麦产量的影响。通过对 228 户家庭进行调查,采用描述性统计、t 检验和回归模型,分析了这些因素对小麦产量和肥料使用的影响。结果表明,作物秸秆保留、改良小麦品种和有机肥显著提高了产量,而播种时施用行肥则产生了负面影响。农户之间的施肥量差异很大,并受到表施、单作和参加农业培训等做法的影响。各地区在产量和肥料反应方面的差异凸显了因地制宜管理的必要性。多元回归分析表明,肥料使用的主要预测因素包括耕地面积、家庭收入、教育程度、小反刍动物所有权和推广联系,其中土地所有权较大、收入较高、使用有机肥料和推广联系最为重要。因地制宜施肥带来的平均增产幅度因地区而异。总体而言,四个地区通过因地施肥实现了大幅增产,平均产量为 5.3 兆克/公顷,而按照当地农民的施肥量,平均产量约为 4 兆克/公顷。这项研究强调了在肥料管理中考虑当地农业生态条件对提高埃塞俄比亚小麦产量、支持粮食安全和经济发展的重要性。
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引用次数: 0
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