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Effectiveness of Gravity Separation of Low Grade Nigerian Gold Ore Using Shaking Table 振动台重选低品位尼日利亚金矿石的效果研究
Pub Date : 2022-01-01 DOI: 10.4236/ijnm.2022.102002
O. Teniola, A. Adeleke, S. Ibitoye, Moshood Deinde Shitu
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引用次数: 0
Utilization of Various Analogy of Synthetic Nanoporous Zeolites and Composite of Zeolites for Decontamination/Detoxification of CWA Simulants—An Updated Review 合成纳米孔沸石和复合沸石的各种类比物在CWA模拟物去污解毒中的应用综述
Pub Date : 2019-10-30 DOI: 10.4236/ijnm.2019.84004
Neeraj Kumar, K. Tiwari, Km. Meenu, Arti Sharma, A. Jain, Shikha Singh, R. Tomar
In this review, we summaries the past few year work on the chemistry of CWA’s and their simulants on various heterogeneous surfaces of zeolites, composites of zeolites and doped zeolite with transition metal oxides. This review elaborates an updated literature overview on the degradation of CWA’s and its simulants. The data written in this review were collected from the peer-reviewed national and international literature.
本文综述了近年来在沸石、沸石复合材料和掺杂过渡金属氧化物的沸石等不同非均相表面上的化学反应及其模拟物的研究进展。本文对CWA及其模拟物降解的最新文献进行了综述。本综述中的数据收集自同行评议的国内和国际文献。
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引用次数: 3
Effect of Sodium Oleate Concentration Variations on Froth Flotation of Manganese Ore 油酸钠浓度变化对锰矿石泡沫浮选的影响
Pub Date : 2019-07-30 DOI: 10.4236/ijnm.2019.83003
O. Oladapo, Alabi Oladunni
Each type of a manganese deposit is a problem by itself in the matter of selection of a proper method of concentration, depending on the manganese minerals and their gangue constituents. Hence, this work studied the effect of sodium oleate concentration variation on the froth flotation of manganese ore obtained from Madaka, Niger State, Nigeria. The chemical analysis of the ore shows that it contains 48.4% MnO (37.5% Mn). Peaks were identified in XRD analysis of the crude sample as that of magnosite (MnO), hausmannite (Mn3O4), spessartine and vemuculite (Mg, Fe2+, Fe3+)3[(AlSiO4)O10](OH)2·4H2O. The ore was beneficiated by froth flotation using sodium oleate as collector at varied concentrations of 3 g/kg, 7 g/kg and 10 g/kg. Other chemical reagents used were sodium silicate, fuel oil and calcium hydroxide as dispersant, frother and pH modifier respectively. Results obtained showed percentage metal recoveries of 9.29%, 14.30% and 19.61%, assaying 65.20%, 62.03% and 61.30% Mn respectively. This indicates that at sodium oleate concentration of 3 g/kg, high grade-concentrate can be obtained.
根据锰矿物及其脉石成分,每种类型的锰矿床在选择合适的浓缩方法方面都是一个问题。因此,本工作研究了油酸钠浓度变化对尼日利亚尼日尔州马达卡锰矿泡沫浮选的影响。矿石的化学分析表明,它含有48.4%的MnO(37.5%的Mn)。在粗样品的XRD分析中鉴定出的峰为镁铁矾(MnO)、hausmanite(Mn3O4)、spessartine和vemuculite(Mg,Fe2+,Fe3+)3[(AlSiO4)O10](OH)2·4H2O。以油酸钠为捕收剂,以3、7和10 g/kg的不同浓度对矿石进行泡沫浮选选矿。使用的其他化学试剂分别是硅酸钠、燃料油和氢氧化钙作为分散剂、起泡剂和pH调节剂。结果表明,金属回收率分别为9.29%、14.30%和19.61%,锰含量分别为65.20%、62.03%和61.30%。这表明在油酸钠浓度为3g/kg时,可以获得高品位的浓缩物。
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引用次数: 1
Effect of Calcination Condition on Thermal Activation of Ibere Clay and Dissolution of Alumina 煅烧条件对粘土热活化及氧化铝溶解的影响
Pub Date : 2019-04-03 DOI: 10.4236/IJNM.2019.82002
U. Mark, C. N. Anyakwo, O. Onyemaobi, C. S. Nwobodo
Bauxite deposits for production of alumina are lacking in Nigeria and there is an aluminium smelter plant in the country which requires alumina for its operation. Development of alternative alumina resource using clays that are abundant in the country is the focus of this paper. The thermal activation of Ibere clay from southeastern Nigeria for optimal leaching of alumina was investigated. The clay assayed 28.52% Al2O3 and 51.6% SiO2, comprising mainly kaolinite mineral and quartz or free silica. The alumina locked up in the clay structure was rendered acid-soluble by thermal activation which transformed the clay from its crystalline nature to an amorphous, anhydrous phase or metakaolinite. The clay samples were heated at calcination temperatures of 500°C, 600°C, 700°C, 800°C, and 900°C at holding times of 30, 60, and 90 minutes. Uncalcined clay samples and samples calcined at 1000°C (holding for 60 minutes) were used in the control experiments. The result of leaching the clay calcines in 1 M hydrochloric acid solution at room temperature, showed that the clay calcines produced at 600°C (holding for 60 minutes) responded most to leaching. Samples calcined for 60 minutes also responded better than those held for 30 or 90 minutes. Based on activation energy studies, it was observed that calcines produced at 600°C (for 60 minutes) had both the highest leaching response (50.27% after 1 hour at leaching temperature of 100°C) and the lowest activation energy of 24.26 kJ/mol. It is concluded therefore that Ibere kaolinite clay should be best calcined for alumina dissolution by heating up to 600°C and holding for 60 minutes at that temperature. The clay deposit has potential for use as alternative resource for alumina production in Nigeria where bauxite is scarce.
尼日利亚缺乏用于生产氧化铝的铝土矿矿床,该国有一家铝冶炼厂,其运营需要氧化铝。利用我国丰富的粘土开发替代氧化铝资源是本文的重点。研究了尼日利亚东南部伊比利亚粘土的热活化对氧化铝的最佳浸出效果。粘土的Al2O3含量为28.52%,SiO2含量为51.6%,主要由高岭石矿物和石英或游离二氧化硅组成。锁定在粘土结构中的氧化铝通过热活化而变得酸溶性,热活化将粘土从其结晶性质转变为无定形无水相或偏高岭土。粘土样品在500°C、600°C、700°C、800°C和900°C的煅烧温度下加热,保温时间分别为30、60和90分钟。在对照实验中使用未煅烧的粘土样品和在1000°C下煅烧(保持60分钟)的样品。在室温下将粘土煅烧物在1M盐酸溶液中浸出的结果表明,在600°C(保持60分钟)下生产的粘土煅烧物对浸出反应最大。煅烧60分钟的样品也比保持30或90分钟的样品反应更好。根据活化能研究,观察到在600°C(60分钟)下生产的煅烧产物具有最高的浸出反应(在100°C的浸出温度下1小时后为50.27%)和24.26kJ/mol的最低活化能。因此,得出的结论是,伊比利亚高岭石粘土最好通过加热至600°C并在该温度下保持60分钟来煅烧以溶解氧化铝。在铝土矿稀缺的尼日利亚,粘土矿床有潜力作为氧化铝生产的替代资源。
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引用次数: 6
Dissolution Behavior of Gold in Alkaline Media Using Thiourea 硫脲对金在碱性介质中的溶解行为研究
Pub Date : 2019-01-01 DOI: 10.4236/ijnm.2019.81001
C. Vargas, P. Navarro, D. Espinoza, J. Manriquez, E. Mejia
In this work the dissolutive behavior of gold in alkaline medium using thiourea (TU), under different variables, was studied in a theoretical and experimental way, in order to determine the conditions under which it is feasible to dissolve gold in thiourea-alkaline medium. A thermodynamic study was conducted by chemical speciation using the method of Ro-jas-Hernandez, together with an electrochemical study where the electric potential was swept in the anodic direction. The main results of the thermodynamic study were that formamidine disulfide (FDS) and sulfinic compounds (S.C.) prevail at alkaline pH; by increasing the initial concen-tration of thiourea at alkaline pH, the presence of the gold complex is al-most zero for any initial concentration of thiourea. By including sodium sulfite in the gold-thiourea system, it was possible to obtain the Au(I)-TU complex at alkaline pH, with a presence of 95.13%. Electrochemical tests allowed verifying that in the absence of sodium sulfite the dissolution of gold in an alkaline medium is very slow but adding sodium sulfite im-provements become evident in the dissolution of the metal. Therefore, sodium sulfite catalyzes the gold dissolution process and stabilizes the thiourea. With this study it was possible to establish the feasibility of using thiourea in an alkaline medium for the dissolution of gold, and the conditions under which it is possible to dissolve the gold in that medium. With these fundamentals and conditions, it is now possible to move forward to test this system for minerals and/or concentrates containing gold.
本文从理论和实验两方面研究了硫脲(TU)在碱性介质中溶解金的行为,确定了硫脲-碱性介质中溶解金的可行条件。利用Ro-jas-Hernandez的化学形态法进行了热力学研究,同时进行了电化学研究,电势在阳极方向上扫过。热力学研究的主要结果是:在碱性条件下,甲脒二硫化物(FDS)和亚砜化合物(S.C.)占主导地位;在碱性pH下增加硫脲的初始浓度,对于任何初始浓度的硫脲,金络合物的存在几乎为零。通过在金-硫脲体系中加入亚硫酸钠,可以在碱性pH下得到Au(I)-TU配合物,存在率为95.13%。电化学试验证实,在没有亚硫酸钠的情况下,金在碱性介质中的溶解非常缓慢,但加入亚硫酸钠后,金的溶解效果明显改善。因此,亚硫酸钠催化了金的溶解过程,稳定了硫脲。通过这项研究,有可能确定在碱性介质中使用硫脲溶解金的可行性,以及在该介质中溶解金的可能条件。有了这些基础和条件,现在就有可能对该系统进行含金矿物和/或精矿的测试。
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引用次数: 4
Scientific Exploration and Practice of Safe Production Management of Non-Ferrous Metal Mines under the New Situation—Taking Dahongshan Copper Mine as an Example 新形势下有色金属矿山安全生产管理的科学探索与实践——以大红山铜矿为例
Pub Date : 1900-01-01 DOI: 10.4236/ijnm.2022.103003
Yan Pan
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引用次数: 0
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