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Investigation of Tunable Surface Plasmon Resonances on Spheroid Core–Shell Alloy Nanoparticles Using DDA Method 球形核壳合金纳米颗粒表面等离子体共振的DDA研究
IF 0.5 4区 材料科学 Q4 Engineering Pub Date : 2018-07-25 DOI: 10.20944/PREPRINTS201807.0480.V1
Jing Liu, C. Su, Qiubo Ye, Wei Chen, Yu-Shan Chen, Cheng-Fu Yang
In this work, numerical simulations for the absorption and scattering efficiencies of spheroid core–shell nanoparticles (CSNs) were conducted and studied using the discrete-dipole approximation method. The characteristics of surface plasmon resonances (SPR) depend upon shell thickness, the compositions of the core and shell materials, and the aspect ratio of the constructed CSNs. We used different core@shell compositions, specifically Au@SiO2, Ag@SiO2, Au@TiO2, Ag@TiO2, Au@Ag, and Ag@Au, for extinction spectra analysis. We also investigated coupled resonance mode wavelengths by adjusting the composition’s layer thickness and aspect ratio. In this study, we show that the extinction efficiency of the Ag@TiO2 core–shell nanoparticles (CSNPs) was higher than that of the others, and we examined the impact of TiO2 shell thickness and Ag core radius on SPR peak positions. From the extinction spectra we found that the Ag@TiO2 nanoparticle had better refractive index sensitivity and figure of merit when the aspect ratio was set to 0.3. All of the experimental results proved that the tunability of these plasmonic resonances was highly dependent on the material used, the layer thickness, and the aspect ratio of the core@shell CSNPs.
本文采用离散偶极子近似方法对球形核壳纳米粒子(CSNs)的吸收和散射效率进行了数值模拟。表面等离子体共振(SPR)的特性取决于壳层厚度、核壳材料的组成以及所构建的csn的长宽比。我们使用不同的core@shell组成,特别是Au@SiO2, Ag@SiO2, Au@TiO2, Ag@TiO2, Au@Ag和Ag@Au进行消光光谱分析。我们还通过调整组合物的层厚和长宽比来研究耦合共振模式波长。在本研究中,我们发现Ag@TiO2核壳纳米粒子(csnp)的消光效率高于其他纳米粒子,并研究了TiO2壳厚度和Ag核半径对SPR峰位置的影响。消光光谱表明,当宽高比为0.3时,Ag@TiO2纳米粒子具有较好的折射率灵敏度和优值。所有的实验结果都证明了这些等离子共振的可调性高度依赖于所用的材料、层厚度和core@shell csnp的长径比。
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引用次数: 1
Studies about the generation and characterisation of microdroplets with a controlled content 含量可控微滴的生成与表征研究
IF 0.5 4区 材料科学 Q4 Engineering Pub Date : 2010-01-01 DOI: 10.5072/ZENODO.34980
V. Nastasa, V. Pradines, I. Andrei, M. Boni, M. Pascu, Reinhard Miller
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引用次数: 6
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Optoelectronics and Advanced Materials-Rapid Communications
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