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Techniques in rheological measurements 流变学测量技术
Pub Date : 1995-01-01 DOI: 10.1016/0956-7143(95)90023-3
J. Karger-Kocsis
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引用次数: 21
Development of a numerical code that simulates combined heat transfer, resin flow and compaction during composites processing 在复合材料加工过程中模拟复合传热、树脂流动和压实的数值代码的开发
Pub Date : 1995-01-01 DOI: 10.1016/0956-7143(95)99648-C
L. Tredoux, J. Van der Westhuizen

The cure and consolidation of thermoset composite materials is a complex physical process involving combined heat transfer, resin curing, fibre bed compaction and fluid flow. Finite difference simulations for either the heat transfer part of this process or for the resin flow part can be found in the literature. The present paper develops and implements the finite element form of the equations governing composites processing and successfully combines resin flow and heat transfer modelling through the temperature-dependent viscosity. Specifically, this paper (i) sets up the finite element form of the Fourier heat conduction equation and the Gutowski/Davé resin flow equation through the Ritz formulation, (ii) overviews the computer implementation of these equations and (iii) presents selected output results to demonstrate the engineering value of the simulation program. An autoclave process is analysed as a test case. The results illustrate that the developed computer code (FCURE) combines existing mathematical models with the versatility of the finite element method into a simulation tool with engineering potential.

热固性复合材料的固化和固结是一个复杂的物理过程,涉及热传导、树脂固化、纤维床压实和流体流动。该过程的传热部分或树脂流动部分的有限差分模拟可以在文献中找到。本文发展并实现了控制复合材料加工方程的有限元形式,并通过温度依赖粘度成功地将树脂流动和传热模型结合起来。具体而言,本文(i)通过Ritz公式建立了傅里叶热传导方程和Gutowski/ dav树脂流动方程的有限元形式,(ii)概述了这些方程的计算机实现,(iii)给出了选择的输出结果,以证明仿真程序的工程价值。以高压灭菌工艺为例进行了分析。结果表明,所开发的计算机代码(FCURE)将现有的数学模型与有限元方法的通用性相结合,成为具有工程潜力的仿真工具。
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引用次数: 18
The influence of preform joints on the processing of RTM composites 预成形接头对RTM复合材料加工的影响
Pub Date : 1995-01-01 DOI: 10.1016/0956-7143(95)93710-2
D.A Steenkamer , D.J Wilkins , V.M Karbhari

In order to develop preforms for large complex parts capable of meeting the demands of global and local loading conditions, resin transfer moulded parts are typically broken down into multiple elements. A separate preform is developed for each of these sub-sections, which are then assembled in the mould cavity and combined by the moulding process. While the decomposition of a structure into sub-sections eases the burden on the preforming operation(s) to form the desired shape with the appropriate microstructure, it also raises the issue of joining these multi-element preform sections. In previous composites applications, the presence of a joint was traditionally considered only in terms of its influence on the performance of the part, since the fibre and resin were already combined into pre-impregnated tape. However, resin transfer moulding (RTM) is a two-step process: fibre preforming followed by resin impregnation and cure. Since the resin must flow through the preform and wet-out the individual fibre bundles, the inclusion of a preform joint in the design of an RTM part's microstructure must be considered in terms of processing (resin flow and wet-out) as well as performance. In this paper we examine the influence of preform joint on resin flow through both computational and experimental approaches. The implications of such joints on the design and processing of RTM parts is discussed.

为了开发能够满足全局和局部加载条件要求的大型复杂零件的预成形件,树脂传递模塑件通常被分解为多个元素。为每一个子部分开发一个单独的预制体,然后在模腔中组装并通过成型过程组合。虽然将结构分解成小截面减轻了预成形操作的负担,以形成具有适当微观结构的所需形状,但它也提出了连接这些多单元预成形截面的问题。在以前的复合材料应用中,由于纤维和树脂已经结合成预浸渍带,因此传统上只考虑接头的存在对部件性能的影响。然而,树脂转移模塑(RTM)是一个两步过程:纤维预成型,然后树脂浸渍和固化。由于树脂必须流经预成型体并湿化单个纤维束,因此在RTM零件微结构设计中包含预成型接头必须考虑加工(树脂流动和湿化)以及性能。本文通过计算和实验两种方法研究了预制接头对树脂流动的影响。讨论了此类接头对RTM零件设计和加工的影响。
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引用次数: 12
Bending of fibre-reinforced thermoplastic sheets 纤维增强热塑性薄板的弯曲
Pub Date : 1995-01-01 DOI: 10.1016/0956-7143(95)95009-N
T.A. Martin, D. Bhattacharyya, I.F. Collins

When forming continuous fibre-reinforced thermoplastic (CFRT) sheets into three-dimensional components, interply shearing may be necessary in order to accommodate the out-of-plane bending because the fibres severely constrain the deformation along the fibre directions within their planes. Furthermore, thermoforming takes place at elevated temperatures so that the molten matrix polymer becomes fluid. These two factors are of prime importance in analysing any forming process with thermoplastic composite materials. This paper examines the process of forming unidirectional Plytron® (a glass fibre-reinforced polypropylene composite, originally developed by ICI, UK) sheets into V-bends at a constant elevated temperature, and compares the experimental results with those predicted by an analytical model for plane strain bending of an incompressible Newtonian fluid reinforced with a single family of inextensible fibres. The shape of a strip as it is formed, the effects of temperature and forming speed on the forming loads are also investigated. A major conclusion from this study is that Plytron sheets demonstrate a viscoelastic response when formed within their melting range and the degree of elasticity is increased by reducing the temperature, which, in turn, can reduce the fibre instability. The theoretical model provides useful results for evaluating the effective longitudinal viscosity of the composite sheet, the effects of forming speed and punch geometry on the bending stresses and also highlights the limitations of a Newtonian fluid model in comparison with the actual material response.

当将连续纤维增强热塑性塑料(CFRT)片材形成三维构件时,由于纤维在其平面内沿纤维方向严重地约束了变形,因此为了适应面外弯曲,可能需要进行交叉剪切。此外,热成型在高温下进行,使熔融的基质聚合物变成流体。这两个因素在分析任何热塑性复合材料的成形过程中都是至关重要的。本文研究了在恒定高温下将单向Plytron®(一种玻璃纤维增强聚丙烯复合材料,最初由英国ICI公司开发)板材成型为v型弯管的过程,并将实验结果与用单族不可拉伸纤维增强的不可压缩牛顿流体的平面应变弯曲解析模型预测的结果进行了比较。研究了带钢成形时的形状、温度和成形速度对成形载荷的影响。本研究的一个主要结论是,Plytron板材在其熔融范围内形成时表现出粘弹性响应,并且通过降低温度来增加弹性程度,从而可以减少纤维的不稳定性。该理论模型为评估复合材料板的有效纵向粘度、成形速度和冲孔几何形状对弯曲应力的影响提供了有用的结果,并突出了牛顿流体模型与实际材料响应的局限性。
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引用次数: 51
Woven fabric composites 机织复合材料
Pub Date : 1995-01-01 DOI: 10.1016/0956-7143(95)90005-5
Alan Newton
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引用次数: 0
Method of manufacturing fibre gypsum board 纤维石膏板的制造方法
Pub Date : 1995-01-01 DOI: 10.1016/0956-7143(95)99657-E
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引用次数: 0
Extrusion of tubes of fibre-reinforced thermoplastics 纤维增强热塑性塑料管的挤压
Pub Date : 1995-01-01 DOI: 10.1016/0956-7143(95)90012-8
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引用次数: 0
Effect of radial stress relaxation on fibre stress in filament winding of thick composites 厚复合材料绕丝过程中径向应力松弛对纤维应力的影响
Pub Date : 1995-01-01 DOI: 10.1016/0956-7143(95)99646-A
Evan A. Kempner, H.Thomas Hahn

During filament winding of thick cylinders, fibre wrinkling often occurs which severely decreases compressive strength. To eliminate fibre wrinkling, appropriate processing conditions must be found. Fibre migration and stress relaxation due to resin flow are generally considered the most important factors affecting fibre buckling. Therefore, the effect of stress relaxation on fibre wrinkling during the filament winding process was investigated. To study the stress development during filament winding of thick cylinders, experiments were carried out using graphite/epoxy prepreg tows as well as dry graphite fibre. Cylinders of approximately 12 mm thickness were hoop wound on a 50.8 mm diameter aluminium mandrel. Winding tensions ranged from 13 to 34 N and winding speed was constant. A foil-type pressure sensor was applied on the mandrel to monitor the interface pressure throughout winding and storage of the cylinder. Significant stress relaxation was found to occur during winding with prepreg tow. Mandrel pressure increased over the winding of the first eight layers or so. However, between the winding of one layer and the next, mandrel pressure dropped quickly. Also, it began to decrease after reaching a maximum value. A stress relaxation analysis was carried out to determine the stress in the cylinders during winding. Several parameters were not known a priori and had to be inferred from the data. Stress distributions following winding were calculated for each case. The radial stress in prepreg wound cylinders was found to relax nearly to zero in the inner part of the tubes. Compressive circumferential stresses occurred throughout each of the cylinders. However, they reached greater magnitudes in the dry wound cylinders due to very low radial moduli. No fibre wrinkling was evident in any of the wound cylinders.

在厚筒绕丝过程中,纤维起皱现象经常发生,严重降低了纤维的抗压强度。为了消除纤维起皱,必须找到合适的加工条件。纤维迁移和树脂流动引起的应力松弛通常被认为是影响纤维屈曲的最重要因素。因此,研究了应力松弛对纤维缠绕过程中起皱的影响。为了研究厚筒缠绕过程中的应力发展,采用石墨/环氧预浸料束和干燥石墨纤维进行了实验。大约12毫米厚的圆筒绕在50.8毫米直径的铝芯轴上。卷绕张力范围为13 ~ 34牛,卷绕速度恒定。在芯轴上安装了箔片式压力传感器,用于监测气缸在卷绕和贮存过程中的界面压力。预浸料束缠绕过程中出现了明显的应力松弛现象。卷绕前八层左右芯轴压力增大。然而,在一层卷绕和下一层卷绕之间,心轴压力迅速下降。在达到最大值后开始减小。通过应力松弛分析确定了卷绕过程中气缸内的应力。有几个参数是事先不知道的,必须从数据中推断出来。计算了每种情况下绕组后的应力分布。在预浸料缠绕圆筒内,径向应力在管内松弛到接近零。压周向应力发生在每个圆柱体中。然而,由于径向模量非常低,它们在干缠绕圆柱体中达到更大的量级。在任何缠绕的钢瓶中都没有明显的纤维起皱。
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引用次数: 18
Thermoplastic filament winding—an experimental investigation of the on-line consolidation of poly(ether imide) fit preforms 热塑性长丝缠绕——聚醚亚胺配合预制体在线固结的实验研究
Pub Date : 1995-01-01 DOI: 10.1016/0956-7143(95)95013-O
J. Romagna, G. Ziegmann, M. Flemming

The development of industrial-scale manufacturing techniques for thermoplastic composites requires new processing technologies. The filament winding of thermoplastic preforms, such as powder-impregnated or intermingled yarns, would be more economical than winding of thermosets, if similar fibre placement speeds could be achieved for similar costs of equipment and preforms. The present experimental work compares two different processing techniques based on hot air and short wave infra-red spot heating, and discusses the influence of preheating the preforms and mandrel. The research work is based on powder-impregnated poly(ether imide) preforms, which are processed to hoop wound tube specimens. These preforms were commercialized under the trade name FIT (Fibres Impregnated with Thermoplastic) in the early 1980s. Characterization of the laminate quality is based on micrographs. The results show the importance of continuous heating at low heating rate. Discontinuous temperature peaks above the matrix melting temperature lead to its thermal degradation and therefore to poor laminate quality.

工业规模的热塑性复合材料制造技术的发展需要新的加工技术。热塑性预成型的长丝缠绕,如粉末浸渍或混纺纱线,将比热固性预成型的缠绕更经济,如果类似的纤维放置速度可以以类似的设备和预成型成本实现。本实验比较了热空气加热和短波红外线加热两种不同的加工工艺,并讨论了预热对预成形件和芯棒的影响。研究工作是基于粉末浸渍聚醚亚胺预制体,将其加工成环绕管试样。这些预制体在20世纪80年代早期以FIT(热塑性纤维浸渍)的商品名称商业化。层压质量的表征是基于显微照片。结果表明,在低加热速率下进行连续加热的重要性。高于基体熔化温度的不连续温度峰导致其热降解,从而导致层压质量差。
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引用次数: 8
SiC coating on carbon fibres by a solution coating process 碳化硅溶液涂层法在碳纤维上的应用
Pub Date : 1995-01-01 DOI: 10.1016/0956-7143(95)99650-H
Yu-Qing Wang , Zuo-Ming Wang , Jun-Ying Yang , Feng-Qiu Zhang , Ben-Lian Zhou

One way of overcoming the shortcomings of carbon fibres is to coat them with SiC. In this work, carbon fibres were coated with a polycarbosilane solution and then pyrolysed continuously at high temperature to obtain the SiC coating. Effects of the coating process on the structure of the coating and the properties of the coated fibres were studied in detail. The results show that the solution coating process is a simple and applicable technique. The uniform and continuous coating improved the oxidation resistance and strength of the carbon fibres, as well as their wettability with aluminium. The coating also controlled the harmful reaction at the interface of aluminium matrix composites and improved composite strength.

克服碳纤维缺点的一种方法是在其表面涂上SiC。在这项工作中,碳纤维涂覆了聚碳硅烷溶液,然后在高温下连续热解得到SiC涂层。详细研究了涂层工艺对涂层结构和涂层纤维性能的影响。结果表明,溶液镀膜工艺是一种简单、实用的工艺。均匀和连续的涂层提高了碳纤维的抗氧化性和强度,以及它们与铝的润湿性。该涂层控制了铝基复合材料界面处的有害反应,提高了复合材料的强度。
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引用次数: 11
期刊
Composites Manufacturing
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